• Korean Journal of Materials Research
• /
• v.27 no.1
• /
• pp.12-18
• /
• 2017

Transparent organic-inorganic hybrid hard coating films were prepared by the addition of $SiO_2$ or $ZrO_2$, as an inorganic filler to improve the hardness property, filler was highly dispersed in the acrylic resin. To improve the compatibility in the acrylic resin, $SiO_2$ or $ZrO_2$ is surface-modified using various silanes with variation of the modification time and silane content. Depending on the content and kind of the modified inorganic oxide, transparent modified inorganic sols were formulated in acryl resin. Then, the sols were bar coated and cured on PET films to investigate the optical and mechanical properties. The optimized film, which has a modified $ZrO_2$ content of 4 wt% markedly improved in terms of the hardness, haze, and transparency as compared to neat acrylate resin and acrylate resin containing modified $SiO_2$ content of 8 wt%. Meanwhile, the low transparency and high haze of these films slowly appeared at $SiO_2$ content above 10 wt% and $ZrO_2$ content of 5 wt%, but the hardness values were maintained at 2H and 3H, respectively, in comparison with the HB of neat acrylate resin.

• Journal of The Korean Society of Agricultural Engineers
• /
• v.49 no.4
• /
• pp.35-41
• /
• 2007

The most agricultural concrete structures for the irrigation and drainage are exposed to the underwater condition at the irrigation period and they take the influence on very severe cold in the winter. Therefore, it is impossible to use repair materials used to the general concrete structures. The research need the development of the repair material for a performance enhance of the agricultural underwater concrete structures. This research evaluated the mechanical and durability performance of the latex modified repair mortar for underwater concrete structures which peformed the repair in the underwater according to the characteristic of the agricultural concrete structure. The latex modified repair mortar is a material that minimize the effect of the ecosystem, environment and the segregation. In this research, the construction condition of the latex modified repair mortar for agricultural concrete structures was considered and the test specimens made in the underwater condition. Test results was then compared with target performance and commercial repair mortar. Experimental test results indicated that the mechanical and durability performance of latex modified repair mortar for agricultural underwater concrete structure satisfied all target performance. Also, the latex modified repair mortar resulted in better repair performance than the commercial repair mortar.

• Proceedings of the International Microelectronics And Packaging Society Conference
• /
• 2000.04a
• /
• pp.9-15
• /
• 2000

Flip chip assembly on organic substrates using ACAs have received much attentions due to many advantages such as easier processing, good electrical performance, lower cost, and low temperature processing compatible with organic substrates. ACAs are generally composed of epoxy polymer resin and small amount of conductive fillers (less than 10 wt. %). As a result, ACAs have almost the same CTE values as an epoxy material itself which are higher than conventional underfill materials which contains lots of fillers. Therefore, it is necessary to lower the CTE value of ACAs to obtain more reliable flip chip assembly on organic substrates using ACAs. To modify the ACA composite materials with some amount of conductive fillers, non-conductive fillers were incorporated into ACAs. In this paper, we investigated the effect of fillers on the thermo-mechanical properties of modified ACA composite materials and the reliability of flip chip assembly on organic substrates using modified ACA composite materials. For the characterization of modified ACAs composites with different content of non-conducting fillers, dynamic scanning calorimeter (DSC), and thermo-gravimetric analyzer (TGA), dynamic mechanical analyzer (DMA), and thermo-mechanical analyzer (TMA) were utilized. As the non-conducting filler content increased, CTE values decreased and storage modulus at room temperature increased. In addition, the increase in tile content of filler brought about the increase of Tg$^{DSC}$ and Tg$^{TMA}$. However, the TGA behaviors stayed almost the same. Contact resistance changes were measured during reliability tests such as thermal cycling, high humidity and temperature, and high temperature at dry condition. It was observed that reliability results were significant affected by CTEs of ACA materials especially at the thermal cycling test. Results showed that flip chip assembly using modified ACA composites with lower CTEs and higher modulus by loading non-conducting fillers exhibited better contact resistance behavior than conventional ACAs without non-conducting fillers.ers.

• Journal of the Microelectronics and Packaging Society
• /
• v.7 no.1
• /
• pp.41-49
• /
• 2000

Flip chip assembly on organic substrates using ACAs have received much attentions due to many advantages such as easier processing, good electrical performance, lower cost, and low temperature processing compatible with organic substrates. ACAs are generally composed of epoxy polymer resin and small amount of conductive fillers (less than 10 wt.%). As a result, ACAs have almost the same CTE values as an epoxy material itself which are higher than conventional underfill materials which contains lots of fillers. Therefore, it is necessary to lower the CTE value of ACAs to obtain more reliable flip chip assembly on organic substrates using ACAs. To modify the ACA composite materials with some amount of conductive fillers, non-conductive fillers were incorporated into ACAs. In this paper, we investigated the effect of fillers on the thermo-mechanical properties of modified ACA composite materials and the reliability of flip chip assembly on organic substrates using modified ACA composite materials. For the characterization of modified ACAs composites with different content of non-conducting fillers, dynamic scanning calorimeter (DSC), and thermo-gravimetric analyser (TGA), dynamic mechanical analyzer (DMA), and thermo-mechanical analyzer (TMA) were utilized. As the non-conducting filler content increased, CTE values decreased and storage modulus at room temperature increased. In addition, the increase in the content of filler brought about the increase of $Tg^{DSC}$ and $Tg^{TMA}$. However, the TGA behaviors stayed almost the same. Contact resistance changes were measured during reliability tests such as thermal cycling, high humidity and temperature, and high temperature at dry condition. It was observed that reliability results were significantly affected by CTEs of ACA materials especially at the thermal cycling test. Results showed that flip chip assembly using modified ACA composites with lower CTEs and higher modulus by loading non-conducting fillers exhibited better contact resistance behavior than conventional ACAs without non-conducting fillers.

• International Journal of Concrete Structures and Materials
• /
• v.2 no.1
• /
• pp.49-55
• /
• 2008

The disadvantage of PMM's (polymer-modified mortars) that are currently on the market is the utilization of expensive polymer additives and also the cost of the other components. One of the possibilities how to decrease this price is the effective utilization of waste materials which are very inexpensive in spite of their good properties. The combinations of different degree in polymer adhesiveness and waste secondary raw materials - fly ash - are experimentally verified in the paper. The use of fly ash in adhesive materials for ceramic tiles is limited by unsatisfactory initial adhesiveness to sintered ceramic sherd as a result of a running pozzolanic reaction that lowers the efficiency of polymer additives. On the other hand, the use of adhesive and backfill coating materials for gluing ETICS board insulation materials has brought very good results.

• Progress in Superconductivity and Cryogenics
• /
• v.5 no.3
• /
• pp.23-25
• /
• 2003

Effect of chemically modified precursor solution on YBCO coated conductor prepared by MOD-TFA method was investigated. YBCO thin films were deposited on (l00)-oriented single crystalline LaAlO$_3$ substrates by conventional MOD-TFA process. The microstructures of YBCO thin films contain maze-like patterns. The origin of this microstructure was delineated by compositional inhomogeneity during the pyrolysis process and it was shown that addition of diethanolamine (DEA) improve the microstructure of grown YBCO films. In addition, it was demonstrated that the chemical modification of precursor solution makes no harmful effect on biaxial texture of YBCO thin films.

• Elastomers and Composites
• /
• v.49 no.2
• /
• pp.117-126
• /
• 2014

Methylene diisocyanate (MDI) was investigated as a novel interfacial modifier to enhance the performances of poly(methyl methacrylate)-modified starch/styrene-butadiene rubber (PMMA-modified starch/SBR) composites. Owing to the formation urethane linkage on one side and ${\pi}-{\pi}$ adhesion on the other side, MDI acted as an intermediated linkage role in the PMMA-modified starch/SBR interfaces, which was evidenced by the morphological, mechanical, dynamic mechanical and thermal decomposition studies. As a result, the presence of MDI significantly improved the mechanical properties and thermal stability of PMMA-modified starch/SBR composites. In addition, the effect of starch concentration on the various performances of the resulted MDI/PMMA-modified starch/SBR composites, such as morphology, vulcanization characteristics, mechanical properties, toluene swelling behavior, and thermal stability were investigated and discussed in detail. The obtained MDI/PMMA-modified starch/SBR composites exhibited superior mechanical properties to carbon black/SBR (CB/SBR) composites, demonstrating the potential use of the renewable starch as a substitute for CB in the rubber compounds.

• Journal of the Korea Concrete Institute
• /
• v.19 no.4
• /
• pp.457-465
• /
• 2007

In this paper, polymer-modified repair materials using polymer dispersions with six repair methods are prepared with various polymer-cement ratios, and tested for compressive and flexural strengths through each curing condition such as dry cure, water cure, and freezing and thawing cyclic action. And, the adhesive interface between the polymer-modified mortar and mortar substrate is observed by a scanning electron microscope. From the test results, the compressive and flexural strengths of cement mortar repaired by polymer-modified mortar are improved with a rise in the polymer-cement ratio regardless of the type of polymer and curing conditions. Such an improvement in the strengths of polymer-modified repair materials to ordinary cement mortar is explained by the high adhesion of polymer-modified mortar. Strength reduction of polymer-modified repair materials after freezing and thawing cyclic actions is recognized, but it is lower than that of unmodified mortar. Especially, cement mortar repaired by polymer-modified mortar with a St/BA emulsion has good strength properties compared with those of SBR latex and PA emulsion. Accordingly, it is judged that polymer-modified mortars with a St/BA emulsion are possible to use as repair materials to ordinary cement mortar and concrete.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 1998.10a
• /
• pp.330-336
• /
• 1998

The friction and wear characteristics of automotive friction materials reinforced with carbon fibers were studied using a direct drive brake dynamometer. Two types of model friction materials, a low-metallic and an NAO type, were prepared and each of the materials was modified by substituting 5 vol% of carbon fibers with other reinforcing fiber used in the model formulations. Drag tests were carried out to investigate the friction properties of these materials at various braking conditions. Results showed that the modified friction materials were improved in the friction stability and the wear resistance.

• The Journal of Korean Academy of Prosthodontics
• /
• v.40 no.3
• /
• pp.269-274
• /
• 2002

statement of problem The viscoelastic property is the most important and peculiar characteristics of soft liners. But the authorized standard is not certainly established than other dental materials. purpose of study This study is aimed to compare the initial flow of gelation of the modified soft liner with 4-META with that of PMMA soft liners using dynamic method and evaluate the clinical acceptance of the trial materials. materials and method This study consists of 3 groups with the given % of 4-META powder in the Coe soft liquid; 0%, 5%, 10% Each group was tested for 10 times to record the change of G′values during 3 hours. the gelation time was recorded by the oscillating rheometer with parallel plate with 1 rad/sec. results As the results of this study, the gelation time of modified soft liner was elongated by 5 to 6 minutes. conclusion The mean gelation time of modified soft liner could be within the range of clinically acceptable.