• Title/Summary/Keyword: Mo(110)

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Ultrasonic Nondestructive Evaluation of Microstructural Degradation in Artificially Aging Heat Treated 2.25CrMo Steel (인공 열화 열처리된 2.25CrMo 강의 미세조직 변화에 대한 초음파 비파괴평가)

  • Byeon, Jai Won;Kwun, S.I.;Park, Un-Su;Park, Ik-Keun
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.2
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    • pp.110-117
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    • 2001
  • Artificial aging was performed to simulate the microstructural degradation in 2.25CrMo steel arising from long time exposure at $540^{\circ}C$. It was found that the carbides became coarser and spheroidized as aging time increased. An attempt was made to evaluate the microstructural degradation in artificially aging heat treated 2.25CrMo steel by the ultrasonic attenuation and velocity measurements. Ultrasonic velocity was found essentially insensitive to the microstructural changes resulting from aging heat treatment. However, the ultrasonic attenuation was observed to increase with increasing aging time. Also, it was noticed that the change of ultrasonic attenuation with aging time was more sensitive at high frequency regions.

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Influence of Deposition Conditions on the Adhesion of Sputter-deposited MoS$_2$-Ti Films

  • Kim, Sun-Kyu;Yongliang Li
    • Journal of the Korean institute of surface engineering
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    • v.37 no.1
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    • pp.1-4
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    • 2004
  • MoS$_2$-Ti films were deposited on SKD-11 tool steel substrate by a D.C. magnetron sputtering system. The influence of deposition parameters on the adhesion of the films was investigated by the scratch test. Crosssection morphology was evaluated using FE-SEM. The plasma etching played an important role on the adhesion of the films. The appropriate etching conditions roughened the surface, resulting In the improved adhesion of the film. The adhesion of the film increased with the interlayer thickness up to 110 nm and then decreased slightly with further increasing of interlayer thickness. The adhesion was highest at a bias voltage of -50 V. Further increase of the bias voltage decreased the film adhesion.

Effect of C/Ti Atomic Ratio of TiCx Raw Powder on the Properties of Ti-Mo-W-TiC Sintered Hard Alloy

  • Nakahara, Kenji;Sakaguchi, Shigeya
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.109-110
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    • 2006
  • We have studied the effect of C/Ti atomic ratio of TiCx (x=0.5, 0.75 and 1.0) raw powder on the properties of the Ti-Mo-WTiC sintered hard alloy. The decrease of C/Ti atomic ratio accelerated the densification in the sintering process. The hardness was remarkably improved up to 1350HV with decreasing the C/Ti atomic ratio because of increase of TiCx phase volume content and its fine dispersion. From the results of electro-chemical tests in acid and 3% NaCl solutions, it was obvious that every alloy had excellent corrosion resistance, which meant about 200 times better than that of WC-Co cemented carbide.

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Optical Properties of CIGS Films as Deposition Conditions of Mo Back Contact (MO 배면전극의 제조조건이 CIGS 박막의 광특성에 미치는 영향)

  • Kim, S.K.;Lee, J.L.;Kang, K.H.;Yoon, K.H.;Park, I.J.;Song, J.;Han, S.O.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1518-1520
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    • 2001
  • Bi-layer Mo films were deposited on sodalime glass substrates using DC magnetron sputtering. As the gas pressure and power density, the resistivity varied from $1.5{\times}10^{-5}$ to $4.97{\times}10^{-4}{\Omega}{\cdot}cm$. Furthermore, stress direction yielded compressive-to-tensile transition stress curves. The microstructure of the compressive stress films which had poor adhesion consists of tightly packed columns, but of the tensile-stressed films had less dense structure. Under all gas pressure conditions, Mo films exhibited distinctly increasing optical reflection with decreasing gas pressure. The expansion of (110) peak width with the gas pressure meant the worse crystalline growth. Also, The highest efficiency was 15.2% on 0.2 $cm^2$. The fill factor, open circuit voltage and short circuit current were 63 %, 570 mV and 42.6 mA/$cm^2$ respectively.

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Photovoltaic Properties of Cu(InGa)$Se_2$ Solar Cells with Sputter Conditions of Mo films (Mo 박막의 성장조건에 따른 Cu(InGa)$Se_2$ 박막 태양전지의 광변환효율)

  • Kim, S.K.;Lee, J.C.;Kang, K.H.;Yoon, K.H.;Park, I.J.;Song, J.;Han, S.O.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.63-66
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    • 2002
  • Bi-layer Mo films were deposited on sodalime glass substrates using DC magnetron sputtering. As the gas pressure and power density, the resistivity varied from $1.5{\times}10^{-5}$ to $4.97{\times}10^{-4}{\Omega}{\cdot}cm$. Furthermore, stress direction yielded compressive-to-tensile transition stress curves. The microstructure of the compressive stress films which had poor adhesion consists of tightly packed columns, but of the tensile-stressed films had less dense structure. Under all gas pressure conditions, Mo films exhibited distinctly increasing optical reflection with decreasing gas pressure. The expansion of (110) peak width with the gas pressure meant the worse crystalline growth. Also, The highest efficiency was 15.2% on 0.2 $cm^2$. The fill factor, open circuit voltage and short circuit current were 63 %, 570 m V and 42.6 $mA/cm^2$ respectively.

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A Study on Composition and Dosimetry of the $CaSO_4$ Phosphors ($CaSO_4$ 열형광체의 조성과 선량측정에 관한 연구)

  • Lee, Duek-Kyu
    • Journal of radiological science and technology
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    • v.21 no.1
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    • pp.59-64
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    • 1998
  • [ $CaSO_4$ ] thermoluminescent phosphors was made by sintring the $CaSO_4$ after doping the transition elements Tm, Pd, Dy, V, Mo, Zr. The maximum Peaks are found in the measured $CaSO_4$(Tm, Pd, Dy, V, Mo, Zr) TL glow curve at $130^{\circ}C,\;110^{\circ}C,\;140^{\circ}C,\;100^{\circ}C$, and $120^{\circ}C$ when the heating rate is $5^{\circ}C/sec$. The activation energy of the main peak has been estimated by the peak shape method. The estimated activation energies are 1.02eV, 1.32eV, 1.12eV, 0.80eV, and 1.17eV, respectively. The thermoluminescence process in $CaSO_4$(Tm, Pd, Dy, V, Mo, Zr)are found to the 2nd order when the main peak of the glow curve is analyzed by peak shape method. The dose responses of $CaSO_4$(Tm, Pd, Dy, V, Mo, Zr) phosphors are linear within $4{\times}10^{-4}{\sim}1Gy$ of X-rays.

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Development of Assessment Methodology on Creep-Fatigue Crack Behavior for a Grade 91 Steel Structure (Mod.9Cr-1Mo 강 구조의 크리프-피로 균열 거동 평가법 개발)

  • Lee, Hyeong-Yeon;Lee, Jae-Han
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.1
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    • pp.103-110
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    • 2010
  • In this study, an assessment method on creep-fatigue crack initiation and crack growth for a Mod.9Cr-1Mo steel (ASME Grade 91) structure has been developed with an extension of the French RCC-MR A16 procedure. The current A16 guide provides defect assessment procedure for a creep-fatigue crack initiation and crack growth for an austenitic stainless steel, but no guideline is available yet for a Mod.9Cr-1Mo steel which is now widely being adopted for structural materials of future nuclear reactor system as well as ultra super critical (USC) thermal plant. In the present study an assessment method on creep-fatigue crack initiation and crack growth is provided for the FMS (Ferritic-Martensitic Steel) and assessment on the creep-fatigue crack behavior for a structure has been carried out. The assessment results were compared with the observed images from a structural test.

The Study of Low Carbon Microalloyed Forging Steels by Direct Quenching Method with Mo Additions (몰리브덴을 첨가한 직접 소입 저탄소 비조질강에 관한 연구)

  • Wee, Kyoum-Bok;Lee, Kyung-Sub
    • Korean Journal of Materials Research
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    • v.2 no.6
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    • pp.452-460
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    • 1992
  • Effects of the microalloyed elements, temperatures and cooling rates on the strength and toughness of the medium carbon microalloyed hot forging steels obtained by air cooling(A.C.) method and the low carbon microalloyed forging steels by direct quenching(D.Q.) method were investigated. Combined additions of V+Nb produced the optimum combination of strength and toughness with ferrite-pearlite structure of the medium carbon steel by the A.C. method. 831MPa in UTS and 52.1J in toughness were obtained for 0.40c+0.12V+0.07Nb. It was martensite structure for the low carbon steel by the D.Q. method. The highest UTS and toughness obtained by Mo additions were 855MPa and 108j by 0.12C+0.10V+0.03Nb+1.13Mo respectively. Especially, the toughness of the low carbon steel was twice better than that of the medium carbon steel. 110$0^{\circ}C$was more appropriate than 120$0^{\circ}C$ for the reheating and forging temperature and 1.$2^{\circ}C$ /s was the best cooling rate from the viewpoint of the strength and toughness. Multiple regression analysis was used to quantify the influence of the microalloyed elements, temperatures and cooling rates on the strength, toughness, austenite grain size, and the pearlite interlamellar spacing.

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A Study on the Flow Characteristics inside a Glove Valve for Ships (선박용 글로브 밸브의 유동특성에 관한 연구)

  • Bae, Ki-Hwa;Park, Jea-Hyoun;Kang, Sang-Mo
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.1
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    • pp.110-118
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    • 2008
  • It is essential for the valid design of a marine flow-control valve to exactly know its flow characteristics. The present study has numerically investigated the flow characteristics inside a marine throttle-type globe valve using a kind of commercial CFD code, CFX10.0, with an adoption of the SST (Shear-Stress Transport) turbulence model. To validate the numerical approach, the flow coefficients are compared with the experimental ones. Results show that the globe valve is effective in the control of flow rate according to the opening ratio in case of the forward-direction flow, whereas it is effective in the flow shutoff in case of the reverse-direction flow. Around the inlet of the valve, a recirculation region is formed due to the blunt body shape, the turbulence intensity becomes strengthened and then an abrupt pressure loss occurs.