• 콘크리트학회논문집
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• 제15권3호
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• pp.497-503
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• 2003

Supplementary cementitious materials (SCM) such as fly ash, ground granulated blast furnace slag and silica fume are now being extensively used in concrete to control expansion due to alkali-silica reactivity (ASR). However, the replacement level of a single SCM needed to deleterious ASR expansion and cracking may create other problem and concerns. For example, incorporating silica fume at levels greater than 10％ by mass of cement may lead to dispersion and workability concerns, while fly ash can lead to poor strength development at early age, The combination of silica fume and fly ash in ternary cementitious system may alleviate this and other concerns, and result in a number of synergistic effects. The aim of the study was to enable evaluation of more realistic suitability of a silica fume-fly ash combination system for ASR resistance based on an in-house modification of ASTM C 1260 test method. The modification can be more closely identified with actual field conditions. In this study three different strengths of NaOH test solution(1N, 0.5N, and 0.25N) were used to measure the expansion characteristics of mortar bar made with a reactive aggregate. The other variable included longer testing period of 28 days instead of a conventional 14 days.

• 한국건축시공학회지
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• 제8권5호
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• pp.85-91
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• 2008

Prepacked concrete has recently been used in the special constructions fields such as underwater concrete work, heavy-weight concrete work, underground structure work, partial repair works for damaged reinforced concrete structures. and polymer-modified mortars have been employed as grouting mortars for the prepacked concrete. The purpose of this study is to recommend the optimum mix design of polymer-modified grouting mortars for prepacked concrete. Polymer-modified mortars using SBR and EVA emulsions as admixture of grouting mortars for prepacked concrete are prepared with various mix proportions such as sand-binder ratio, fly ash replacement ratio, polymer-binder ratio. and tested for flowability, viscosity of grouting mortars, bleeding ratio, expansion ratio, flexural and compressive strengths of grouting mortars and compressive and tensile strengths of prepacked concretes. From the test results, it is apparent that polymer-modified mortars can be produced as grouting mortars when proper mix design is chosen. We can design the mix proportions of high strength mortars for prepacked concrete according to the control of mix design factors such as type of polymer, polymer-binder ratio, sand-binder ratio and fly ash replacement ratio. Water-binder ratio of plain mortars for a constant flowability value are in the ranges of 43% to 50%. SBR-modified mortar has a little water-binder ratios compared to those of plain mortar, however, EVA-modified mortar needs a high water-binder ratio due to a high viscosity of polymer dispersion. The expansion and bleeding ratios of grouting mortars are also controlled in the proper value ranges. Polymer-modified grouting mortars have good flexural. compressive and tensile strengths, are not affected with various properties with increasing fly ash replacement to cement and binder-sand ratio. In this study, SBR-modified grouting mortar with a polymer-binder ratio of 10% or less, a fly ash replacement of 10% to cement and a sand-binder ratio of 1.5 is recommended as a grouting mortar for prepacked concrete.

• Advances in nano research
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• 제4권1호
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• pp.15-29
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• 2016

A low cost environmentally benign surface coating binder is highly desirable in the field of material science. In this report, castor oil based hyperbranched polyester/bitumen modified fly ash nanocomposites were fabricated to achieve the desired performance. The hyperbranched polyester resin was synthesized by a three-step one pot condensation reaction using monoglyceride of castor oil based carboxyl terminated pre-polymer and 2,2-bis (hydroxymethyl) propionic acid. Also, the bulk fly ash of paper industry waste was converted to hydrophilic nano fly ash by ultrasonication followed by transforming it to an organonano fly ash by the modification with bitumen. The synthesized polyester resin and its nanocomposites were characterized by different analytical and spectroscopic tools. The nanocomposite obtained in presence of 20 wt% styrene (with respect to polyester) was found to be more homogeneous and stable compared to nanocomposite without styrene. The performance in terms of tensile strength, impact resistance, scratch hardness, chemical resistance and thermal stability was found to be improved significantly after formation of nanocomposite compared to the pristine system after curing with bisphenol-A based epoxy and poly(amido amine). The overall results of transmission electron microscopic (TEM) analysis and performance showed good exfoliation of the nano fly ash in the polyester matrix. Thus the studied nanocomposites would open up a new avenue on development of low cost high performing surface coating materials.

• 시멘트 심포지엄
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• 18호
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• pp.40-52
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• 1990

For the development of multi-functional materials which has water reducing power, air entraining power and waterproofing power as well as a blending additive in cement mortar the low grade fly ash was modified with asphalt-stearic acid or asphalt-boiled o

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2009년도 추계학술대회 논문집
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• pp.130-132
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• 2009

• 한국농공학회논문집
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• 제54권5호
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• pp.25-34
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• 2012

It has been well known that concrete structures exposed to acid and sulfate environments such as sewer etc. show significant decrease in their durability due to chemical attack. Such deleterious acid and sulfate attacks lead to expansion and cracking in concrete, and thus, eventually result in damage to cement mortar by forming expansive hydration products due to the reaction between cement hydration products and acid and sulfate ions. In this study, the effect of fly ash and blast furnace slag on the bond performances of structural synthetic fiber in latex modified cement mortar under sulfate environments. Fly ash and blast furnace slag contents ranging from 0 % to 20 % are used in the mix proportions. The latex modified cement mortar specimens were immersed in fresh water, 8 % sodium sulfate ($Na_2SO_4$) solutions for 28 and 50 days, respectively. Pullout tests are conducted to measure the bond performance of structural synthetic fiber from latex modified cement mortar after sulfate environments exposure. Test results are found that the incorporation of fly ash and blast furnace slag can effectively enhance the PVA fiber-latex modified cement mortar interfacial bond properties (bond behavior, bond strength and interface toughness) after sulfate environments exposure. The microstructural observation confirms the findings on the interface bond mechanism drawn from the fiber pullout test results under sulfate environments.

• Geomechanics and Engineering
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• 제14권6호
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• pp.533-544
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• 2018

The importance of using materials cost effectively to enhance the strength and reduce the cost, and weight of earth fill materials in geotechnical engineering led researchers to seek for modifying the soil properties by adding proper additives. Lightweight fill materials made of soil, binder, water, and Expanded polystyrene (EPS) beads are increasingly being used in geotechnical practices. This paper primarily investigates the behavior of sandy soil, modified by EPS particles. Besides, the mechanical properties of blending sand, EPS and the binder material such as fly ash and cement were examined in different mixing ratios using a number of various laboratory studies including the Modified Standard Proctor (MSP) test, the Unconfined Compressive Strength (UCS) test, the California Bearing Ratio (CBR) test and the Direct Shear test (DST). According to the results, an increase of 0.1% of EPS results in a reduction of the density of the mixture for 10%, as well as making the mixture more ductile rather than brittle. Moreover, the compressive strength, CBR value and shear strength parameters of the mixture decreases by an increase of the EPS beads, a trend on the contrary to the increase of cement and fly ash content.

• 한국건축시공학회지
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• 제12권2호
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• pp.194-202
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• 2012

This paper predicts the cementing efficiency of fly-ash(FA) based on mortar test considering binder-water ratio and FA replacement ratio as experimental variables. The cementing efficiency prediction model proposed by statistical analysis enables us to estimate the value according to the binder-water ratio and FA replacement ratio of matrix. When FA replacement ratio is the same, the lower the binder-water ratio, the higher the estimated cementing efficiency. There are significant differences in the values according to binder-water ratio at FA replacement ratios of 15% or less, but there are almost no differences when FA replacement ratio is more than 15%. As the binder-water ratio increases, the variations in the values according to FA replacement ratio are great at FA replacement ratios of 15% or less. As the FA replacement ratios increase, the values increase for FA replacement ratios of 15% or less, but decrease for more than 15%. The values range from -0.71 to 1.24 at binder-water ratio of 1.67-2.86 and FA replacement ratio of 0-70%. The RMSE of the 28-day compressive strength predicted by modified water-cement ratio is 2.2 MPa. The values can be trusted, as there is good agreement between predicted strength and experimental strength.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.569-572
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• 2006

This study was performed to investigate the characteristics of carbonation for latex modified concrete with fly ash and blast furnace slag. The experimental variables consisted of ground granulated blast-furnace slag contents (0%, 30%, 50%), fly ash contents (0, 30%) latex contents (0, 5, 10, 15%). Two different methods of carbonation test such as $CO_2$ gas and 5% sulphuric acid digestion resistance test were varied in this study.

• Journal of Mechanical Science and Technology
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• 제15권5호
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• pp.602-612
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• 2001

The equation of the particle collection efficiency proposed by Deutsch has been modified through the various experiments to correct the errors caused by the assumptions made for the equation. In order to get an modified Deutsch equation that can be applied to real conditions, a pilot scale electrostatic precipitator is used. The effects of operational variables on the particle collection efficiency are evaluated. Particle resistivity, gas temperature, moisture contents in gas, gas velocity and particle concentration are used as the operational variables. Two different types of coal fly-ash obtained from the fluidized bed combustor and the pulverized coal combustor are used as test particulate to evaluate the effect of the physiochemical and electrical characteristics of the particle on the particle collection efficiency. The experimental results are fitted with the modified Deutsch equation made by Matts-Ohnfeldt and the extended Deutsch equation made by E. C. Potter to evaluate the effect of the particle characteristics and the operation conditions on the particle collection efficiency of the electrostatic precipitator.