• Journal of the Mineralogical Society of Korea
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• v.26 no.4
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• pp.229-244
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• 2013

Arsenic contamination may be brought about by a variety of natural and anthropogenic causes. Among diverse naturally-occurring chemical speciations of arsenic, trivalent (As(III), arsenite) and pentavalent (As(V), arsenate) forms have been reported to be the most predominant ones. It has been well known that the behavior of arsenic is chiefly affected by aluminum, iron, and manganese oxides. For this reason, this study was initiated to evaluate the applicability of manganese slag (Mn-slag) containing high level of Mn, Si, and Ca as an efficient sorbent of arsenic. The main properties of Mn-slag as a sorbent were investigated and the sorption of each arsenic species onto Mn-slag was characterized from the aspects of equilibrium as well as kinetics. The specific surface area and point of zero salt effect (PZSE) of Mn-slag were measured to be $4.04m^2/g$ and 7.73, respectively. The results of equilibrium experiments conducted at pH 4, 7 and 10 suggest that the sorbed amount of As(V) was relatively higher than that of As(III), indicating the higher affinity of As(V) onto Mn-slag. As a result of combined effect of pH-dependent chemical speciations of arsenic as well as charge characteristics of Mn-slag surface, the sorption maxima were observed at pH 4 for As(V) and pH 7 for As(III). The sorption of both arsenic species reached equilibrium within 3 h and fitting of the experimental results to various kinetic models shows that the pseudo-second-order and parabolic models are most appropriate to simulate the system of this study.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.1148-1151
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• 2002

Dielectric ceramics with nominal composition of $(Ba_{0.93}Sr_{0.07}O)-0.5Sm_2O_3-4.5TiO_2$ was prepared using the conventional mixed oxide process-derived powder. Effect of $SiO_2$, $MnO_2$ and $Al_2O_3$ impurity addition on the microwave properties was examined in some detail. Measured relative permittivity $(\varepsilon_r)$ values were in the range of 53 to 59 and showed little dependence on impurity addition. In contrast, quality factor $(Q{\cdot}f)$ and temperature coefficient of resonant frequency $(\tau_f)$ values were greatly influenced by the type and the amount of impurities. It was found that 0.1~0.2wt% addition of $Al_2O_3$ was most effective for improving the properties, where ${\varepsilon}_r$, $Q{\cdot}f$ and $\tau_f$ values were 57.7, 10000, and +7ppm/$^{\circ}C$, respectively.

• Journal of Environmental Science International
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• v.16 no.1
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• pp.39-44
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• 2007

This study was conducted to investigate the contents of residual solvents and mineral components(11 kinds) in ginseng extracts with different extracting conditions(5 types) and commercial ginseng extract products(domestic, imported). Fine root was extracted with solution having various ethanol concentration after hexane treatment. Among 5 type extracts, residual solvent(hexane) was detected ginseng extracts treated ethanol mixed with hexane. But extracts that dried after soaked in hexane wasn't detected hexane. Mineral components(Al, Mn, Fe, Cu and Zn) were detected in fine root and 5 types of extracts. The contents of mineral components between fine root and extracts with various extracting conditions were similar, however, extracts that dried after soaked in hexane showed the lower amount in Al, Fe, Pb than the others. In comparison with commercial ginseng ex-tract products(domestic, imported), the distribution pattern of mineral was similar but the contents were a little different.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.396.2-396.2
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• 2014

백색 유기발광소자는 전색 디스플레이, 조명으로서의 잠재적인 특성으로 차세대 디스플레이 소자 기술로 많은 주목을 받고 있다. 백색 유기발광소자는 주로 R-G-B 영역의 다양한 발광층을 적층하여 제작한다. 하지만 여러 발광층을 적층해야하기 때문에 제작할 때 공정 과정이 복잡해지고, 높은 생산단가를 가지게 된다. 이런 문제를 해결하기 위해 형광체를 이용한 백색 유기발광소자의 연구가 진행되고 있지만, 아직 색순도와 색좌표에 대한 많은 연구가 미흡한 상태이다. 본 연구에서는 무기물 형광체를 활용하여 백색 유기발광소자의 전기적 특성과 광학적 특성을 관찰하였고, 광원으로 사용된 청색 유기발광소자에 녹색과 적색의 무기물 형광체를 결합하는 방법으로 백색 유기발광소자를 제작하였다. 광원으로 사용한 청색 유기발광 소자는 투명전극으로 ITO를 사용하였고, 정공 수송층으로 N,N'-bis-(1-naphthyl)-N,N'-diphenylbenzidine, 발광층으로 4,4-bis(2,2-diphenylethen-1-yl)biphenyl, 정공 저지 층과 전자 수송 층은 각각 bathocuproine 과 4,7-diphenyl-1,10-phenanthroline 을 사용 하였다. 전자 주입 층으로는 lithium quinolate를 사용하였으며 음극으로는 Al을 사용하였다. 색 변환 층으로 사용된 유기물 형광체는 sol-gel 방법으로 제작된 녹색 형광체 Y3Al5O12:Ce, 적색 형광체 Ca2AiO19:Mn 을 사용하였다. Sol-gel 방법으로 제작된 형광체는 X선 회절 분석기를 통해 JCPDS cards를 확인하였고, 형광체의 녹색과 적색의 혼합비율에 따른 색좌표를 확인하여 백색 유기발광소자를 제작 하였다.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.53 no.9
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• pp.455-458
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• 2004

In this paper, we investigated impurities content and physical properties showing by changing the content of carbon black that is semiconductive materials for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Impurities content of specimens was measured by ICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometer), and density of specimens were measured by density meter And then specific heat (Cp) was measured by DSC (Differential Scanning Calorimetry). A ranges of measurement temperature were from $0^{\circ}[C]$ to $200^{\circ}[C]$, and heating temperature was $4^{\circ}[C/min]$. Impurities content was highly measured according to increasing the content of carbon black from this experimental result, also density was increased according to these properties. Especially impurities content values of the Al and A2 of existing resins were measured more than 4000［ppm］. Specific heat from the DSC results was decreased according to increasing the content of carbon black. Because ionic impurities of carbon black having Fe, Co, Mn, Al and Zn are rapidly passed kinetic energy increasing the number of times breaking during the unit time with the near particles according to increasing vibration of particles by the applied heat energy.

• Journal of the Korean Society for Heat Treatment
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• v.17 no.5
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• pp.299-304
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• 2004

Influence of Ca addition on microstructure and room temperature mechanical properties has been studied for AZ31(Mg-3%Al-1%Zn-0.2%Mn)-(0~0.5)%Ca wrought alloys, based on experimental results from metallography, X-ray diffractometry and mechanical tests. Yield strength, ultimate tensile strength and hardness of the alloys increased remarkably with increasing Ca content, whereas elongation was deteriorated continuously. Microstructural examination revealed that Ca addition efficiently refined grains of ${\alpha}$(Mg) phase and that some of the Ca dissolved in ${\beta}(Mg_{17}Al_{12})$ precipitates. The former and the latter facts are thought to be responsible for improved strength and loss of ductility of the AZ31+Ca wrought alloys, respectively.

• Journal of Welding and Joining
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• v.26 no.6
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• pp.54-58
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• 2008

Laser welding with AZ61 filler wire was carried out to improve formability though reduction of porosity and formation of under fill bead. Optimum welding condition and mechanical properties of butt joint for $400{\times}500{\times}1.3mm$ magnesium sheets were studied. Optimal welding conditions of laser power, welding speed, and defocusing length are 1000W, 3m/min, and 2mm, respectively. Results of tensile test indicated that both tensile strength and elongation of specimens welded with filler wire were improved at room temperature because of reduction of porosity and under-filled bead formation in addition to the precipitation hardening and microstructure refinement by Al-Mn and Mg-Al-Zn precipitates. At elevated temperature of $200{\sim}350^{\circ}C$, fracture location of tensile specimen was shifted from weld metal to base metal, indicating less softening of weld metal than base metal.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.200-202
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• 2008

동해 울릉분지에서는 시추선 RemEtive를 사용하여 UBGH-X-01 가스하이드레이트 탐사가 2007년에 실시되었다. 본 연구에서는 천부 가스하이드레이트가 확인된 UBGH1-10 정점에서 무인잠수정(Quantam WROV)을 사용하여 획득된 푸쉬코어와 해저지형 분석을 수행되었다.UBGH1-10 정점은 seismic chimneys의 탄성파 특성이 발달된 지역이다. 이곳에서는 해저표면으로부터 수 m 하부에서 가스하이드레이트가 발견되었다. 이 정점은 수 m 높이의 얕은 둔덕들이 무인잠수정에 부착된 비디오 카메라에 의해서 관찰되었다.이곳에서 채취된 길이 약40 cm의 푸쉬코어는 생물교란된 뻘질 퇴적물로 구성되어 있으며, 가스하이드레이트와 chemosynthetic community는 관찰되지 않았다. 푸쉬코어는 X-ray fluorescence scanner를 사용하여 퇴적물의 26가지 원소 조성을 분석하였다. UBGH1-10 정점의 산화환원환경은 Mo/Al과 Mn/Ti 원소비를 이용하여 천부 가스하이드레이트가 발견되지 않은 UBGH1-9와 UBGH1-1 정점과 대비하였다. 이 정점의 일차생산력은 Ba/Al 원소비를 이용하여 다른 정점과 대비하였다. 천부 가스하이드레이트가 발견된 UBGH1-10 정점은 활발한 가스방출과 관련된 생물집단 서식 또는 자생광물 형성의 흔적이 발견되지 않으며, 퇴적물에서도 산화환원환경과 일차생산력의 큰 차이가 관찰되지 않는다.

• Corrosion Science and Technology
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• v.9 no.4
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• pp.164-170
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• 2010

Thermodynamic consideration was performed for Alloy 617 exposed to an impure helium ($H_2$ 20pa, $H_2O$ 0.5pa, $CH_4$ 2pa and CO 5pa) at $950^{\circ}C$. Oxidation power was decreased in the order Al > Ti > Si > Cr > Mn. Decarburization and carburization reactions were available leading to carbon activity decrease and increase, respectively, depending on carbon and Cr activities. The thermodynamic prediction was compared with the experimental results obtained in similar conditions (($H_2$ 20pa, $H_2O$ 0.05pa, $CH_4$ 5pa and CO 2pa) and $950^{\circ}C$) by others for Alloy 617. The driving force for oxidation of Al, Ti and Si is very large to be oxidized at a given impure helium and the environment is actually carburizing towards the structural alloy, which is consistent with this work.

• Journal of Korea Foundry Society
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• v.35 no.1
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• pp.8-14
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• 2015

Variations of nickel contents and microstructures in molten magnesium alloys on the addition of aluminum, zirconium, and manganese have been investigated. Specimens were prepared by melting under $SF_6$ and $CO_2$ atmosphere and casting into a disc of 29 mm diameter with 7~10 mm thickness from the melt acquired at the top of crucible. Before casting, the molten metal was stirred for 3 minutes after each addition of alloying elements and maintained for 30 minutes for settling down. Results showed that zirconium did not significantly affect the content of nickel while aluminum remarkably reduced it by forming $Al_3Ni_2$ phase. When manganese are added to Mg-1wt%Ni alloy along with aluminum, both elements remarkably reduced the content of nickel. The addition of 1.5 wt% manganese to Mg-1wt%Ni alloy containing aluminum further reduced the content of nickel by more than 30%, during which an additional intermetallic phase $Al_{10}Mn_3Ni$ was precipitated in the molten magnesium.