• 한국재료학회지
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• 제27권12호
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• pp.643-651
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• 2017

Four types of high Mn TWIP(Twinning Induced Plasticity) steels were fabricated by varying the Mn and Al content, and the tensile properties were measured at various strain rates and temperatures. An examination of the tensile properties at room temperature revealed an increase in strength with increasing strain rate because mobile dislocations interacted rapidly with the dislocations in localized regions, whereas elongation and the number of serrations decreased. The strength decreased with increasing temperature, whereas the elongation increased. A martensitic transformation occurred in the 18Mn, 22Mn and 18Mn1.6Al steels tested at $-196^{\circ}C$ due to a decrease in the stacking fault energies with decreasing temperature. An examination of the tensile properties at $-196^{\circ}C$ showed that the strength of the non-Al added high Mn TWIP steels was high, whereas the elongation was low because of the martensitic transformation and brittle fracture mode. Although a martensitic transformation did not occur in the 18Mn1.9Al steel, the strength increased with decreasing temperature because many twins formed in the early stages of the tensile test and interacted rapidly with the dislocations.

• 한국주조공학회지
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• 제25권5호
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• pp.216-220
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• 2005

High ductility Al-Mg alloys often contain some Mn and Si, however the effects of these minor alloying elements on various properties of alloys have not been fully understood. In this study the castability and mechanical properties of Al-5%Mg alloy were investigated according to the addition of Mn and Si. The fluidity of the alloys was generally increased by increasing Si or Mn contents. The feedability was also increased by increasing Si content, but it was rather decreased by increasing Mn content. Both the tensile strength and the ductility appeared to be deteriorated by Si addition, while they were found to be improved by Mn addition.

• 대한화학회지
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• 제43권1호
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• pp.23-29
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• 1999

황산용액에서 제조된 Al양극 산화피막 내부로 여러 주파수의 교류전압을 통하여 1 g/L $KMnO_4$ 용액내에서 Mn금속을 전착시켰다. 이때 Al 산화피막 내부로 전착되는 Mn금속의 변화와 산화피막의 특성변화를 임피던스를 통하여 조사했다. 낮은 교류전압의 주파소로 Mn전착된 피막의 임피던스 스펙트럼은 황산에서 제조된 산화피막의 임피던스 스펙트럼과 차이를 나타냈으며, 특히 등가회로에서는 Mn전착의 영향을 나타내는 파라미터인 저항과 축전용량이 추가로 첨가되었다. 또한 Mn전착은 기공성의 산화피막 내부로 진행되는 것으로 나타났다. 또한 기공성의 산화피막의 경우는 저주파를 부하하여 Mn전착시킬 경우 비전도성의 피막성장에 의해 전하이동저항이 높게 나타났다. 이러한 Al산화피막의 특성은 전도도의 구배를 나타내는 파라미터인 Young 임피던스를 통하여 관찰되었다.

• The Korean Journal of Ceramics
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• 제4권4호
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• pp.297-303
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• 1998

The effect of aliovalent dopants, $ Nb_2O_5$ and MnO, on the phase stability of 12 mol% ceria partially-stabilized zirconia (Ce-TZP) polycrystals was studied. Both dopants (MnO and $ Nb_2O_5$) significantly increased the stability of the tetragonal zirconia phase (Mb temperature lower than liquid nitrogen temperature). The enhancement of the stability of the tetragonal phase in Ce-TZP doped with 1 mol% of Mno(Ce-TZP/MnO) andCe-TZP doped with 1 mol% of $ Nb_2O_5$(Ce-TZP/$ Nb_2O_5$) were explained by the significant reduction of the driving force, -${\Delta}$Gchem, for the tetragonal-to-mono-clinic phase transformation caused by the addition of MnO and $ Nb_2O_5$. The enhanced stability of the tetragonal phase in the Ce-TZP and Al2O3 composite (Ce-TZP/$Al_2O_3$) is believed to be caused by smaller grain size, moderate reduction in the chemical driving force and increase in the strain energy barrier to the transformation. Mechanical properties of the Ce-TZP and the Ce-TZP/$Al_2O_3$ with (i) the same grain size and (ii) the same Mb temperature were examined by measuring stress-strain behavior in 3 point bending. The Ce-TZP/$Al_2O_3$ composite doped with 1.3w% MnO (Ce-TZP/$Al_2O_3$/MnO), which had the same grain size as the Ce-TZP and De-TZP/$Al_2O_3$ showed more transformation plasticity than either the Ce-TZP or the Ce-TZP/$Al_2O_3$ composite. The Ce-TZP wihch had the same Mb temperature as that of the Ce-TZP/$Al_2O_3$/MnO did not show any transformation plasticity.

• Journal of Welding and Joining
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• 제28권1호
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• pp.60-65
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• 2010

This paper is concerned with effects of Al, Mn and Si contents on spatter, fume, microstructure and mechanical property with 490MPa Grade Flux Core Wire(FCW). Ten kinds of FCW were fabricated by varying Mn, Si and Al contents and each FCW was weld for check the amount of spatter and fume generations, microstructures and mechanical property. Amount of spatter and fume generations was decreased with the increasing Si contents and decreasing by Al contents in FCW. And, their microstructure of weld metal were changed by Mn, Al and Si contents in FCW. With increasing of Al and Si, acicular ferrite was fine and volume fraction of acicula ferrite was increased. Thereby leading to improvement of Charpy impact property and strength.

• 전기화학회지
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• 제9권2호
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• pp.64-69
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• 2006

초음파분무열분해법과 한 단계의 후열처리로 이차상이 없는 Al이 첨가된 $Li(Ni_{1/3}Co_{1/3}Mn_{1/3-x}Al_x)O_2$ (x=0.0, 0.005, 0.01. 0.05) 리튬이차전지용 양극활물질을 합성하였다. 합성된 분말은 Al의 첨가량이 많아짐에 따라서 $I_{003}/I_{104}$ 비는 감소하고 입자가 커지는 경향을 보였다. 상온에서 전류밀도 1C의 rate로 $3.0\sim4.5V$ 범위에서 충방전 시험한 결과, Al 치환량이 0.5와 1.0 at%에서는 초기용량이 180과 $184mAhg^{-1}$으로 치환하지 않았을 때의 $182mAhg^{-1}$과 차이가 없었으며, 싸이클 특성도 치환하지 않은 것과 0.5, 1.0 at% 치환한 조성에서 각각 81, 77, 81%의 방전용량이 유지되었다. 그러나 $3.0\sim4.6V$에서는 치환효과가 확실하게 나타나서, 50 싸이클 후의 치환하지 않은 것의 방전용량은 초기용량의 30%가지 감소한데 비하여 Al을 0.5 at% 치환한 것은 70%를 유지하였다. 치환에 의한 싸이클 특성 향상은 XPS 분석 결과 Al 치환이 $Mn^{3+}$의 양을 감소시켰기 때문인 것으로 사료되었다.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.3005-3012
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• 2013

The effect of Mn-promotion on high surface area Al-pillared montmorillonite (AlMMT) supported Co nanoparticles prepared by hydrothermal method have been investigated. A series of different weight% Mn-promoted Co nanoparticles were prepared and characterized by XRD, TPR, TGA, BET and SEM techniques. An increase in the surface area of MMT is observed with Al-pillaring. Fischer-Tropsch catalytic activity of the as prepared catalysts was studied in a fixed bed micro reactor at $225^{\circ}C$, $H_2/CO$ = 2 and at 1 atm pressure. The data showed that by the addition of Mn the selectivity of $C_1$ dropped drastically while that of $C_2-C_{12}$ hydrocarbons increased significantly over all the Mn-promoted Co/AlMMT catalysts. The $C_{13}-C_{20}$ hydrocarbons remained almost same for all the catalysts while the selectivity of $C_{21+}$ long chain hydrocarbons decreased considerably with the addition of Mn. The catalyst with 3.5%Mn showed lowest $C_{21+}$ and highest $C_2-C_{12}$ hydrocarbons selectivity due to cracking of long chain hydrocarbons over acidic sites of MMT.

• 한국재료학회지
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• 제27권6호
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• pp.318-324
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• 2017

In this study, two Fe-30Mn-0.2C-(1.5Al) high-manganese steels with different surface conditions were hydrogen-charged under high temperature and pressure; then, tensile testing was performed at room temperature in air. The yield strength of the 30Mn-0.2C specimen increased with decreasing surface roughness(achieved via polishing), but that of the 30Mn-0.2C-1.5Al specimen was hardly affected by the surface conditions. On the other hand, the tendency of hydrogen embrittlement of the two high-manganese steels was not sensitive to hydrogen charging or surface conditions from the standpoints of elongation and fracture behavior. Based on the EBSD analysis results, the small decrease in elongation of the charged specimens for the Fe-30Mn-0.2C-(1.5Al) high-manganese steels was attributed to the enhanced dislocation pile-up around grain boundaries, caused by hydrogen.

• Journal of Welding and Joining
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• 제31권6호
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• pp.65-70
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• 2013

In joining Alumina to copper plate by Mo-Mn metallizing process, the effects of the composition of metallizing paste on the bonding strength were investigated. The bonding strength increased with increasing Mn amount in the paste up to 20% but followed by the decrease with addition of Mn. The maximum bonding strength reached 50MPa at 20%Mn when heated to $1550^{\circ}C$ for 60minute. The addition of Si to the metallizing powder increased the bonding strength of the joint by enhancing the mechanical bonding between the Alumina and the metallizing layer due to the decrease of layer viscosity with the addition of $SiO_2$. It is thought that MnO reacted with $Al_2O_3$ to yield $MnAl_2O_4$ spinel, forming a joint.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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• pp.271-278
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• 2006

Green light emitting $Zn_2SiO_4$Mn and Al co-doped $Zn_2SiO_4$:Mn phosphor were synthesized by a sol-gel method combined with a furnace firing. The luminescent properties of the sample have been investigated. We have found that the phosphor powder with uniform shape show the maximum luminescent intensity when it is prepared with sol-gel method and fired at relatively high temperature ($1100{\sim}1300^{\circ}C$).