• Title/Summary/Keyword: Model compound

Search Result 870, Processing Time 0.028 seconds

Finite Element Analysis of Powdering of Hot-dip Galvannenled Steel using Damage Model (합금화 용융아연 도금강판의 가공시 손상모델을 이용한 도금층 파우더링에 관한 유한요소 해석)

  • Kim, D.W.;Kim, S.I.;Jang, Y.C.;Lee, Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
    • /
    • 2007.10a
    • /
    • pp.215-222
    • /
    • 2007
  • Coating of Hot-dip galvannealed steel consists of various Fe-Zn intermetallic compounds. Since the coating is hard and there for is very brittle, the surface of steel sheet is easy to be ruptured during second manufacturing processing. This is called as powdering. In addition, forming equipment might be polluted with debris by powdering. Therefore, various research have been carried out to prohibit powdering fur improving the quality of GA steel. This paper carried out finite element analysis combined with damage model which simulate the failure of local layer of hot-dip galvannealed steel surface during v-bending test. Since the mechanical property of intermetallic compound was unknown exactly, we used the properties calculated from measurements. The specimen was divided into substrate, coating layer and interface layer. Local failure at coating layer or interface layer was simulated when elemental strain reached a prescribed strain.

  • PDF

A Calculation of C-V Characteristics for ${Hg}_{1-x}{Cd}_{x}$Te MIS Device (${Hg}_{1-x}{Cd}_{x}$Te MIS 소자의 C-V 특성 계산)

  • 이상돈;김봉흡;강형부
    • The Transactions of the Korean Institute of Electrical Engineers
    • /
    • v.43 no.3
    • /
    • pp.420-431
    • /
    • 1994
  • The HgCdTe material, which is II-VI compound semiconductor, is important materials for the fabrication of the infrared detectros. To suggest the model of accurate MIS C-V calculation for narrow band gap semiconductors such as HgCdTe, non-parabolicity from k.p theory and degeneracy effect are considered. And partially ionized effect and compensation effect which are material's properties are also considerd. Especially, degenerated material C-V characteristics from Fermi-Dirac statistics and exact charge theory are presented to get more accurate analysis of the experimental results. Also the comparison with calculation results between the general MIS theory from Boltzmann appoximation method and this model which is considered the narrow band gap semiconductor properties, show that this model is more useful theory to determination of accurate low and high frequency C-V characteristics.

  • PDF

Turbine Design for Turbo-compound System to Recover Exhaust Gas Energy Using 1-D Mean Line Flow Model (1-D Mean Line Flow Model을 이용한 엔진 배기에너지 회수를 위한 터보컴파운드 시스템용 터빈 설계)

  • Jang, Jinyoung;Yun, Jeong-Eui
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.24 no.1
    • /
    • pp.74-81
    • /
    • 2016
  • The aim of this study was to find the initial design value of turbine blade for electrical type turbocompound system generating 10 kW. Turbocompound is one of the waste heat recovery system applying to internal combustion engine to recover exhaust gas energy that was about 30 % of total input energy. To design the turbine blade, 1-D mean line flow model was used. Exhaust gas temperature, pressure, flow rate and turbine rotating speed was fixed as primary boundary conditions. The velocity triangles was defined and used to determine the rotor inlet radius and width, the rotor outlet radius at shroud and radius at hub, the rotor flow angles and the number of blades.

Estimation of Bioconcentration Factors in Fish for Organic Nonelectrolytes Using the Linear Solvation Energy Relationship

  • Jung Hag Park;Eun Hee Cho
    • Bulletin of the Korean Chemical Society
    • /
    • v.14 no.4
    • /
    • pp.457-461
    • /
    • 1993
  • Bioconcentration factors (BCF) in fish of organic nonelectrolytes are well correlated by a linear solvation energy relationship (LSER) of the form : log BCF= -0.95 + 4.74 $V_I/100 - 4.39{\beta} + 0.88{\alpha}$ where $V_I$ is the intrinsic solute molecular volume and ${\beta}$ and ${\alpha}$ are the solvatochromic parameters that measure hydrogen bond acceptor basicity and donor acidity of the compound. The LSER model can not only correlate the property with an accuracy comparable to molecular connectivity model but also provide a quantitative informationon on the nature and relative strength of solute-target system interactions affecting the property of interest. Such an information can hardly be obtained from molecular connectivity model.

Isolation and Identification of Antioxidant Substances from the Stems of Butterbur (Petasites japonicus) (머위(Petasites japonicus) 엽병으로부터 항산화 물질의 분리 및 동정)

  • Kim, Min-Young;Yi, Jung-Hyun;Hwang, Yun-Yi;Song, Kyung-Sik;Jun, Mi-Ra
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.37 no.8
    • /
    • pp.979-984
    • /
    • 2008
  • The stems of P etasites japonicus were extracted with ethanol and then partitioned with hexane, chloroform, ethyl acetate, n-butanol and water, successively. The antioxidant potency of five crude fractions were determined using (1) 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging assay, (2) thiobarbituric acid reactive substances (TBARS) assay in the linoleic acid model system, and (3) lipoxygenase inhibition assay. Among the crude fractions, the ethyl acetate fraction exhibited the most potent antioxidant effect. By activity-guided fractionation, compound PJ-4 was isolated from the ethyl acetate fraction through the repeated silica gel open column chromatography. The chemical structure of the isolated compound was determined as kaempferol by $^1H-$ and $^{13}C$-NMR analysis and its antioxidative capacity was further investigated. DPPH radical scavenging activity of the compound was 65.76% at the concentration of $100 \;{\mu}g/mL$. The inhibitory activity of the compound against lipid peroxidation and lipoxygenase exhibited 43.47% and 58.60%, respectively at the concentration of $100\;{\mu}g/mL$. The result suggests that the compound may serve as a useful natural antioxidant and furthermore indicates the possibility of developing the stems of Petasites japonicus as a natural antioxidant source.

Effects of coal devolatilization model and turbulent reaction rate in numerical simulations of a large-scale pulverized-coal-fired boiler (상용 미분탄 보일러 연소해석에서 석탄 탈휘발 모델 및 난류반응속도의 영향 평가)

  • Yang, JooHyang;Kim, Jung-en A.;Ryu, Changkook
    • 한국연소학회:학술대회논문집
    • /
    • 2014.11a
    • /
    • pp.59-62
    • /
    • 2014
  • Predicting coal combustion by computational fluid dynamics (CFD) requires a combination of complicated flow and reaction models for turbulence, radiation, particle flows, heterogeneous combustion, and gaseous reactions. There are various levels of models available for each of the phenomena, but the use of advanced models are significantly restricted in a large-scale boiler due to the computational costs and the balance of accuracy between adopted models. In this study, the influence of coal devolatilization model and turbulent mixing rate was assessed in CFD for a commercial boiler at 500 MWe capacity. For coal devolatilization, two models were compared: i) a simple model assuming single volatile compound based on proximate analysis and ii) advanced model of FLASHCHAIN with multiple volatile species. It was found out that the influence of the model was observed near the flames but the overall gas temperature and heat transfer rate to the boiler were very similar. The devolatilization rate was found not significant since the difference in near-flame temperature became noticeable when it was multiplied by 10 or 0.1. In contrast, the influence of turbulent mixing rate (constant A in the Magnussen model) was found very large. Considering the heat transfer rate and flame temperature, a value of 1.0 was recommended for the rate constant.

  • PDF

F.E. Analysis of the Radial Tire Inflation Using the Hyperelastic Properties of Rubber Compounds Sampled from a Tire (타이어 고무배합물의 초탄성을 고려한 레이디얼 타이어의 팽창에 관한 유한요소해석)

  • 김용우;김종국
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.11 no.4
    • /
    • pp.125-134
    • /
    • 2003
  • In this study, Mooney-Rivlin 1st model and Mooney-Rivlin 3rd model are adopted as strain energy density functions of the rubber compounds of a radial tire. It is shown that the FE analysis using Mooney-Rivlin models for rubber compounds may provide good approximations by employing the appropriate strain range of experimental stress-strain data in a way to describe the stress-strain relationship accurately. Especially, Mooney-Rivlin 3rd model gives an accurate stress-strain relationship regardless of the fitting strain range used within the strain of 100%. The static nonlinear FE analysis of a tire inflation is performed by employing an axisymmetric model, which shows that the outside shapes of the tire before and after inflating the tire agree well with those of the real tire. Additionally, the deformations at crown center and turning point on sidewall, distribution of belt cord force, interlaminar shear strain are predicted in terms of variation of belt cord angle which is known as the most influential factor in inflation behavior of a tire.

Thermal Model for Power Converters Based on Thermal Impedance

  • Xu, Yang;Chen, Hao;Lv, Sen;Huang, Feifei;Hu, Zhentao
    • Journal of Power Electronics
    • /
    • v.13 no.6
    • /
    • pp.1080-1089
    • /
    • 2013
  • In this paper, the superposition principle of a heat sink temperature rise is verified based on the mathematical model of a plate-fin heat sink with two mounted heat sources. According to this, the distributed coupling thermal impedance matrix for a heat sink with multiple devices is present, and the equations for calculating the device transient junction temperatures are given. Then methods to extract the heat sink thermal impedance matrix and to measure the Epoxy Molding Compound (EMC) surface temperature of the power Metal Oxide Semiconductor Field Effect Transistor (MOSFET) instead of the junction temperature or device case temperature are proposed. The new thermal impedance model for the power converters in Switched Reluctance Motor (SRM) drivers is implemented in MATLAB/Simulink. The obtained simulation results are validated with experimental results. Compared with the Finite Element Method (FEM) thermal model and the traditional thermal impedance model, the proposed thermal model can provide a high simulation speed with a high accuracy. Finally, the temperature rise distributions of a power converter with two control strategies, the maximum junction temperature rise, the transient temperature rise characteristics, and the thermal coupling effect are discussed.

In silico High-Throughput Screening by Hierarchical Chemical DB Search by 3D Pharmacophore Model

  • Shin, Jae-Min
    • Proceedings of the PSK Conference
    • /
    • 2002.10a
    • /
    • pp.181-182
    • /
    • 2002
  • Recentadvancesin '-omics ' technologies enable us to discover more diverse disease- relevant target proteins, which encourages us to find out more target-specific novel lead compounds as new drug candidates. Therefore, high-throughput screening (HTS) becomes an essential tool in this area. Among many HTS tools, in silico HTS is a very fast and cost-effective tool to try to derive a new lead compound for any new targets, especially when the target protein structures are known or readily modeled. (omitted)

  • PDF

The Chiroptical Properties and Absolute Configuration of 28-nor-$\beta$-amyrins

  • Woo, Won-Sick
    • Archives of Pharmacal Research
    • /
    • v.14 no.2
    • /
    • pp.160-164
    • /
    • 1991
  • The existence in nature of two isomers of 28-nortriterpenes is known. One is normal D/E cis form and the other is $17\alpha$-hydrogen D/E trans form. Since the latter cannot exist with ring D in the chair conformation, the chiroptical method is not applicable to determination of the absolute configuration. The stereochemical assignment would now be made by NMR data. Confirmation of this view could be provided by the synthesis of $3\beta, 21\beta-{dihydroxy-16-keto-28-nor-17}\alpha, \;18\beta-{olean-12-ene}$ as a model compound.

  • PDF