• 제목/요약/키워드: Modified materials

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Organic Thin-Film Transistors with Screen Printed Silver Source/Drain Electrodes

  • Kim, Sam-Soo;Kim, Min-Soo;Choi, Gyu-Seok;Kim, Heon-Gon;Kim, Yong-Bae;Lee, Dong-Gu;Roh, Jae-Seong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1305-1307
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    • 2007
  • We show that the electrical properties of organic thinfilm transistors(OTFTs) can be enhanced by controlling the morphology of interface between screen printed electrodes and gate dielectrics. Modified surface of the insulator layer($SiO_2$) affect on the interface energy of electrode on $SiO_2$ layer. Contact angle measurement and FT-IR spectrum shows that the interface is properly modified. OTFTs device with high efficiency has been realized through modification of interface layer.

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A synthesis of sugar-modified S-adenosyl-L-homocysteine(AdoHcy) analogues as inhibitors of AdoHcy hydrolase via the coupling sugar-modified adenosine analogues with L-homocysteine sodium salt.

  • Kim, Beom-Tae;Kim, Seung-Ki;Ryu, Jeong-Hyun;Hwang, Ki-Jun
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.235.3-236
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    • 2003
  • S-adenosyl-L-homocysteine(AdoHcy) is the product of all biological methylation in which S-adenosyl-L-methionine (AdoMet) is utilized as a methyl donor and is reversibly hydrolyzed to L-homocysteine and adenosine by AdoHcy hydrolase physiologically. Inhibition of this enzyme results in intracelluar accumulation of AdoHcy leading to a feedback inhibition of AdoMet-dependent methylation reactions which are essential for viral replication. (omitted)

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Correlation Analysis of the Thermal Conductivity Heat Flow Meter and MTPS (Modified Transient Plane Source) Method Using Wood Flooring and Wall Materials (목질마루바닥재와 벽체용 재료를 이용한 평판열류계법과 MTPS (Modified Transient Plane Source)법의 열전도율 상관관계 분석)

  • Cha, Jung-Hoon;Seo, Jung-Ki;Kim, Su-Min
    • Journal of the Korea Furniture Society
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    • v.22 no.2
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    • pp.118-125
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    • 2011
  • These days global warming is the most important problem and the most important factor is high emission of carbon dioxide. The 23% of carbon dioxide emission for building construction must be reduced. Thermal conductivity is the most basic factor that can decrease the energy consumption especially insulation. Therefore, an accurate and continuous thermal conductivity measurement can be a way to save energy. In this paper, there are methods about how to investigate thermal conductivity measurements and comparing two methods which are the Heat Flow Meter 436 and TCi.

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The effect of pore structure and surface properties of carbon nanotube films on the performance of a lithium sulfur battery

  • Song, Hyeonjun;Hwang, Yunjae;Kumar, Vimal Tiwari;Jeong, Youngjin
    • Carbon letters
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    • v.27
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    • pp.12-17
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    • 2018
  • We fabricated a Li-S battery with post-treated carbon nanotube (CNT) films which offered better support for sulfur, and investigated the effect of the surface properties and pore structure of the post-treated CNT films on Li-S battery performance. Post-treatments, i.e., acid treatment, unzip process and cetyltrimethylammonium bromide (CTAB) treatment, effectively modified the surface properties and pore structure of the CNT film. The modified pore structure impacted the ability of the CNT films to accommodate the catholyte, resulting in an increase in initial discharge capacity.

Computation of mixed-mode stress intensity factors in functionally graded materials by natural element method

  • Cho, J.R.
    • Steel and Composite Structures
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    • v.31 no.1
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    • pp.43-51
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    • 2019
  • This paper is concerned with the numerical calculation of mixed-mode stress intensity factors (SIFs) of 2-D isotropic functionally graded materials (FGMs) by the natural element method (more exactly, Petrov-Galerkin NEM). The spatial variation of elastic modulus in non-homogeneous FGMs is reflected into the modified interaction integral ${\tilde{M}}^{(1,2)}$. The local NEM grid near the crack tip is refined, and the directly approximated strain and stress fields by PG-NEM are enhanced and smoothened by the patch recovery technique. Two numerical examples with the exponentially varying elastic modulus are taken to illustrate the proposed method. The mixed-mode SIFs are parametrically computed with respect to the exponent index in the elastic modulus and external loading and the crack angle and compared with the other reported results. It has been justified from the numerical results that the present method successfully and accurately calculates the mixed-mode stress intensity factors of 2-D non-homogeneous functionally graded materials.

Durability of High-fluidity Polymer-Modified Mortar Using Redispersible Polymer Powder (재유화형 분말수지 혼입 고유동 폴리머 시멘트 모르타르의 내구성)

  • Joo Myung-Ki;Lee Youn-Su;Youn Do-Yong;Jung In-Su
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.703-708
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    • 2005
  • The effects of polymer-cement ratio and antifoamer content on the setting time and durability of high-fluidity polymer-modified mortars using redispersible polymer powder are examined. As the result, the setting time of the polymer-modified mortars using redispersible polymer powder tends to be delayed with increasing polymer-cement ratio, regardless of the antifoamer content. The water absorption, chloride ion penetration depth and carbonation depth of the high-fluidity polymer-modified mortars using redispersible polymer powder decrease with increasing polymer-cement ratio and antifoamer content. The resistance of freezing and thawing and chemicals improvement is attributed to the improved bond between cement hydrates and aggregates because of the incorporation of redispersible polymer powder

Temperature-sensitive Liposomes Modified with Poly(N-isopropylacrylamide-co-acrylamide) (Poly(N-isopropylacrylamide-co-acrylamide)로 변형된 온도민감성 리포좀)

  • Hee Dong Han;Sung Soo Kim;Ho Suk Choi;Byung Cheol Shin
    • Journal of the Korean Chemical Society
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    • v.47 no.3
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    • pp.257-264
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    • 2003
  • This study has investigated the temperature-sensitive liposomes, which release anticancer drug(doxorubicin) at the hyperthermia temperature$(~40^{\circ}C)$. The temperature-sensitive liposomes were modified with a copolymers of N-isopropylacrylamide(NIPAAm) and acrylamide(AAm), which exhibit a lower critical solution temperature (LCST) at the hyperthermia temperature. The release of doxorubicin from the modified liposomes was determined by measuring the fluorescence intensity with changing temperature and time. The release of doxorubicin from liposomes modified with poly(NIPAAm-co-AAm) copolymer was increased significantly, because poly(NIPAAm-co-AAm) could undergo the conformational transition in the narrow hyperthermia temperature region$(~40{\pm}2^{\circ}C)$. Moreover, we observed that doxorubicin released from liposomes within 5 minutes, and the size of modified liposomes was 120~170 nm. In this study, we have prepared temperature-sensitive liposomes which could be controlled by temperature. They can be applied in the field of a drug delivery system for tumor targeting by temperature control.

Synthesis and Characterization of Y2O3 Powders by a Modified Solvothermal Process

  • Jeong, Kwang-Jin;Bae, Dong-Sik
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.78-81
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    • 2012
  • $Y_2O_3$ nanomaterials have been widely used in transparent ceramics and luminescent devices. Recently, many studies have focused on controlling the size and morphology of $Y_2O_3$ in order to obtain better material performance. $Y_2O_3$ powders were prepared under a modified solvothermal condition involving precipitation from metal nitrates with aqueous ammonium hydroxide. The powders were obtained at temperatures at $250^{\circ}C$ after a 6h process. The properties of the $Y_2O_3$ powders were studied as a function of the solvent ratio. The synthesis of $Y_2O_3$ crystalline particles is possible under a modified solvothermal condition in a water/ethylene glycol solution. Solvothermal processing condition parameters including the pH, reaction temperature and solvent ratio, have significant effects on the formation, phase component, morphology and particle size of yttria powders. Ethylene glycol is a versatile, widely used, inexpensive, and safe capping organic molecule for uniform nanoparticles besides as a solvent. The characterization of the synthesized Y2O3 powders were studied by XRD, SEM (FE-SEM) and TG/DSC. An X-ray diffraction analysis of the synthesized powders indicated the formation of the $Y_2O_3$ cubic structure upon calcination. The average crystalline sizes and distribution of the synthesized $Y_2O_3$ powders was less than 2 um and broad, respectively. The synthesized particles were spherical and hexagonal in shape. The morphology of the synthesized powders changed with the water and ethylene glycol ratio. The average size and shape of the synthesized particles could be controlled by adjusting the solvent ratio.

Preparation and Properties of Silicone-Modified Epoxy Coating Materials (실리콘 변성 에폭시 코팅 액의 제조와 물성)

  • Kim, Jin Kyung;Bak, Seung Woo;Hwang, Hee Nam;Kang, Doo Whan;Kang, Ho Jong
    • Applied Chemistry for Engineering
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    • v.25 no.4
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    • pp.352-356
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    • 2014
  • PDMS modified epoxy resin with epoxy group (EMPDMS) was prepared from the reaction of ${\alpha},{\omega}$-aminopropylpolydimethylsiloxane and diglycidyl ether of bisphenol-A (DGEBA) based epoxy resin, and PDMS modified epoxy hybrid compound (EMPDMSH) was prepared by introducing alkylesteraminopropyl alkoxy silane to EMPDMS. Their structures were characterized using FT-IR, $^1H$-NMR and $^{29}Si$-NMR. Coating materials were prepared by mixing EMPDMSH base and solvent. Physical properties of the coating materials coated on epoxy/glass fiber composite film were measured according to the content of PDMS in EMPDMSH. Contact angle of coating film was increased 30 to 71 degree. Adhesive property of coating film was 5B degree better then epoxy or acrylate coating materials, and surface roughness was decreased as increasing in EMPDMSH.

Preparation of Mesoporous Materials and Thin Films It's Application for DNA Sensor

  • Han, Seung-Jun;Heo, Soon-Young;Park, Keun-Ho;Lee, Soo;Kim, Byung-Kwan;Kim, Jin-Heung
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.4
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    • pp.345-351
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    • 2004
  • Highly ordered pure-silica MCM-41 materials possessing well-defined morphology have been successfully prepared with surfactant used as a template. The fabrication of mesoporous silica has received considerable attention due to the need to develop more efficient materials' for catalysis, separations, and chemical sensing. The surface modified MCM-41 was used as anadsorbent for biomolecules. Silica-supported organic groups and DNA adsorption on surface modified MCM-41 were investigated by FT-IR and UV-Vis spectrometer, respectively. The use of MCM-41 as the modification of electrode surfaces were investigated electrochemical properties of metal mediators with biomolecules. The modified ITO electrodes increased peak currents for a redox process of $[Ru(bpy)_3]^{2+}$ relative to the bare electrode. The electrochemical detection of DNA by cyclic voltammetry when the current is saturated in the presence of the mediator appeared more sensitive due to a higher catalytic current on the MCM-41 supported electrodes modified by carboxylic acid functional groups. The carboxyl or amine groups on the surface of MCM-41 interact and react with the $-NH_2$ groups of guanine and backbone, respectively. Highly ordered mesoporous materials with organic groups could find applications as DNA sensors.