• 제목/요약/키워드: Mo addition

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Paste의 조성과 입도 변화가 알루미나 세라믹스의 Metallizing에 미치는 영향에 관한 연구 (The Effect of Paste Composition and Particle Size on the Alumina Ceramics Metallizing)

  • 김태송;김성태;김종희
    • 한국세라믹학회지
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    • 제30권5호
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    • pp.347-356
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    • 1993
  • In joining alumina ceramics to metal by using Mo-Mn metallizing process the effects of metallizing thickness, temperature, and the composition of paste on the bond strength and the microstructure of joining interface were investigated. The bond strength variation in the range of metallizing temperature, 1350~155$0^{\circ}C$ was more than 150MPa above 145$0^{\circ}C$ and the optimum metallizing thickness was 30${\mu}{\textrm}{m}$. The optimum contents of Mn in Mo-Mn paste was 5% due to the bond strength decrease with the increase of addition. The effect of SiO2 addition in paste on bond strength was saturated around 200MPa. It was also observed that as the particle size of Mo decreased, the joinning with higher bond strength was shown in spite of low metallizing temperature.

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저 열팽창 주철의 경도향상 및 선팽창계수에 미치는 탄화물 형성원소의 영향 (Effect of Carbide Forming Elements on Hardness and Linear Thermal Expansion Coefficient of Low Thermal Expansive Cast Irons)

  • 문병문;홍준표
    • 한국주조공학회지
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    • 제17권1호
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    • pp.36-50
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    • 1997
  • Invar-type austenitic cast irons are being used as low thermal expansive materials because of its good low thermal expansion characteristics and castability despite its low hardness. The effects of alloying elements such as Cr, Ti, V, and Mo on hardness and linear thermal expansion coefficient of the invar-type austenitic cast irons were investigated. A combined use of V and Mo addition was found to be the most effective for the improvement of hardness without causing an increase in the thermal expansion coefficient. With a combined addition of 4.6wt%V and 3.8wt%Mo, the hardness increased up to 180HB and the thermal expansion coefficient was kept at a relatively low value of $4.6{\times}10^{-6}/^{\circ}C$ in the temperature range from room to $250^{\circ}C$.

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송전선 강심용 고장도 인하합금의 Mo 첨가의 영향 (Effect of Mo Addition of High-Strength Invar Alloy for Core of Transmission Line)

  • 김봉서;유경재;김병걸;이희웅
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 추계학술대회 논문집 학회본부 C
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    • pp.891-893
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    • 1999
  • Invar alloys have characteristics with very low thermal expansion coefficient and low tensile strength. The mechanical properties of invar alloy have to being improved to apply for structural materials, especially for core of transmission line in electrical field. It is necessary low thermal expansion and high strength core material to transmit increased current capacity. In this paper, we investigated effect of Mo addition affected to thermal and mechanical properties and microstructure in Fe-Ni-Co ternary system.

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Thermal Compatibility of High Density U-Mo Powder Fuels Prepared by Centrifugal Atomization

  • Kim, Ki-Hwan;Ahn, Hyun-Suk;Chang, Se-Jung;Ko, Young-Mo;Lee, Don-Bae;Kim, Chang-Kyu;Kuk, Il-Hyun
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1997년도 춘계학술발표회논문집(2)
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    • pp.165-170
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    • 1997
  • Samples of extruded dispersions of 24 vol.% spherical U-2wt%Mo and U-10wt.%Mo powders in an aluminum matrix were annealed for over 2,000 hours at 40$0^{\circ}C$. No significant dimensional changes occurred in the U-1025.%Mo/aluminum dispersions. The U-2wt.%Mo/aluminum dispersion, however, increased in volume by 26% after 2,000 hours at 40$0^{\circ}C$. This large volume change is mainly due to the formation of voids and cracks resulting from nearly complete interdiffusion of U-Mo and aluminum. Interdiffusion between U-10wt.%Mo and aluminum was found to be minimal. The different diffusion behavior is primarily due to the fact that U-2wt.%Mo decomposes from an as-atomized metastable r-phase(bcc) solid solution into the equilibrium r-U and U$_2$Mo two-phase structure during the experiment, whereas U-10wt.%Mo retains the metastable r-phase structure after the 2,000 hours anneal and thereby displays superior thermal compatibility with aluminum compared to U-2wt.%Mo. In addition, the molybdenium supersaturated in U-10wt.%Mo particles inhibits the diffusion of aluminum atoms along the grain boundary into the particle. Also, the dissolution of only a few Mo atoms in UAL$_3$ retards the formation of the intermediate phase, as Mo atoms need to migrate from new intermetallic compounds to unreacted islands.

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Ni을 첨가한 $MoSi_2$분말성형체의 소결시 치밀화거동의 관찰 (Observation of Densification Behavior during the Sintering of Ni-added $MoSi_2$ Powder Compacts)

  • 이승익
    • 한국분말재료학회지
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    • 제4권4호
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    • pp.298-303
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    • 1997
  • The activated sintering behavior of $MoSi_2$ powder compacts with addition of 0.5 and 1.0 wt.%Ni during the sintering under As atmosphere was studied. The shrinkage was measured and the microstructures were observed by SEM (scanning electron microscopy) and BEI (backscattered electron image) along with the phase analysis by EDS during heating up to 155$0^{\circ}C$ and holding for various time at 155$0^{\circ}C$. The most of shrinkage occurred upon heating and 92% of theoretical density was attained after sintering for 1 hr at 155$0^{\circ}C$. However, little shrinkage ensued even for prolonged sintering over 1 hr at 155$0^{\circ}C$. A liquid film formed at about 135$0^{\circ}C$ along necks and grain boundaries. The polyhedral grain structure composed of $(Mo,Ni)_5Si_3$and $Ni_2Si$ across the $MoSi_2$ grain boundary developed at 155$0^{\circ}C$. It was concluded that the activated sintering of $MoSi_2$ powder by Ni led to the diffusion of Si into Ni decreasing the liquidus temperature and the enhanced diffusion of Mo and Si through such a liquid phase and/or interboundary of $(Mo,Ni)_5Si_3$.

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오스템퍼드 구상흑연주철의 파괴특성에 미치는 Ni의 영향에 관한 연구 (Effect of Ni on the Mechanical Properties and Fracture Characteristics of Austempered Ductile Iron)

  • 백상호;김홍범;김창규;최창옥
    • 한국주조공학회지
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    • 제14권1호
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    • pp.52-61
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    • 1994
  • The effect of Ni addition, on the mechanical properties and fracture characteristics of Mo-Cu and Mo-Ni-Cu alloyed ductile iron austenitized at $900^{\circ}C$ and austempering temperatures of $250^{\circ}C$, $300^{\circ}C$ and $350^{\circ}C$. The tensile strength, yield strength and hardness are decreased and elongation and impact value are increased in both Mo-Cu and Mo-Ni-Cu alloyed austempered ductile iron, with increased austempering temperature. According to the austempering temperature are increased, the amount of retained austenite are increased. Maximum value of fracture toughness is obtained at $350^{\circ}C$ austempering temperature at this condition, the amount of retained austenite came to 40% in Mo-Ni-Cu alloyed ADI and 34% in Mo-Cu alloyed ADI. The fracture surface of ADI which had represented high toughness are showed a quasi-cleavage pattern and a dimple pattern with micro void. Comparing the fracture characteristics of Mo-Cu alloyed ADI with that of Mo-Ni-Cu alloyed ADI, the latter was superior to the former.

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