• Title/Summary/Keyword: Modified synthesis

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Implementation of Formant Speech Analysis/Synthesis System (포만트 분석/합성 시스템 구현)

  • Lee, Joon-Woo;Son, Ill-Kwon;Bae, Keuo-Sung
    • Speech Sciences
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    • v.1
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    • pp.295-314
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    • 1997
  • In this study, we will implement a flexible formant analysis and synthesis system. In the analysis part, the two-channel (i.e., speech & EGG signals) approach is investigated for accurate estimation of formant information. The EGG signal is used for extracting exact pitch information that is needed for the pitch synchronous LPC analysis and closed phase LPC analysis. In the synthesis part, Klatt formant synthesizer is modified so that the user can change synthesis parameters arbitarily. Experimental results demonstrate the superiority of the two-channel analysis method over the one-channel(speech signal only) method in analysis as well as in synthesis. The implemented system is expected to be very helpful for studing the effects of synthesis parameters on the quality of synthetic speech and for the development of Korean text-to-speech(TTS) system with the formant synthesis method.

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Response Optimization for the Preparation of MIL-100(Fe)@COF Materials Using Design of Experiments

  • Min Hyung Lee;Sangmin Lee;Kye Sang Yoo
    • Applied Chemistry for Engineering
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    • v.34 no.4
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    • pp.455-459
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    • 2023
  • Three different optimization studies were conducted for the synthesis of MIL-100(Fe) and MIL-100(Fe)@COF using design of experiments. In the first study, the optimal concentration of precursors was determined using a mixture design method, and a modified molar ratio of 0.4155:0.2664:0.3182 was found to yield the highest crystallinity. In the second study, a central composite design was used to optimize the main factors of synthesis temperature and time with a synthesis temperature of 161℃ and a synthesis time of 12 hours. In the third study, a screening design method was used to determine the effect of five precursors on the formation of MIL-100(Fe)@COF, and the presence of characteristic peaks at 1552, 1483, and 1354 cm-1 was found to be important for the existence of the COF structure. MIL-100(Fe)@COF synthesized with a modified molar ratio of 0.4831:0.4169:0.1 was predicted to exhibit optimal conditions.

Synthesis of Water Soluble Acrylic Modified Epoxyester Resin and Physical Properties of Coatings (수용성 아크릴 변성 에폭시에스테르 수지의 합성 및 도막물성)

  • Kim, Seong-Kil;Shin, Pan-Woo;Lee, Dong-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.1
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    • pp.35-47
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    • 2011
  • For the synthesis of water soluble acrylic modified epoxyester resin, fatty acid/epoxy ratio of 50/50 was used, and introduced maleic anhydride. Ratio of styrene/acrylic acid of acrylic monomers was fixed 85/15 and ratio of epoxyester/acrylic monomer was controlled 80/20, 75/25, 70/30, 65/35, and degree of neutralization were changed 65%, 80%, to 100%. As a result, 40% solids acrylic modified epoxyester resins were synthesized. Resins were evaluated water soluble stability, drying time, water resistant, storage stability and physical properties. And the white paints were prepared, and were evaluated viscosity, drying time, water resistance, adhesion, sagging, spray workability, gloss, salt spray resistance, skinning, whiteness and flash rust. As a result, the degree of neutralization of 100% and the ratio of epoxyester/acrylic monomer of 75/25 showed the best properties.

MUSCLE PROTEIN SYNTHESIS IN VITRO IN CHICKS FED A LOW-PROTEIN DIET

  • Kita, K.;Kuzuya, Y.;Matsunami, S.;Okumura, J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.9 no.2
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    • pp.171-174
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    • 1996
  • Muscle protein synthesis in vitro was measured in chicks fed low-protein(10% CP) and control(20% CP) diets. Right leg muscles (M. gastrocnemius) were mounted on a support made of stainless steel to stretch in constant tension, whereas left leg muscles were unmounted. Both leg muscles were incubated in Dulbecco's modified Eagle's medium including L-[$4-^3H$] phenylalanine for 60 min to measure in vitro protein synthesis. There was no significant difference in fractional synthesis rate(FSR) of muscle protein between both dietary protein levels, whereas FSR with stretch in constant tension was significantly higher than that without constant tension due to an increase in the absolute synthesis rate(ASR) per unit RNA(the efficiency of RNA to synthesize protein). The ASR of muscle protein in chicks fed the control diet was significantly higher than that in the low-protein diet group.

A Study on the Development of Polymer-Modified Mortars Using Styrene-Butyl Acrylate Latexes (St/BA의 모노머 비에 따른 폴리머 시멘트 모르타르 개발에 관한 연구)

  • Hyung, Won-Gil;Mun, Kyung-Ju;Song, Hun
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.785-791
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    • 2006
  • The purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars based on styrene and butyl acrylate latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. This paper deals with the effects of monomer ratio on the typical properties of the polymer-modified mortars with styrene and butyl acrylate latexes. The polymer-modified mortars using the styrene and butyl acrylate latexes polymerized with various monomer ratios are prepared with different polymer-cement ratios, and tested for the particle size of polymer latexes, air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the polymer-modified mortars using styrene and butyl acrylate latexes with the mix proportions of synthesis having monomer ratios of 50:50 to 60:40 for the appropriate mix proportions can be recommended for practical applications. Their basic properties are greatly affected by the polymer-cement ratio rather than the monomer ratio, and are improved over un-modified mortar.

Synthesis and Antibiotic Activities of Poly (acrylic acid) Modified $\beta$-Lactam Cyclics ($\beta$-락탐계 항생물질의 폴리아크릴산 중합체의 합성 및 항균성)

  • 진정일;최성모;장민선;민신홍
    • YAKHAK HOEJI
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    • v.30 no.5
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    • pp.232-237
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    • 1986
  • A series of modified poly(acrylic acid)'s containing different levels of 6-aminopenicillanic acid (6-APA), 7-aminocephalosporanic acid (7-ACA) and 6-[D-(-)-$\alpha$-aminophenyl acetamido] penicillanic acid (ampicillin) as pendant groups were prepared. Antibiotic activities of the newly prepared drugs were examined against the various gram-positive and gram-negative bacteria. It was found that ampicillin modified composition posses antibiotic activities against the gram-negative as well as the gram-positive bacteria.

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