• 제목/요약/키워드: Mn12

검색결과 1,031건 처리시간 0.026초

금속 수소화물 전극제조에 있어서 알카리 무전해 구리 도금법의 응용 (Application of an electroless copper coating in alkaline bath to preparation of the metal hydride electrode)

  • 최전;박충년
    • 한국수소및신에너지학회논문집
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    • 제3권2호
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    • pp.9-15
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    • 1992
  • Electroless copper plating method using an alkaline bath have been employed in copper coating of the (LM)Ni4.5Co0.1MnO.2A10.2 hydrogen storage alloy powders for electrode preparation. The plating were conducted without any pretreatment of alloy powders. For the preparation of the electrodes, about 0.12g of the copper coated alloy powder (copper to alloy ratio 1/3 by weight) was compacted with pressure of 6 tons/cm2 at room temperature. The disk-type compacts had a diameter of 10mm and thickness of about 0.24mm. The electrode characteristics were examined through SEM observations and electrochemical measurements in a half cell. The electrochemical measurement showed that the maximum discharge capacity of the electrodes prepared by using alkaline bath were 245mAh per gram of coated alloy (327mAh per gram of alloy) and appeared a considerable degradation with increasing number of cycles. The decrease of the discharge capacity after 100 cycles was about 30% It can be suggested that, with a slight of improvement, this electroless copper plating method could be applied to the preparation of the rare earth-nickel based alloy electrode.

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서울지역 지하수의 오염도와 성분별 相關性 檢討 (Studies on the Water Quality of Ground Water in Seoul Area and Correlation Analysis Among their Contaminants)

  • Ahn, Soo-Mi;Oh, Soo-Kyoung;Park, Sung-Bae
    • 한국환경보건학회지
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    • 제15권1호
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    • pp.51-62
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    • 1989
  • This survey was performed to investigate contamination degree and significance in each item of 406 samples of ground water, which was collected in Seoul area from Jan. to Dec. 1988. The results of this study were as follows 1. The unsuitable rate of ground water investigated was 69.7%(32.4% in only bacteria, 23.6% in both bacteria and physico-chemistry and 13.6% in only physico-chemical contamination). 2. The unsuitable rate in each item was the highest(54.2%) in standard plate countland 29.8% in coliform, 12.8% in turbidity, 11.3% in Zn, and 10.8% in Mn. 3. The total mean concentrations in each item were lower than standard except standard plate count, coliform, and Fe. 4. In the analysis of corelation, among items, both total hardness and residual solids were showed very high correlationship (P < 0.01) with other items, and both S.P.C. and coliform showed very highly significant (P < 0.01) with NH$_3$-N.

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광범위 출력 측정이 가능한 레이저 계측장치 개발 (Development of the laser measurement system for the wide output power range)

  • 황대석;이영우
    • 한국정보통신학회논문지
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    • 제9권8호
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    • pp.1799-1804
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    • 2005
  • 넓은 출력 범위의 $CO_2$ 및 Nd:YAG 레이저광 출력측정 및 교정을 위해 정밀한 칼로리미터를 제작하고 성능의 정가에 관한 연구를 수행하였다. 칼로리미터의 수광부는 금 코팅된 구리재질의 공동을 사용하여 제작되었다. 교정용 히터는 망가닌으로 제작되고, 출력 측정은 망가닌과 구리의 저항 브릿지를 사용하여 측정하였다. 교정 인자는 100W에서 489.13 J/mV이고 500W에서 497.04J/mV이다 Nd:YAG Laser를 이용하여 보정 계수를 구한 결과 100W일 때는 0.99이고 500W일 때는 1.006으로 레이저 에너지와 전기적 교정의 차이는 $1\%$이하이다.

$(Ba,Ca)(TiZr)O_3$ 세라믹을 적용한 적층 칩 커패시터의 전기적 특성 (The Electric Properties of Multilayer Ceramic Capacitors with $(Ba,Ca)(TiZr)O_3$ Ceramics)

  • 윤종락;여동훈;이현용;이석원
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제55권1호
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    • pp.1-5
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    • 2006
  • The effect of A/B moi ratios and sintering temperatures on dielectric properties and microstructure of $(Ba_{0.93}Ca_{0.07})_m(Ti_{0.82}Zr_{0.18})O_3$ ceramics were investigated. The dielectric constant decreased with increasing the A/B mol ratio. However, the dielectric loss is improved. As the dielectric properties of A/B mol ratio with m = 1.009 at sintered temperature $1260^{\circ}C$, we obtained dielectric constant 12,800, dielectric loss $3.5\%$ and Y5V temperature characteristics. Highly reliable Ni-MLCCs, 1.6mm$(length){\time}0.8mm(width){\time}0.8mm$(height) with capacitance of 1.23 ${\mu}F$ and 야ssipation loss of $5.2\%$ were obtained employing dielectric material composed of $(Ba_{0.93}Ca_{0.07})_{1.009}(Ti_{0.82}Zr_{0.18})O_3$ - $MnO_2\;0.2wt\%-Y_2O_3\;0.18wt\%,\;-\;SO_2\;0.15wt\%-(Ba_{0.4}Ca_{0.6})SiO_3\;1wt\%$.

꽃사과(Malus prunifolia Wild. Borkh. "Red Fruit")에서 에탄올 추출한 안토시안 색소의 안정성 (Stabilities of Anthocyanin Pigmenta obtained from Crab Apple (Malus prunifolia Wild. Borkh. "Red Fruit") by Ethanol Extraction)

  • 김용환
    • 한국식품영양학회지
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    • 제12권1호
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    • pp.85-90
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    • 1999
  • The characcteristics of anthocyanin pigments from crab apple (Malus prunifolia Wild. Borkh. "red fruit") by ethanol extract were investigated at various condition of light temperature sugar, organic acid me-tal ion and pH. The pigments were stable(over the 60%) on the light irradiation throughout 20 days sto-rage period at room temperature and in the pesenc of Al-foil red blue green and yellow cover were rage period at room temperature and in the pesence of Al-foil red blue green and yellow cover were very stable. The pigments also showed high thermal stbility(over the 67% at 115$^{\circ}C$ 10min) at pH2.5 respectively. The pigments with added organic acid greatly increased thickness of red color. The pig-ments with added metal ions at pH 2.5 such as Na+ K+, Mg2+ Ca2+ and Mn2+ were stable throughout 20 days storage period at $25^{\circ}C$. But Cu2+ addition showed the rapidly degradation of the pigments and Al3+ addition induced the color conversion from red to redish violet. The thickness of the red color of anthocyanin pigments increased increased as the pH decreased. These results indicated that crab apple antho-cyanin pigments might be potental source of natural food colorant. colorant.

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ANISOTROPY CONSTANTS OF $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ COMPOUNDS (RE=RARE EARTH)

  • Kim, H.T.;Kim, Y.B.;Park, W.S.;Kim, C.S.;Kim, T.K.;Jin, Han-Min
    • 한국자기학회지
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    • 제5권5호
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    • pp.683-686
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    • 1995
  • Using by the x-ray diffractometry(XRD), the thermomagnetic analysis(TMA), a scanning electron microscopy (SEM-EDX), we knew that the $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ (RE=Ce,Pr,Nd,Sm,Gd,Tb) compounds were formed to tetragonal $ThMn_{12}$-type structure having a uniaxial magnetocrystalline anisotropy with easy magnetization c-axis. The intrinsic magnetic properties of those were determined by fitting the two magnetization curves of experimental and calculation magnetization. The anisotropy constant $K_{1}$ of this compounds was in the range of $1.75\;-\;9.2\;MJ/m^{3}$ and approximately one order higher than $K_{2}$. $SmFe_{11}Ti$ had the highest anisotropy of $K_{1}\;=\;9.2\;MJ/m^{3}$, $K_{2}\;=\;0.4\;MJ/m^{3}$ and ${\mu}_{o}H_{A}=\;19.8\;T$ among the compounds, substitution of any other rare earth elements for Sm decreased magnetocrystalline anisotropy.

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The mycelial growth and ligninolytic enzyme activity of cauliflower mushroom (Sparassis latifolia)

  • Sou, Hong-Duck;Ryoo, Rhim;Ka, Kang-Hyeon;Park, Hyun
    • Forest Science and Technology
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    • 제13권4호
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    • pp.158-163
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    • 2017
  • We examined the activities of lignin-degrading enzymes of the mycelium of cauliflower mushroom (Sparassis latifolia). Three different strains of S. latifolia collected from several sites in Korea and one crossbred strain were cultured on potato dextrose broth (PDB) and Kirk's medium in order to study the activities of their ligninolytic enzymes. Mycelial growth reached maximum levels between 14 and 21 days after inoculation and pH increased by 0.12 units over 35 days. Laccase activity began increasing after 14 days on both types of media. Manganese peroxidase (MnP) activity followed a trend similar to that of laccase on Kirk's medium, but not on PDB. The activity of lignin peroxidase (LiP) differed from that of other enzymes; its activity decreased by half after 14 days on PDB but remained constant on Kirk's medium over 35 days. The total protein concentration increased considerably after 14 days and peaked at 21 days on PDB. A similar maximum was attained on Kirk's medium. In contrast, the residual glucose increased rapidly at 14 days on Kirk's medium, while increasing gradually up to 28 days on PDB. This study indicates that S. latifolia is more similar to white rot fungi than to other brown rot fungi.

가공유기 마르텐사이트 변태를 갖는 합금의 감쇠능에 미치는 가공열처리의 영향 (Effect of Thermo-Mechanical Treatment on the Damping Capacity of Alloy with Deformation Induced Martensite Transformation)

  • 한현성;강창룡
    • 한국재료학회지
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    • 제29권3호
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    • pp.160-166
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    • 2019
  • This study investigates the effect of thermo-mechanical treatment on the damping capacity of the Fe-20Mn-12Cr-3Ni-3Si alloy with deformation induced martensite transformation. Dislocation, ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ are formed, and the grain size is refined by deformation and thermo-mechanical treatment. With an increasing number cycles in the thermo-mechanical treatment, the volume fraction of ${\varepsilon}-martensite$ increases and then decreases, whereas dislocation and ${\alpha}^{\prime}-martensite$ increases, and the grain size is refined. In thermo-mechanical treated specimens with five cycles, more than 10 % of the volume fraction of ${\varepsilon}-martensite$ and less than 3 % of the volume fraction of ${\alpha}^{\prime}-martensite$ are attained. Damping capacity decreases by thermo-mechanical treatment and with an increasing number of cycles of thermo-mechanical treatment, and this result shows an opposite tendency for general metal with deformation induced martensite transformation. The damping capacity of the thermo-mechanical treated damping alloy with deformation induced martensite transformation greatly affect the formation of dislocation, grain refining and ${\alpha}^{\prime}-martensite$ and then ${\varepsilon}-martensite$ formation by thermo-mechanical treatment.

Radiation protective qualities of some selected lead and bismuth salts in the wide gamma energy region

  • Sayyed, M.I.;Akman, F.;Kacal, M.R.;Kumar, A.
    • Nuclear Engineering and Technology
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    • 제51권3호
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    • pp.860-866
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    • 2019
  • The lead element or its salts are good radiation shielding materials. However, their toxic effects are high. Due to less toxicity of bismuth salts, the radiation shielding properties of the bismuth salts have been investigated and compared to that of lead salts to establish them as a better alternative to radiation shielding material to the lead element or its salts. The transmission geometry was utilized to measure the mass attenuation coefficient (${\mu}/{\rho}$) of different salts containing lead and bismuth using a high-resolution HPGe detector and different energies (between 81 and 1333 keV) emitted from point sources of $^{133}Ba$, $^{57}Co$, $^{22}Na$, $^{54}Mn$, $^{137}Cs$, and $^{60}Co$. The experimental ${\mu}/{\rho}$ results are compared with the theoretical values obtained through WinXCOM program. The theoretical calculations are in good agreement with their experimental ones. The radiation protection efficiencies, mean free paths, effective atomic numbers and electron densities for the present compounds were determined. The bismuth fluoride ($BiF_3$) is found to have maximum radiation protection efficiency among the selected salts. The results showed that present salts are more effective for reducing the intensity of gamma photons at low energy region.

화염분무열분해법을 이용한 구형의 고결정성 리튬 과잉 양극재 제조 (Synthesis of Li-rich Cathode Material with Spherical Shape and High Crystallinity by Using Flame Spray Pyrolysis)

  • 임성남
    • 신재생에너지
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    • 제20권3호
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    • pp.20-27
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    • 2024
  • A Li-rich cathode material, Li1.167Mn0.548Ni0.18Co0.105O2, with a spherical shape and high crystallinity, is prepared using flame spray pyrolysis. The post-heat treatment condition influences the properties of the prepared material, such as its structure, morphology, and chemical composition, and optimum performance is achieved at 900℃. Various excess Li contents (0-12 wt.%) are introduced in the precursor solution to compensate for volatilized Li during synthesis, bringing it close to the target composition. Compensation for volatilized Li enhances the electrochemical performance, i.e., the Li-compensated sample shows a good discharge capacity of 247 mAh g-1 at a current density of 20 mA g-1 in a potential window of 4.6-2.5 V. In addition, the prepared Li-rich cathode material supplemented with 9 wt.% of the Li source shows increased discharge capacity of 175 and 148 mAh g-1 at 200 and 400 mA g-1, respectively, compared with those of a bare sample (164 and 127 mAh g-1, respectively).