• Bulletin of the Korean Chemical Society
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• 제21권9호
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• pp.860-866
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• 2000

Hydrocarbostyril, which is a key intermediate in our new synthetic route to 6-nitroquipazine, can be prepared from 1-indanone oxime by Beckmann rearrangement. We have optimized the reaction by using a Lewis acid, aluminum chloride,in the yield of 91% instead of common acids such as polyphosphoric acid,and sulfuric acid used in conventional Beckmann rearrangement (20% in the literature, 10% in our experiment).The optimized condition is established by usingthree equivalents of aluminum chloride in CH2Cl2 at -40 $^{\circ}C$ - room tempera-turefor 40 min. We have applied this condition to other 1-indanone derivatives, such as 4-methyl-, 4-methoxy-, 4-nitro and 6-nitro-1-indanones. The mechanism ofthis BR has been proposed on the basis of the effect of tem-perature and substituenton product ratio, with the aid of PM3 calculation for a model system.

• International Journal of Naval Architecture and Ocean Engineering
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• 제12권1호
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• pp.157-167
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• 2020

The purpose of this study is to analyze the relationship between the occurrence of intermediate peak and time duration, and to conduct a review for the causes of the intermediate peak. In this test, ice impact tests were conducted using a bow side shell frame and ice specimen. A total of 70 samples were manufactured. Two types of ice specimen with relatively different surface conditions were used. The criterion for dividing the two types of ice specimen was the different exposure times to room temperature after freezing. This experiment was conducted for each parameter in order to reproduce the actual icebreaking situation. As a result of the analysis, the intermediate peak in the ice load signal have been found to be caused by mechanisms by which the inner surface of broken ice contact with hull immediately after the initial hitting point of ice has been broken.

• 한국압력기기공학회 논문집
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• 제12권2호
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• pp.40-49
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• 2016

Flow accelerated corrosion (FAC) of the carbon steel piping has been a significant problem in nuclear power plants. FAC occurs under certain hydrodynamic, environmental, and material conditions, and extensive research into the factors of FAC has been conducted. The basic process of FAC is now relatively well understood; however, a full mechanistic model has not yet been established. Recently, the Korea Atomic Energy Research Institute (KAERI) has built a large experiment loop system for FAC. To produce significant experimental results using this system, the factors affecting on FAC should be analyzed quantitatively, and a model needs to be developed. In this work, a statistical modeling methodology to develop an empirical model is described in detail, and a preliminary model is suggested. Firstly, FAC data were collected from the research literature in Japan and the results of domestic experiments. The flow rate, water temperature, pH at room temperature, and the Cr content are selected as major factors, and nonlinear regression is used to find the best fit of the available data. An iterative procedure between suggesting and evaluating a model is used until an optimum model is obtained. The developed model gives the FAC rate comparable to the measured FAC rate. The developed model is going to be refined using additional laboratory data in the future.

• 한국재료학회지
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• 제30권4호
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• pp.155-159
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• 2020

Nanoporous silica aerogel insulation material is both lightweight and efficient; it has important value in the fields of aerospace, petrochemicals, electric metallurgy, shipbuilding, precision instruments, and so on. A theoretical calculation model and experimental measurement of equivalent thermal conductivity for nanoporous silica aerogel insulation material are introduced in this paper. The heat transfer characteristics and thermal insulation principle of aerogel nano are analyzed. The methods of SiO₂ aerogel production are compared. The pressure range of SiO₂ aerogel is 1Pa-atmospheric pressure; the temperature range is room temperature-900K. The pore diameter range of particle SiO₂ aerogel is about 5 to 100 nm, and the average pore diameter range of about 20 ~ 40 nm. These results show that experimental measurements are in good agreement with theoretical calculation values. For nanoporous silica aerogel insulation material, the heat transfer calculation method suitable for nanotechnology can precisely calculate the equivalent thermal conductivity of aerogel nano insulation materials. The network structure is the reason why the thermal conductivity of the aerogel is very low. Heat transfer of materials is mainly realized by convection, radiation, and heat transfer. Therefore, the thermal conductivity of the heat transfer path in aerogel can be reduced by nanotechnology.

• Journal of Biosystems Engineering
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• 제27권2호
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• pp.117-124
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• 2002

This research was conducted to develop a method to remove the effect of surface temperature of Shingo pears for sugar content measurement. Sugar content was measured by a near-infrared spectrum analysis technique. Reflected spectrum and sugar content of a pear were used for developing regression models. For the model development, reflected spectrums having wavelengths in the range of 654 to 1,052nm were used. To remove the effect of surface temperature, special sample preparation techniques and partial least square (PLS) regression models were proposed and tested. 71 Shingo pears stored in a cold storage, which had 2$^{\circ}C$ inside temperature, were taken out and left in a room temperature for a while. Temperature and reflected spectrum of each pear was measured. To increase the temperature distribution of samples, temperature and reflected spectrum of each pear was measured four times with one hour twenty minutes interval. During the experiment, temperature of pears increased up to 17 $^{\circ}C$. The total number of measured spectrum was 284. Three groups of spectrum data were formed according to temperature distribution. First group had surface temperature of 14$^{\circ}C$ and total number of 51. Second group consisted of the first and the fourth experiment data which contained the minimum and the maximum temperatures. Third group consisted of 155 data with normal temperature-distribution. The rest data set were used for model evaluation. Results shelved that PLS model I, which was developed by using the first data group, was inadequate for measuring sugar content of pears which had different surface temperatures from 14$^{\circ}C$. After temperature compensation, sugar content predictions became close to the measured values. Since using many data which had wide range of surface temperatures, PLS model II and III were able to predict sugar content of pears without additional temperature compensation. PLS model IV, which included the surface temperatures as an independent variable. showed slightly improved performance(R$^2$=0.73). Performance of the model could be enhanced by using samples with more wide range of temperatures and sugar contents.

• Nuclear Engineering and Technology
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• 제52권6호
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• pp.1120-1130
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• 2020

The CREOLE experiment performed In the EOLE critical facility located In the Nuclear Center of CADARACHE - CEA have allowed us to get interesting and complete experimental information on the temperature effects in the light water reactor lattices. To analyze these experiments with accuracy an elaborate calculation scheme using the Monte Carlo method implemented in the MCNP6.1 code and the ENDF/B-VII.1 cross section library has been developed. We have used the ENDF/B-VII.1 data provided with the MCNP6.1.1 version in ACE format and the Makxsf utility to handle the data in the specific temperatures not available in the MCNP6.1.1 original library. The main purpose of this analysis is the qualification of the ENDF/B-VII.1 nuclear data for the prediction of the Reactivity Temperature Coefficient while ensuring the ability of the MCNP6.1 system to model such a complex experiment as CREOLE. We have analyzed the case of UO₂ lattice with 1166 ppm of boron in ordinary water moderator in specified temperatures. A detailed comparison of the calculated effective multiplication factors with the reference ones [1] in room temperature presented in this work shows a good agreement demonstrating the validation of our 3D calculation model. The discrepancies between calculations and the differential measurements of the Reactivity Temperature Coefficient for the analyzed configuration are relatively small: the maximum discrepancy doesn't exceed 1,1 pcm/℃. In addition to the analysis of direct differential measurements of the reactivity temperature coefficient performed in the poisoned UO₂ lattice configuration, we have also analyzed integral measurements in UO₂ clean lattice configuration using equivalency of the integral temperature reactivity worth with the driver core fuel reactivity worth and soluble boron reactivity worth. In this case both of the ENDF/B-VII.1 and JENDL.4 libraries were used in our analysis and the obtained results are very similar.

• 대한기계학회논문집A
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• 제34권10호
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• pp.1377-1384
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• 2010

본 논문에서는 솔더 재료 중에서 가장 많이 사용되어 온 Sn37Pb 솔더에 대한 변형거동을 가장 정확히 나타낼 수 있는 재료 모델을 결정하기 위한 방법을 연구하였다. 이를 위해 실제 전자패키지와 유사한 변형 거동을 보이는 시편을 제작하였고 상온에서 $125^{\circ}C$ 까지의 열 사이클 하에서 모아레 간섭계를이용하여 변형을 측정하는 실험을 수행하였다. Sn37Pb 솔더에 대해 세 가지 서로 다른 구성방정식을 적용하여 시편에 대한 유한요소해석을 수행하였다. 실험 결과 나타난 시편의 굽힘 변형과 해석 결과나타난 굽힘 변형을 비교하였고, 세 가지 재료모델의 계수를 미지수로 놓고 최적설계 기법을 적용하여 유한요소 해석과 실험 결과가 최대한 일치하는 계수 값을 결정하였다. 이를 통해 Anand 에 의해 제안된 구성방정식이 솔더의 거동을 가장 잘 표현한다고 결론을 낼 수 있었다.

• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1264-1264
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• 2001

The affect of surface temperatures of fruits on spectrum which measures actual sugar contents was observed. PLSR was applied to develop the sugar content evaluation system that was not affected by temperature. The reflected spectrum was used at the wavelengths of 654 and 1052nm with the separation distance of 2.5nm. To increase the conformance of a model using unknown samples, let the minimum value of PRESS be an optimum factor. 71 Shingo pears stored in a refrigerator were left in a room temperature for a while and these temperatures and reflected spectrums were measured. Reflected spectrums were measured at the wavelengths of 654 and 1052nm, 3 samples in one second. To measure these at different temperatures, the experiment was repeated hourly and four times. Starting temperatures of 2-3 were increased up to 17. The total number of measured spectrum was 284. To develop a sugar content evaluation system model using measured reflected spectrum, three groups of samples were considered. First group had 51 samples at 14 and second group had 141 samples with lower or higher temperatures than 14. Third group had 155 samples with well distributed temperatures. Other samples were used as validations to ensure the conformance. Measuring the sugar contents of samples with surface temperatures other than 14 were difficult with PLS model I, developed by using a sample temperature of 14. If the sugar contents were compensated using samples' temperatures, results of prediction would be close to the expected results and it would be one of the most important factors to develop this system. PLS models I and II could compensate the temperature but the precision would not come up to the standard. High precision was expected by using samples with wide ranges of temperatures and sugar contents. Both models showed the possibility of an improvement of a sugar content evaluation system disregarding the temperature. For practical use of a system, selecting samples should be done carefully to reduce the effect of the temperature.

• 대한조선학회논문집
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• 제49권3호
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• pp.232-238
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• 2012

The effects of temperature on the structural behavior of polar class vessels have been experimentally and numerically investigated. Experiments were carried out on single frame structures made of steel material, DH36, which is used for outer shell of the vessels making transit through the polar region. A knife edge type striker was dropped down onto single frame structures. The temperatures of the single frames were set to $-30^{\circ}C$, $-50^{\circ}C$ and room temperature. The deflection around the mid-point of the single frame was measured and numerically simulated using finite element model. Strain rate effect on the structural behavior has been investigated and turned out that the strain rate effect can be neglected. From the results of the experiment and numerical analyses, it has been noticed that the permanent deflection at lower temperature was reduced due to a temperature hardening of material as expected.

• 품질경영학회지
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• 제39권3호
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• pp.365-376
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• 2011

Robust design (RD) has emerged as a key feature in process design and development for more than twenty years. Many researchers and industrial engineers around the world have invested their intensive efforts to develop and apply RD in many fields in order to improve quality of output products. However, there is also room for improvement. The primary objective of this research is to determine "robust formulation" of a medicine by checking its gelation index. In order to achieve this target, based on the nature of problem, at first, a customized experimental format is designed for obtaining data. Second, time-depended responses based models are developed by the proposed inverse problem (IP) methodology. Third, an RD model based on mean square error (MSE) concept is introduced for time-depended responses. Finally, the proposed approach is illustrated by a case study while comparing obtained results to the response surface methodology (RSM) approach.