• Membrane and Water Treatment
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• v.3 no.2
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• pp.77-98
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• 2012

A two-dimensional (2D) steady state numerical model of concentration polarisation (CP) phenomena in a membrane channel has been developed using the commercially available computational fluid dynamics (CFD) package CFX (Ansys, Inc., USA). The model incorporates the transmembrane pressure (TMP), axially variable permeate flux, variable diffusivity and viscosity, and osmotic pressure effects. The model has been verified against several benchmark analytical and empirical solutions from the membrane literature. Additionally, the model is able to predict the rejection of an arbitrary solute by the membrane using a pore model, given some basic knowledge of the geometry of the solute molecule or particle, and the membrane pore geometry. This allows for predictive design of membrane systems without experimental determination of the membrane rejection for the specified operating conditions. A demonstration of the model is presented against experimental results for two uncharged test compounds (sucrose and PEG1000) from the literature. The model will be extended to incorporate charge effects, transient simulations, three-dimensional (3D) geometry and turbulent effects in future work.

• Journal of Korean Society of Water and Wastewater
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• v.27 no.1
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• pp.139-146
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• 2013

A process diagnosis method for membrane water treatment plant was developed using a constant flux membrane fouling model. This diagnosis method can be applied to a real-field membrane-based water treatment plant as an early alarming system for membrane fouling. The constant flux membrane fouling model was based on the simplest equation form to describe change in trans-membrane pressure (TMP) during the filtration cycle from a literature. The model was verified using a pilot-scale microfiltraton (MF) plant with two commercial MF membrane modules (72 m2 of membrane area). The predicted TMP data were produced using the model, where the modeling parameters were obtained by the least square method using the early plant data and modeling equations. The diagnosis was carried out by comparing the predicted TMP data (as baseline) and real plant data. As a result of the case study, the diagnsis method worked pretty well to predict the early points where fouling started to occur.

• Membrane and Water Treatment
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• v.12 no.1
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• pp.23-35
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• 2021

A POM-membrane was fabricated by immobilizing a keggin type polyoxometalate (POM) H5PV2Mo10O40 onto the surface of microporous flat-sheet polymeric polyvinylidene fluoride (PVFD) membrane using a chemical deposition method. The POM-membrane was characterized by FT-IR, SEM and EDX to confirm existing of the POM onto the membrane surface. The POM-membrane was used to remove an anionic textile dye (Reactive Black 5 named as an RB5) from aqueous phases with a cross-flow membrane filtration and a batch adsorption system. The dye removal efficiency of the POM-membrane using the cross-flow membrane filtration system and the batch adsorption system was about 88% and 98%, respectively. The influence factors such as contact time, adsorbent dosage, pH, and initial dye concentration were investigated to understand the adsorption mechanism of the RB5 dye onto the POM-membrane. To find the best fitting isotherm model, Langmuir, Freundlich, BET and Harkins-Jura isotherm models were used to analyze the experimental data. The isotherm analysis showed that the Langmuir isotherm model was found to the best fit for the adsorption data (R2 = 0.9982, qmax = 24.87 mg/g). Also, adsorption kinetic models showed the pseudo second order kinetic model was found the best model to fit the experimental data (R2 = 0.9989, q = 8.29 mg/g, C0 = 15 ppm). Moreover, after four times regeneration with HNO3 acid, the POM-membrane showed high regenerability without losing dye adsorption capacity.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.5
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• pp.632-638
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• 2005

Membrane fouling index such as Silt Density Index (SDI) and Modified Fouling Index (MFI) is an important parameter in design of the integrated RO/NF membrane processes for drinking water treatment. In this study, the effect of particle, membrane and feed water characteristics on membrane fouling index were investigated systematically. Higher fouling index values were observed when filtering suspensions with smaller particle size and higher feed particle concentration. Larger membrane resistance due to smaller pore size resulted in an increased membrane fouling index. The variations of feed water hardness and TDS concentrations did not show any impact on fouling index, suggesting that there were no significant colloidal interactions among particles and thus the porosity of particle cake layer accumulated on the membrane surface could be assumed to be 0.36 according to random packing density. Based on the experimental observations, fundamental membrane fouling index model was developed using Happel Cell. The effect of primary model parameters including particle size ($a_p$), particle concentration ($C_o$), membrane resistance ($R_m$), were accurately assessed without any fitting parameters, and the prediction of membrane fouling index such as MFI exhibited very good agreement with the experimental results.

• Membrane Journal
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• v.14 no.1
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• pp.75-84
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• 2004

In this study, we present a noble study far membrane transport models using chlorine resistance of polyamide RO membranes. Membrane transport mechanism is investigated by the comparison of membrane permeation performance under the continuous and Intermittent operation modes with mixed feed solution containing NaOCl and NaCl. Analysis of permeation performance indicates that solution-diffusion model and preferential adsorption-capillary flow model are relatively efficient according to operation mode. Under the continuous flow state, mass transfer depends on preferential adsorption-capillary flow model rather than solution-diffusion model. On the other hand, it prefers solution-diffusion model to preferential adsorption-capillary flow model under the stationary state. SEM images of NaOCl treated membrane surfaces strongly support these conclusions. These surface images reveal that NaOCl treated membrane in continuous operation mode exhibits ridge and valley structure in some fraction of the surface area, whereas that in intermittent operation mode shows surface degradation entirely.

• Computers and Concrete
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• v.3 no.6
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• pp.439-454
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• 2006

This paper develops an artificial neural network (ANN) model for uniformly loaded restrained reinforced concrete (RC) slabs incorporating membrane action. The development of membrane action in RC slabs restrained against lateral displacements at the edges in buildings and bridge structures significantly increases their load carrying capacity. The benefits of compressive membrane action are usually not taken into account in currently available design methods based on yield-line theory. By extending the existing knowledge of compressive membrane action, it is possible to design slabs in building and bridge decks economically with less than normal reinforcement. The processes involved in the development of ANN model such as the creation of a database of test results from previous research studies, the selection of architecture of the network from extensive trial and error procedure, and the training and performance validation of the model are presented. The ANN model was found to predict accurately the ultimate strength of fully restrained RC slabs. The model also was able to incorporate strength enhancement of RC slabs due to membrane action as confirmed from a comparative study of experimental and yield line-based predictions. Practical applications of the developed ANN model in the design process of RC slabs are also highlighted.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.8
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• pp.596-603
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• 2009

The performance of proton exchange membrane fuel cell (PEMFC) is seriously changed by the humidification condition which is intrinsic characteristics of the PEMFC. Typically, the humidification of fuel cell is carried out with internal or external humidifier. A membrane humidifier is applied to the external humidification of residential power generation fuel cell due to its convenience and high performance. In this study, a simple static model is constructed to understand the physical phenomena of the membrane humidifier in terms of geometric parameters and operating parameters. The model utilizes the concept of shell and tube heat exchanger but the model is also able to estimate the mass transport through the membrane. Model is constructed with FORTRAN under Matlab/$Simulink^{(R)}$ $\Box$environment to keep consistency with other components model which we already developed. Results shows that the humidity of wet gas and membrane thickness are critical parameters to improve the performance of the humidifier.

• Wind and Structures
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• v.36 no.2
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• pp.133-147
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• 2023

The random vibration of saddle membrane structures under wind load is studied theoretically and experimentally. First, the nonlinear random vibration differential equations of saddle membrane structures under wind loads are established based on von Karman's large deflection theory, thin shell theory and potential flow theory. The probabilistic density function (PDF) and its corresponding statistical parameters of the displacement response of membrane structure are obtained by using the diffusion process theory and the Fokker Planck Kolmogorov equation method (FPK) to solve the equation. Furthermore, a wind tunnel test is carried out to obtain the displacement time history data of the test model under wind load, and the statistical characteristics of the displacement time history of the prototype model are obtained by similarity theory and probability statistics method. Finally, the rationality of the theoretical model is verified by comparing the experimental model with the theoretical model. The results show that the theoretical model agrees with the experimental model, and the random vibration response can be effectively reduced by increasing the initial pretension force and the rise-span ratio within a certain range. The research methods can provide a theoretical reference for the random vibration of the membrane structure, and also be the foundation of structural reliability of membrane structure based on wind-induced response.

• Membrane and Water Treatment
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• v.7 no.2
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• pp.87-100
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• 2016

A numerical simulation of membrane evaporation process was carried out in this work. The aim of simulation is to describe transport of water through porous membranes applicable to the concentration of aqueous solutions. A three-dimensional mathematical model was developed which considers transport phenomena including mass, heat, and momentum transfer in membrane evaporation process. The equations of model were then solved numerically using finite element method. The results of simulation in terms of evaporation flux were compared with experimental data, and confirmed the accuracy of model. Moreover, profile of pressure, concentration, and heat flux were obtained and analyzed. The results revealed that developed 3D model is capable of predicting performance of membrane evaporators in concentration of aqueous solutions.

• Membrane and Water Treatment
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• v.2 no.4
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• pp.225-237
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• 2011

In this study, response of reversibility of membrane flux during chemically enhanced backwash (CEB) to changes in filtration time, filtration flux and coagulant concentration dosing during ultrafiltration (UF) process was investigated using a regression model. The model was developed via empirical modelling approach using response surface methodology. In developing the model, statistically designed UF experiments were conducted and the results compared with the model output. The results showed that the performance of CEB, evaluated in terms of the reversibility of the membrane flux, depends strongly on the changes in coagulant concentration dosage and the filtration flux. Also the response of the reversibility of membrane flux during CEB is independent of the filtration time. The variance ratio, VR << $F_{value}$ and $R^2$ = 0.98 obtained from the cross-validation experiments indicate perfect agreement of the model output with experimental results and also testify to the validity and suitability of the model to predict reversibility of the membrane flux during CEB in UF operation.