• Title/Summary/Keyword: Modified adhesion

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Effect of fiber-matrix adhesion on the fracture behavior of a carbon fiber reinforced thermoplastic-modified epoxy matrix

  • Carrillo-Escalante, H.J.;Alvarez-Castillo, A.;Valadez-Gonzalez, A.;Herrera-Franco, P. J.
    • Carbon letters
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    • v.19
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    • pp.47-56
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    • 2016
  • In this study, the fracture behavior of a thermoplastic-modified epoxy resin reinforced with continuous carbon fibers for two levels of fiber-matrix adhesion was performed. A carbon fiber with commercial sizing was used and also treated with a known silane, (3-glycidoxy propyl trimethoxysilane) coupling agent. Toughness was determined using the double cantilever test, together with surface analysis after failure using scanning electron microscope. The presence of polysulfone particles improved the fracture behavior of the composite, but fiber-matrix adhesion seemed to play a very important role in the performance of the composite material. There appeared to be a synergy between the matrix modifier and the fiber-matrix adhesion coupling agent.

Comparison of Adhesion Performance According to Concrete Moisture Content of Primer Mixed with Cement and Modified Polymer (시멘트와 변성 폴리머를 혼합한 프라이머의 콘크리트 함수율에 따른 부착성능 비교)

  • Kang, Hyo-Jin;An, Ki-Won;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.231-232
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    • 2019
  • In this study, primers were prepared by mixing cement and modified polymer, and the adhesion to the substrate surface was enhanced by using cement which is the same material as the basement outer wall. The improved primer is used to verify the adhesion performance of the substrate in wet concrete environments.

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Effect of Coating Method on Properties of Polymer-Modified Paste (폴리머 시멘트 페이스트의 특성에 미치는 도포방법의 영향)

  • Joo Myung Ki;Lee Youn Su;Kim Youn Hwan;Han Jung Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.803-806
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    • 2005
  • The effect of coating method and binder content on the tensile adhesion strength, water absorption and cl- penetration depth of polymer-modified pastes using redispersible polymer powders and ceramic powder are examined. As a result, the tensile adhesion strength of the polymer-modified pastes tend to increase with increasing binder content and: number of coating. The water absorption and cl- penetration depth of the polymer-modified pastes tend to decrease with increasing binder content and number of coating.

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Metallization of Polymers Modified by Ton-Assisted Reaction (IAR)

  • J.S. Cho;Bang, Wan-Keun;Kim, K.H.;Sang Han;Y.B. Sun;S.K. Koh
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.1
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    • pp.53-59
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    • 2001
  • Surfaces of PTFE and PVDF were modified by ion-assisted reaction (IAR) in which 1 keV $Ar^{+}$ ions were irradiated on the surface of the polymer with varying ion dose in an oxygen gas environment, and Cu, Pt, Al and Ag thin films were deposited on the modified polymers. Wettability of the modified polymers was largely improved by the formation of hydrophilic groups due to chemical reaction between polymer surface and the oxygen gas during IAR. The change in wettability in the modified polymers was also related to the change in surface morphology and roughness. Adhesion between metal films and polymers modified by IAR was significantly improved, so that no detachment was possible in the $Scotch^{TM}$ tape test. The increase of adhesion strength between the metal film and the modified PVDF was mainly attributed to the formation of hydrophilic groups, which interacted with the metal film. In the case of the modified PTFE, the enhanced adhesion to metal film could be explained by the change in surface morphology together with the formation of hydrophilic groups. The electrical properties of the metal films on the modified polymers were also investigated.

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Thermal Lamination of Polyethylene Film on Aluminum by Surface Modification (표면개질을 이용한 폴리에틸렌 필름과 알루미늄간의 열융착)

  • Cho, Dong-Lyun;Yun, Ta-Song
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.594-601
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    • 2001
  • Direct thermal lamination of polyethylene film on aluminum plate without using adhesive was tried by modifying their surfaces to have polar groups. Polyethylene film was modified by treating with oxygen or acrylic acid plasma. Aluminum plate was modified by treating with boiling water or diaminocyclohexane plasma. Fairly high adhesion strength was obtained even in the case when only the polyethylene film was modified, and adhesion strength was so high that film was broken during the adhesion test if both the film and the aluminum plate were modified. Even chemical bonding seemed to be possible when the film treated with acrylic acid was laminated on the plate treated with diaminocyclohexane plasma by forming amide linkage through the reaction between COOH groups on the film surface and NH$_2$ groups on the plate surface.

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Effects of Plasma Lipoproteins on Expression of Vasular Cell Adhesion Molecule- in Human Microvasuclar Endothelial Cells (혈관내피세포에서 Vascular Cell Adhesion Molecule-1 발현에 대한 혈장 지단백의 효과)

  • 박성희
    • Journal of Nutrition and Health
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    • v.31 no.8
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    • pp.1235-1243
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    • 1998
  • Although an elevated plasma level of high density lipoprotein (HDL) is known as a protective component against the development of atherosclerosis and ensuing coronary heart diseases, the related mechanisms are still not established . It has been clearly demonstrated in the early stages of atherogenesis that adhesion of monocytes and lymphocytes to the vascular endothelium is enhanced via adhesion molecules, and that monocytes and macrophages accumulate in the subendothelial space. The present study has investigated whether isolated plasma HDL plays a role in protection against atherogenesis by inhibiting the expression of vascular cell adhesioin molecule-1(VCAM-1) on the endothelial cells. Effects of plasma native low density lipoprotein (LDL) and ac ethylated LDL(AcLDL) on VCAM-1 expression were also examined by using an immunocytochemical technique. While plasma HDL did not alter the basal expression of VCAM-1 , lipopolysaccharide(LPS) induction of this adhesion modlecule was markedly inhibited at a phyaiological concentration of HDL. In contrast, 30$\mu\textrm{g}$ protein/ml AcLDL increased sifnificantly both basal VCAM-1 expression and its LPD induction , suggesting that this modified LDL enhances leukocyte adhesiion to endothelial cells. Unlike AcLDL , plasma native LDL inhibited significantly VCAM-1 expression. This indicates that LDL did not undergo oxidative modificantion while incubated with endothelial cells. These results suggest that plasam HDL may inhibit atherogenesis by reducing the expression of adhesion molecules, which is a protective mechanism independent of tis reverse cholesterol transport function . Modified LDL is a potent iducer for adhesion molecules in vascular endothelical cells and could play a role in the pathogenesis of atherosclerosis by adhering to blood cells.

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표면특성 변화에 따른 유류분해 미생물의 토양내 거동성 조절

  • 류두현;목지예;최상일;김용미;이경애
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.360-362
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    • 2003
  • The adhesion of hydrocarbon degrading bacteria(HDB) differing in surface hydrophobicity was investigated. Cell wall hydrophobicity was modified chemically and physiologically. Modified adhesion deficient mutant of HDB was selected in a soil column assay Physiologically and chemical modification increased cell surface hydrophobicity. Cell surface charcteristis including BATH and zeta potential were measured. Physiological modification using ampicillin was not stable, but chemical modification was stabel. Hydrocarbon degrading potential was measured for modified and unmodifed HDB.

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유류분해 미생물의 표면특성에 따른 분해성 및 거동성 변화

  • 류두현;목지예;최명석;김진명;김동일;전경화;박소연
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.273-276
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    • 2004
  • The adhesion of hydrocarbon degrading bacteria(HDB) differing in surface hydrophobicity was investigated. Cell wall hydrophobicity was modified chemically and physiologically. Modified adhesion deficient mutant of HDB was selected in a soil column assay. Physiologically and chemical modification increased cell surface hydrophobicity. Cell surface characteristics including BATH and FTIR were measured. Physiological modification using ampicillin was not stable, but chemical modification was stable. Hydrocarbon degrading efficiency was measured of TPH modified and unmodifed HDB.

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A Study on Basic Properties of Grouting Motars for polymer-Modified preplaced Aggregate Concrete (프리팩트 폴리머 시멘트 콘크리트용 주입 폴리머 시멘트 모르터의 성질에 관한 연구)

  • 이철웅;김완기;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10a
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    • pp.350-355
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    • 1998
  • Preplaced aggregate concrete in the building fields has recently been used in the partial repair works for damaged reinforced concrete structures, and polymer-modified mortars have been employed as grouting mortars for the preplaced aggregate concrete. The objective of this study is to clear the properties of polymer-modified grouting mortars. Polymer-modified mortars using a polystyrene acrylic(St/Ac) emulsion as grouting mortars for preplaced aggregate concrete are prepared with various mix proportions, and tested for flexural and compressive strengths, adhesion in tension. The flexural strength of emulsion-modified grouting mortars does not give much variation with increasing fly ash replacement for cement and sand-binder ratio. With increasing polymer-binder ratio, the flexural strength and adhesion in tension of St/Ac emulsion-modified grouting mortars increases, become nearly constant or reaches a maximum at a polymer-binder ratio of 5%. From the test results, St/Ac emulsion-modified grouting mortar with a polymer-binder ratio of 5%, a fly ash replacement of 10% for cement and sand-binder ratio of 1.0 is recommended as a grouting mortar for preplaced aggregate concrete.

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A Study on Tribological Characteristics of Materials for MEMS/NEMS Using Chemically Modified AFM tip (AFM을 이용한 MEMS/NEMS 공정용 재료의 트라이볼로지 특성에 관한 연구)

  • Heo, Jung-Chul;Kim, Kwang-Seop;Kim, Kyung-Woong
    • Tribology and Lubricants
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    • v.24 no.2
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    • pp.63-71
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    • 2008
  • Friction and adhesion tests were conducted to investigate tribological characteristics of materials for MEMS/NEMS using atomic force microscope (AFM). AFM Si tips were chemically modified with a self-assembled monolayer (SAM) derived from trichlorosilane like octadecyltrichlorosilane (OTS) and (1H, 1H, 2H, 2H-perfluorooctyl) trichlorosilane (FOTS), and various materials, such as Si, Al, Au, Cu, Ti and PMMA films, were prepared for the tests. SAMs were coated on Si wafer by dipping method prior to AFM tip to determine a proper dipping time. The proper dipping time was determined from the measurements of contact angle, surface energy and thickness of the SAMs. AFM tips were then coated with SAMs by using the same coating condition. Friction and adhesion forces between the AFM Si tip modified with SAM and MEMS/NEMS materials were measured. These forces were compared to those when AFM tip was uncoated. According to the results, after coating OTS and FOTS, the friction and adhesion forces on all materials used in the tests decreased; however, the effect of SAM on the reduction of friction and adhesion forces could be changed according to counterpart materials. OTS was the most effective to reduce the friction and adhesion forces when counterpart material was Cu film. In case of FOTS, friction and adhesion forces decreased the most effectively on Au films.