• Korean Journal of Materials Research
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• v.4 no.2
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• pp.194-205
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• 1994

In this research, we attempt to fabricate an excellent CFRC(Carbon Fiber Reinforced Carbon), which has good thermal and mechanical properties, with 8H/satin woven fabric prepreg, high modulus and high strength type continuous carbon fiber and raw coal tar pitch(RCTP) matrix or THF soluble fraction(THFSP) matrix which has good graphitizability. Green bodies were fabricated with hot press molding technique and CFRC samples were made after carbonization, impregnation, recarbonization and graphitization steps. For the purpose of characterization of the physical properties, SEM, polarized light microscope, TGA were observed, and tested flexural strength, modulus and ILSS. After heat treating the THFSP matrix up to $2300^{\circ}C$, the value of $C_0$/2 was 3.380$\AA$, which is analogous to the structure of natural graphite and the value of 2$\theta$ is $26.276^{\circ}$ approached to the Bragg's angle of natural graphite. As a result of TGA to test the high temperature air oxidation, the THFSP matrix, graphitized up to $2300^{\circ}C$, exhibited the best air oxidation resistance. And mechanical properties were increased up to 65~70% as fiber volume fraction increased. Because of the good orientation graphitizability, the fracture surface of THFSP matrix CFRC is very good.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.81.2-81.2
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• 2012

To fabricate a metal mold for injection molding, hot-embossing and imprinting process, mechanical machining, electro discharge machining (EDM), electrochemical machining (ECM), laser process and wet etching ($FeCl_3$ process) have been widely used. However it is hard to get precise structure with these processes. Electrochemical etching has been also employed to fabricate a micro structure in metal mold. A through mask electrochemical micro machining (TMEMM) is one of the electrochemical etching processes which can obtain finely precise structure. In this process, many parameters such as current density, process time, temperature of electrolyte and distance between electrodes should be controlled. Therefore, it is difficult to predict the result because it has low reliability and reproducibility. To improve it, we investigated this process numerically and experimentally. To search the relation between processing parameters and the results, we used finite element simulation and the commercial finite element method (FEM) software ANSYS was used to analyze the electric field. In this study, it was supposed that the anodic dissolution process is predicted depending on the current density which is one of major parameters with finite element method. In experiment, we used stainless steel (SS304) substrate with various sized square and circular array patterns as an anode and copper (Cu) plate as a cathode. A mixture of $H_2SO_4$, $H_3PO_4$ and DIW was used as an electrolyte. After electrochemical etching process, we compared the results of experiment and simulation. As a result, we got the current distribution in the electrolyte and line profile of current density of the patterns from simulation. And etching profile and surface morphologies were characterized by 3D-profiler(${\mu}$-surf, Nanofocus, Germany) and FE-SEM(S-4800, Hitachi, Japan) measurement. From comparison of these data, it was confirmed that current distribution and line profile of the patterns from simulation are similar to surface morphology and etching profile of the sample from the process, respectively. Then we concluded that current density is more concentrated at the edge of pattern and the depth of etched area is proportional to current density.

• Polymer(Korea)
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• v.36 no.2
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• pp.155-162
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• 2012

Sulfonated poly(ether ether ketone) (SPEEK) nanofibers were prepared by electrospinning. The nanofibrous membrane for polymer electrolyte membrane fuel cell (PEMFC) was fabricated by compression molding. The maximum degree of sulfonation was 95% and the initial thermal degradation temperature was $280^{\circ}C$ and it's value was lower than that of PEEK. The contact angle of SPEEK increased with decreasing the degree of sulfonation. The optimum voltage, flow rate, tip to collector distance (TCD) and concentration of electrospinning conditions were 22 kV, 0.3 mL/hr, 15 cm, and 23 wt%, respectively. The average nanofibrous diameter was 47.6 nm. The water uptake and ion exchange capacity of SPEEK nanofibrous membrane increased with increasing the sulfonation time and the amount of sulfonating agent. The electrical resistance and proton ionic conductivity of SPEEK membrane increased with decreasing and increasing the sulfonation time, respectively. Their values were 0.58~0.06 ${\Omega}{\cdot}cm^2$and 0.099 S/cm.

• Clean Technology
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• v.24 no.4
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• pp.280-286
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• 2018

In this study, the adsorption performance of vapor phase VOCs under dry conditions was evaluated by using two metal oxides, $TiO_2$ powder and $Al_2O_3$ powder. BET analysis and ammonia in-situ FT-IR analysis were used to analyze specific surface area and surface acid site. As a result, $TiO_2$ powder and $Al_2O_3$ powder had a specific surface area of $317.6m^2\;g^{-1}$ and $64m^2\;g^{-1}$, respectively. In the case of $TiO_2$ powder, many acid sites were observed on the surface. As a result of evaluating the vapor phase VOCs adsorption performance using two metal oxide powders, $TiO_2$ powder having a relatively large specific surface area and a large number of acid sites exhibited relatively good adsorption performance. In particular, it is considered that the specific surface area directly affects the adsorption performance, and further study on the effect of the acid site is required. Based on the $TiO_2$ exhibited excellent adsorption performance, it manufactured into various forms of honeycomb, hollow fiber and disc. As a result, the adsorption performance was lower than that of the powder, but it is advantageous in view of applicability. In addition, it was confirmed that the disc adsorbent having excellent thermal durability due to the characteristics of the manufacturing process stably maintains adsorption performance even at a high temperature desorption process several times.

• Journal of the Korean Society of Radiology
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• v.12 no.6
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• pp.713-718
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• 2018

In many previous studies, monte carlo simulation is used to produce lead-free shielding sheet, and the possibility of radiation shielding capability and weight reduction is presented. But it is difficult to simulation for binder and micro-pores because of In fact it does not provide sufficient information necessary for the commercialization process. Therefore, in this paper, the results of radiation shielding capability corresponding to filling factor was presented by using the screen printing method to provide information on gel-paste required for the commercialization process. In this study, the geometric setup for evaluate of radiation shielding ability was designed to comply with IEC 61331-1:2014 and KS A 4025. In addition, radiation irradiation conditions were 100 kVp filtered with 2.0 mmAl total filtration was applied according to KS A 4021 standard. In this study, Pb $1270{\mu}m$, $BaSO_4$ $3035{\mu}m$, $Bi_2O_3$ $1849{\mu}m$ and $WO_3$ $2631{\mu}m$ were analyzed based on ten value layer. Additionally, the filling factor was analyzed as $BaSO_4$ 38.6%, $Bi_2O_3$ 27.1%, $WO_3$ 30.15%. However, in the case of applying low-temperature high-pressure molding in the future, it is expected that the radiation shielding capability can be sufficiently improved by reducing the porosity while increasing the filling factor.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.314-320
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• 2022

The function of reinforcing fibers used in building materials is to maintain resistance to bending loads and to function for cracking caused by drying shrinkage. High-density fiber-cement composites are mainly used for linear plates and are used to increase bending resistance. Therefore, tensile properties, bonding strength with cement hydrate, alkali resistance, and the like are required. Recently, as the non-combustible performance has been strengthened, a function to minimize the occurrence of sparks during high-temperature heating has been added. Therefore, the use of organic fibers is limited. In this study, a study was conducted to replace polypropylene used as reinforcing fiber with hemp fiber with excellent heat resistance. Hemp fibers have excellent heat resistance, good affinity with cement, and excellent alkali resistance. Based on the total volume of polypropylene fibers used in the existing formulation, the non-combustible performance was compared and evaluated by using hemp fibers instead of the polypropylene fibers, and basic physical properties such as flexural strength were tested. As a result of conducting a non-combustibility and physical property test using hemp fibers with a fiber length of 7 mm using 2 % and 3 % by weight, it was found that there is no remaining time of the flame, and the flexural strength can be secured at 95 % level of the existing polypropylene fiber.

• Clean Technology
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• v.28 no.4
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• pp.331-338
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• 2022

The objective of this study is to prepare bead-type and pellet-type Pt (1 wt%)/Kieselguhr catalysts as hydrogenation catalysts for the polycyclic aromatic hydrocarbons (PAHs) included in pyrolysis fuel oil (PFO). The optimal reaction temperature to maximize the yield of saturated cyclic hydrocarbons during the PFO-cut hydrogenation reaction in a trickle bed reactor was determined to be 250 ℃. A hydrogen/PFO-cut flow rate ratio of 1800 was found to maximize 1-ring saturated cyclic compounds. The yield of saturated cyclic compound increased as the space velocity (LHSV) of PFO-cut decreased. The difference in hydrogenation reaction performance between the pellet catalyst and the bead catalyst was negligible. However, the catalyst impregnated by Pt after molding the Kieselguhr support (AI catalyst) showed higher hydrogenation activity than the catalyst molded after Pt impregnation on the Kieselguhr powder (BI catalyst), which was a common phenomenon in both the pellet catalysts and bead catalysts. This may be due to a higher number of active sites over the AI catalyst compared to the BI catalyst. It was confirmed that the pellet catalyst prepared by the AI method had the best reaction activity of the prepared catalysts in this study. The majority of the PFO-cut hydrogenation products were cyclic hydrocarbons ranging from C₈ to C₁₅, and C₁₁ cyclic hydrocarbons had the highest distribution. It was confirmed that both a cracking reaction and hydrogenation occurred, which shifted the carbon number distribution towards light hydrocarbons.

• Composites Research
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• v.36 no.2
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• pp.126-131
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• 2023

Growing environmental concerns regarding pollution caused by conventional plastics have increased interest in biodegradable polymers as alternative materials. The purpose of this study is to develop a 100% biodegradable nanocomposite material by introducing organic nucleating agents into the biodegradable and thermoplastic resin, poly(lactic acid), to improve its properties. Accordingly, cellulose nanofibers, an eco-friendly material, were adopted as a substitute for inorganic nucleating agents. To achieve a uniform dispersion of cellulose nanofibers (CNFs) within PLA, the aqueous solution of nanofibers was lyophilized to maintain their fibrous shape. Then, they were subjected to primary mixing using a twin-screw extruder. Test specimens with double mixing were then produced by injection molding. Differential scanning calorimetry was employed to confirm the reinforced physical properties, and it was found that the addition of 1 wt% CNFs acted as a reinforcing material and nucleating agent, reducing the cold crystallization temperature by approximately 14℃ and increasing the degree of crystallization. This study provides an environmentally friendly alternative for developing plastic materials with enhanced properties, which can contribute to a sustainable future without consuming inorganic nucleating agents. It serves as a basis for developing 100% biodegradable green nanocomposites.

• Korean Journal of Weed Science
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• v.12 no.1
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• pp.8-15
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• 1992

Arrowhead (Sagittaria trifolia L.), a perennial weed dominant in paddy field, is considerably difficult to control by herbicides. The investigation on the effects of environmental factors on emergence of arrowhead tuber can aid for controlling this weed. The results exmined were as follows : From the results of emergence characteristics at different levels of temperature, arrowhead tuber could germinated at 15$^{\circ}C$-40$^{\circ}C$. The optimal temperature for basal emergence was ranged from 25 to 30$^{\circ}C$. Basal emergence at 15$^{\circ}C$ and 20$^{\circ}C$ began at 56 and 12 days after tuber plantation, respectively and were later than those at the optimal temperature. At the different levels of shading, all the tested tubers could emerged. The days required for basal emergence at 25% and 50% shading plots were shorter than those at 70%, 80% and non-shading plots. The basal emergence was more effective under blue and clear films than any other phyto-selective materials. Some of arrowhead tubers could not emerged under green, red and yellow films. On the soil pH, the basal emergence was best at soil pH 6.0 and 7.0. At soil pH 4.0, 5.0 and 8.0, the required days for emergence were longer than those at soil pH 6.0 and 7.0 and some of tubers could not emerged. Arrowhead tubers more then 0.5 g showed the shorter shooting days than those less than 0.5 g. Tubers were able to emerge at water depth ranging from 0 to 20 cm. At 3 cm and 5 cm water depth, the required days for basal shooting were shorter than those at any other levels of water depth. The emergence of basals was best at molding depth of 0 cm, and the rates at 3 to 5 cm of plantation depth were decreased. At 10 cm plantation depth, the shooting rate was significantly decreased.

• Korean Journal of Heritage: History & Science
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• v.47 no.3
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• pp.24-41
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• 2014

Since the celadons excavated from the Son-gok 2-ri 4th kiln site are located in the Beopcheon temple site and at close range, the similarity to the celadons excavated from the Beopcheon temple site is being raised. Thus, this study examined the correlation using a natural-scientific method. In this study, historical ceramic properties of total 19 celadons were examined and they were scientifically analyzed. First of all, according to the scientific analysis, chemical compositions of celadon clay showed a dispersed distribution at RO2 3.79-7.77mole and RO+R2O 0.33-0.49mole. When the microstructure was analyzed, most celadons excavated from the Beopcheon temple site, Wonju, which are estimated to be used in real life, had a favorable state, and some celadons from the Son-gok 2-ri 4th kiln site were found not to be glazed and sintered properly. When analyzing body crystalline phases of the celadons using the XRD method, quartz and mullite were extracted from all of the samples. And corundum was extracted from sg4 sample. Though firing temperature of each sample was different, they were mostly fired to temperatures between 1150 and $1200^{\circ}C$ and some of them experienced a low temperature of $1100^{\circ}C$ or a high temperature above $1200^{\circ}C$. Various chemical compositions and producing techniques were observed in the celadons from the Beopcheon temple site and Son-gok 2-ri 4th kiln site and it is hard to assure that the Son-gok 2-ri 4th kiln site was the production kiln site of the celadons used in the Beopcheon temple site. But according to the analysis of rare earth elements, some of the celadons from the Beopcheon temple site and Son-gok 2-ri 4th kiln site displayed a distribution pattern with certain regularity and this implies there is a possibility that the raw materials used in producing the ceramics might have come from the same origin. From the perspective of ceramic history, the celadons excavated from the Beopcheon temple site and Son-gok 2-ri 4th kiln site were produced using the same molding and sintering technique. Also, it is estimated that they were produced in the 12th or 13th century, judging from the overall shapes and patterns of the celadons.