• Title/Summary/Keyword: Modified PP

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Modification of Polypropylene for Improving the Laser Transmission Weldability to Polycarbonate (폴리카보네이트와의 레이저 투과 용접성 개선을 위한 폴리프로필렌 개질)

  • Kim, Dae-Jin;Jeon, Il-Ryeon;Park, Hae-Youn;Seo, Kwan-Ho
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.753-763
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    • 2013
  • Laser transmission welding of polymers is now used in a very wide range of industries due to its advantages. If the joining between polypropylene (PP) and polycarbonate (PC) occurs by laser transmission welding, the automotive headlight will get a large profit. However, PP/PC have poor miscibility. In the laser transmission welding results, the adhesion strength between PP and PC was very weak. In this study, PP was modified by grafting of glycidyl methacrylate (GMA). The adhesion strength of PC and PP-g-GMA as a reactive compatibilizer was observed. The adhesion strength was investigated by compatibility with PC, mechanical properties and laser transmission welding.

Influence of Surface Functionalized Waste Tire Ponder on the Thermal and Rheological Properties of Polypropylene/Waste Tire Powder Composite (표면기능화된 폐타이어 분말이 PP/폐타이어분말 복합체의 열 및 유변학적 성질에 미치는 영향)

  • Ryu, Sung-Hun;Shanmugharaj, A.M.;Kim, Jin-Kuk;Ryu, Sung-Hun
    • Elastomers and Composites
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    • v.41 no.1
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    • pp.49-56
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    • 2006
  • The waste tire powder is modified with allylamine in the presence of ultraviolet radiation and the influence of surface modification on the thermal and rheological properties of polypropylene/waste tire powder composites was investigated. X-ray diffraction studies of PP/waste tire powder composite without compatibilizer, such as maleic anhydride-g-polypropylene (MA-PP), shows the increase in peak intensity of ${\beta}$ crystalline peaks, whereas it completely disappears in the presence of the MA-PP. Differential scanning calorimetry results further supported the above fact. The melt viscosities and storage modulus of the composites with modified waste tire powder show higher value than that of composites with unmodified powder and it is attributed to the interaction between amine group on modified powder surface and maleic anhydride of MA-PP.

Mechanical Properties of Natural Fiber Composites by Co-polymerized Thermoplastics (공중합된 열가소성 수지에 의한 자연섬유 복합재의 기계적 물성에 관한 연구)

  • Lee, Jung-Hoon;Hwang, Byung-Sun;Byun, Joon-Hyung;Kim, Byung-Sun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.116-120
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    • 2005
  • In this study, composites with polypropylene(PP) and Jute fiber were prepared by compression molding technique. Generally, hydrophilic jute fibers do not adhere well to PP, which is hydrophobic. Maleic anhydride grafted polypropylene(MAPP) had been widely used as a coupling agent to improve the bonding between ligno-cellulosic fibers and PP. The coupling agent improved the tensile and flexural properties when the mechanical properties were tested by using a UTM. The mechanical properties of natural fiber composites(NFCs) by modified thermoplastics were higher than those of NFCs by unmodified thermoplastics. Fracture surfaces of the composites and the fiber orientations were investigated by scanning electron microscopy. The mechanical performance of NFCs by modified thermoplastics appeared to be improved by the enhanced interface adhesion between the fiber and the matrix.

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A Study on Polypropylene and Surface Modified PET Fiber Composites (표면처리된 PET 섬유와 PP 복합재료에 관한 연구)

  • Hahm, Moon-Seok;Kim, Chang-Hyeon;Ryu, Ju-Whan
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.7-12
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    • 2008
  • We confirmed that poly (ethylene terephthalate) (PET) fiber had the possibility to improve the mechanical properties of polypropylene (PP) by fabricating PP/PET fiber composites because PET enhanced mechanical properties and higher melting temperature than PP. But lower compatibility of between PP and PET fibers induced poor mechanical properties of PP/PET fiber composites in spite of incorporating PP-g-MAH as compatibilizer. To solve these problems of PP/PET fiber composites, we carried out a surface treatment on PET fiber using NaOH solution and Prepared PP/PET fiber composites with good mechanical properties by adding PP-g-MAH as a compatibilizer Then the behavior of the mechanical properties was correlated with the results obtained from SEM and IR spectroscopy.

The Evaluation of the Packaging Properties and Recyclability with Modified Acrylic Emulsion for Flexible Food Paper Coating (유연 종이 식품 포장재의 개질 아크릴 에멀젼 코팅 특성 및 재활용성 평가)

  • Myungho Lee;In Seok Cho;Dong Cheol Lee;Youn Suk Lee
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.3
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    • pp.153-161
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    • 2023
  • The worldwide effects of COVID-19 have led to a surge in online shopping and contactless services. The consumption pattern has caused the issues such as the environmental pollution together with the increase of plastic waste. Reducing the reliance on the petroleum based plastic use for the package and replacing it with environmentally friendly material are the simple ways in order to solve those problems. Paper is an eco-friendly product with high recyclability as the food packaging materials but has still poor barrier properties. A barrier coating on surface of the paper can be achieved with the proper packaging materials featuring water, gas and grease barrier. Polyethylene (PE) or polypropylene (PP) coatings which are generally laminated or coated to paper are widely used in food packaging applications to protect products from moisture and provide water or grease resistance. However, recycling of packaging containing PE or PP matrix is limited and costly because those films are difficult to degrade in the environment. This study investigated the recyclability of modified acrylic emulsion coating papers compared to PE and PP polymer matrixes as well as their mechanical and gas barrier properties. The results showed that PE or modified acrylic emulsion coated papers had better mechanical properties compared to the uncoated paper as a control. PE or PP coating papers showed strong oil resistance property, achieving a kit rating of 12. Those papers also had a significantly higher percentage of screen reject during the recycling process than modified acrylic coated paper which had a screen rejection rate of 6.25%. In addition an uncoated paper had similar value of a screen rejection rate. It may suggest that modified acrylic emulsion coating paper can be more easily recycled than PE or PP coating papers. The overall results of the study found that modified acrylic emulsion coating paper would be a viable alternative to suggest a possible solution to an environmental problem as well as enhancing the weak mechanical and poor gas barrier properties of the paper against moisture.

Effects of Planting Pattern and Plant density on Seed Production of a Modified Single Cross Corn Hybrid (파종양식과 재식밀도가 옥수수 변형단교잡종 교배친의 생육 및 채종량에 미치는 영향)

  • Park, K.Y.;Kang, Y.K.;Park, S.E.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.29 no.1
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    • pp.62-66
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    • 1984
  • One row of pollen parent to two rows of seed parent (1:2), 2:4 and solid (1:2) planting patterns (PP) were compared in seed parent densities of 3,500, 5,000 and 6,500 plants per 10 ares to determine effects of PP and plant density on growths of seed and pollen plants, and seed yield of seed parent of modified single cross corn hybrid. Planting pattern did not significantly affect agronomic characteristics of seed plant except ear number per 100 plants and seed yield which were greater in solid and 1:2 PP than in 2:4 PP. Significant PP x plant density interaction did not exist for agronomic characteristics of seed parent. In the seed parent, plant height and 100 kernel weight were not affected by plant density, but ear height, ear number per 100 plants, and kernel number per ear were linearly decreased with increased plant densities. Seed yield ranged from 330 to 460 kg per 10 ares and overall yield response to plant density was quadratic. Tassel length and spikelet number per tassel of the pollen parent were significantly affected by PP and plant density. Significant PP x plant density interaction existed for tassel length and spikelet number per tassel. Tassel length and spikelet number per tassel were greater in 1:2 and 2:4 PP compared to solid PP and were greatly reduced with increased plant densities in solid and 1:2 PP. The results indicated that 1:2 or 2:4 PP at around 5,000 plants per 10 ares for seed parent would be suitable for seed production of modified single cross com hybrid.

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A Study on the Preparation and Hydrophilization of Polypropylene Microfiltration Membrane by Radiation-Induced Graft Polymerization (방사선 중합에 의한 폴리프로필렌 정밀여과막의 제조 및 친수화 거동에 관한 연구)

  • 황택성;이선아;황의환
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.621-628
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    • 2000
  • Microporous polypropylene (PP) membranes have the high chemical and corrosion resistance, the good mechanical properties and the thermal stability under high temperatures, but its application is restricted within narrow limits due to hydrophobicity of membranes. In order to impart permanent hydrophilicity to the PP microfiltration membrane, the radiation-induced graft of 2-hydroxyethyl methacrylate (HEMA) and acrylic acid (AAc) containing hydrophilic functional group onto the membrane has been studied. The effect of graft conditions such as reaction time, total radiation dose, reaction temperatures, acid compositions on graft yield was investigated. Modified PP membranes were shown to cause an increase in the gas flux. Oil emulsion permeation flux of both original PP membrane and modified PP membrane was examined.

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Effect of succinylation on functional properties of soy protein isolate and qualities of soy bean curd (Succinyl화가 대두 단백질의 기능성과 두부의 품질에 미치는 영향)

  • 김수희
    • Journal of the Korean Home Economics Association
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    • v.28 no.4
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    • pp.41-50
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    • 1990
  • Soy protein was isolated from Korean soy bean 'Chang ryub' and chemically modified with succinic anhydride. Functionality of the soy protein isolate(SPI), succinylated SPI(SPPI), and PP590(commercial) at various pH were investigated. The mechanical and sensory properties of soy bean curds made from several mixing ratio of succinylated soy bean milk were observed. The solubility of SPI significantly increased with succinylation. The solubility of PP590 was lower than that of SSPI. The solubility of SPPI increased significantly in 0.03M CaCl2 solution. The emulsifying activity of SSPI increased. On the range of pH above pI the emulsifying activity of PP590 was higher than that of SPI. There was no difference in emulsion stability among the groups. The foam expansion capacity of SPPI increased at higher pH than pI but the foam stability decreased significantly above pH 9. Mechanical texture profile analysis revealed the modified soy bean curds had the lower hardniss, chewiness and cohesiveness with increased modification. The mechanical characteristics of modified soy bean curds revealed generalized Maxwell Model of 7-elements or 5-elements. In sensory evaluation, the hardness, the springiness and acceptability of modified soy bean curds were lower significantly than those of control soy bean curd.

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Effects of Storage Temperature and Materials on Maintenance of Quality of Solidago virgaurea spp. gigantea in Modified Atmosphere Packaging (MAP 포장재의 종류와 온도가 울릉미역취의 품질에 미치는 영향)

  • Choi, Mal-Gum;Chung, Hun-Sik;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.15 no.6
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    • pp.804-809
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    • 2008
  • Modified atmosphere packaging (MAP) was assessed in terms of extending the shelf life of Solidago virgaurea spp. gigantea. In June 2005 Solidago virgaurea spp. gigantea were harvested from Ulleung Island, packaged in $30\;{\mu}m$ PP, $30\;{\mu}m$ Antifogging-OPP, $30\;{\mu}m$ LDPE, $18\;{\mu}m$ Macroperforated-HDPE, $60\;{\mu}m$ nylon/PE, or $85\;{\mu}m$ PVC/PE film, then stored at 4, 10 or $20^{\circ}C$ for up to 14 days. The $O_2$ concentration decreased to $9{\sim}10%$ in the PP and A-OPP packaging, to $12{\sim}16%$ in LDPE packaging, and to 2% in nylon/PE and PVC/PE packaging at $10^{\circ}C$. The $CO_2$ concentration increased to 5% at $10^{\circ}C$ in PP, A-OPP and LDPE packaging, but increased consistently in the nylon/PE and PVC/PE packaging. Weight loss was markedly reduced by all MAP films except M-HDPE, and which was enhanced with decreasing storage temperature. The soluble solids and pH were not affected by the packaging material at $4^{\circ}C$ and $10^{\circ}C$, but were affected at $20^{\circ}C$. The highest score for sensory qualities (appearance, color and overall acceptability) was obtained for vegetables stored at $4^{\circ}C$ in PP films. Our results show that MAP using PP films and $4^{\circ}C$ storage can effectively maintain the quality of Solidago virgaurea spp. gigantea.

Miscibility and Bleaching of Modified Polypropylene (개질 Polypropylene의 혼화성과 표백)

  • Cho, Kyu-Min;Cho, In-Sul;Chang, Du-Sang;Lee, Eun-Woo;Kim, Oh-Nyen
    • Textile Coloration and Finishing
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    • v.10 no.6
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    • pp.33-41
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    • 1998
  • 이 연구는 염색성이 열악한 polypropylene(PP) 섬유의 염색성을 개선하기 위해 추진한 것이다. 연구목적에 따라서 PP 섬유를 개질하기 위해 1차 cellulosic유도체를 추출하고 이 유도체와 PP를 9:1의 혼합비율로 섞어 master batch를 만든 다음 master batch 17%와 PP를 blending하여 개질 PP를 만들었다. 이렇게 제조된 개질 PP는 혼합된 변성 cellulosic polymer의 영향으로 착색이 심하게 되어 있으므로 이를 표백하는 것을 이 연구의 목적으로 하였다. 연구결과 blend한 개질 PP(Grand P)의 혼화성이 우수하였고, 아염소산나트륨에 표백적성을 가지며, 표백의 최적조건은 표백제의 농도가 0.1% $NaClO_2$, 표백온도 $70^\circ{C}$, 표백시간 30분이었다.

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