• Title/Summary/Keyword: MnAl

Search Result 1,114, Processing Time 0.043 seconds

A1-25Nb계와 (A1,X)-25Nb계 (X = Cr, Cu, Fe, Mn)의 기계적 합금화에 의한 금속간 화합물의 형성 거동에 관한 연구 (Behavior of Intermetallic Compound Formation in Al-25Nb system and (Al,X)-25Nb (X= Cr, Cu, Fe, Mn) systems by Mechanical Alloying Method)

  • 최재웅;강성군
    • 한국재료학회지
    • /
    • 제11권9호
    • /
    • pp.733-739
    • /
    • 2001
  • In Al-25Nb binary system, it was observed only formation of $D0_{22}$ $Al_3Nb$ intermetallic compound after 5hr milling but it was not observed formation of meta stable phase like L1$_2$ phase. In this state, $D0_{22}$ $Al_3Nb$ fabricated had nano sized grain of approximately 20nm. Ternary systems, transition metals such as Cr, Cu, Fe, Mn were added 6~12at.% as substitution of Al, showed formation of $D0_{22}$ $Al_3Nb$ like Al-25Nb binary system. In Al- l2Cu-25Nb system, it was observed that broad XRD pattern like amorphization of Al and not observed formation of $D0_{22}$ $Al_3Nb$ after 5hr milling. But there was mixed phase of a lot of amorphous Al and little $D0_{22}$ $Al_3Nb$ through TEM. In the states of unalloyed, 5~7hr milling time, those showed exothermic reaction at 35$0^{\circ}C$, which was formation of $D0_{22}$ $Al_3Nb$ like Al-25Nb binary system. With increasing milling time to 10hr, $D0_{22}$ $Al_3Nb$ was transformed to mixed phase of amorphous and nanocryatlline, having approximately 10nm grain but the meta stable $Al_3Nb$ was not fabricated by adding transition metals.

  • PDF

Al-Si 도금된 22MnB5강의 핫스탬핑 TWB 적용을 위한 레이저용접성 고찰 (A Study on Laser Weldability of Al-Si Coated 22MnB5 Steel for TWB Hot Stamping)

  • 김용;박기영;이보영
    • Journal of Welding and Joining
    • /
    • 제31권2호
    • /
    • pp.30-36
    • /
    • 2013
  • Recently the use of ultra high strength steels(UHSS) in structural and safety component is rapidly increasing in the automotive industry. Furthermore, it commonly use in tailor welded blank laser welding process before hot stamping to reduce lightweight vehicle. However TWB process is to be a problem about welded strength after hot stamping because it's welded before heat treatment. Therefore, in this study, laser welds of TWB after heat treatment were analyzed for changes in the characteristics, especially the impact on the oxidation and decarburization in order to prevent pre-coated Al-Si layer welds on the properties for intensive investigation. As a result, the degradation of the TWB weldments changes in the heat treatment conditions alone, without any pre-treatment of the coating layer has confirmed that there is a limitation on the improvement. Furthermore Al-Si elements are overall distributed on the weldment and it specially concentrated along the fusion line. Hardness value of Al-Si segregation area is less than 350Hv and tensile strength showed just 78~83% compared with substrate. Accordingly, we proved that both side Al-Si coating should be removed in order to ensure the strength of the substrate.

Mn-Ce 복합 산화물에 의한 톨루엔 촉매 산화 (Toluene Catalytic Oxidation by Manganese-Cerium Bimetallic Catalysts)

  • 천태진;최성우;이창섭
    • 한국환경과학회지
    • /
    • 제14권4호
    • /
    • pp.427-433
    • /
    • 2005
  • Activity of manganese oxide supported on ${\nu}-Al_2O_3$ was increased when cerium was added. Also, cerium-added manganese oxide on ${\nu}-Al_2O_3$ was more effective in oxidation of toluene than that without cerium. XRD result, it was observed that $MnO_2+CeO_2$ crystalline phases were present in the samples. For the used catalyst, a prominent feature has increased by XPS. TPR/TPO profiles of cerium-added manganese oxide on ${\nu}-Al_2O_3$ changed significantly increased at a lower temperature. The activity of $18.2 wt{\%}\;Mn+ 10.0 wt{\%}\;Ce/{\nu}-Al_2O_3$ increased at a lower temperature. The cerium added on the manganese catalysts has effects on the oxidation of toluene.