• Title/Summary/Keyword: Mn12

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The Electromagnetic and Thermal Properties of the Mn-Zn Ferrite for the Power Line Communication

  • Lee, Hae-Yon;Kim, Hyun-Sik;Huh, Jeoung-Sub;Oh, Young-Woo
    • KIEE International Transactions on Electrophysics and Applications
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    • v.12C no.4
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    • pp.220-224
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    • 2002
  • The electromagnetic properties and thermal behavior of Mn-Zn ferrite cores for the blocking filter of PLC application were investigated as the function of additives. The highest density and permeability were 4.98 g/㎤ and 8,221, respectively and were obtained to the specimen with composition of MnO 24 mol%, ZnO 25 mol% and Fe$_2$O$_3$51 mol%, added MoO$_3$ of 400 ppm, SiO$_2$ of 100 ppm, and CaO of 200 ppm. The uniform grains were organized, and the microstructures were compacted due to reduction of pores in the specimen. The permeability was increased up to 13,904 as the temperature of specimen increased to 110。C. However, it was decreased precipitously under 100 over 110。C. The exothermic behavior was observed in the frequency range from 1 kHz to 1 MHz, and the maximum temperature of specimen was 102。C at 1 MHz. In the consequence, the Mn-Zn ferrite core developed in this research will maintain the stable electromagnetic properties since the temperature of ferrite core rose to 93 。C in the range of 100 kHz to 450 kHz bandwidth qualified for PLC. The blocking filters were designed for single phase and three phases using the in-line and non-contact core. The best attenuation ratios of -46.46 dB and -73.9 dB were measured in the range of 100 kHz to 450 kHz bandwidth, respectively.

Formation of Retainted Austenite and Mechanical Properties of 4~8%Mn Hot Rolled TRIP Steels (4~8%Mn 열연 TRIP강의 잔류오스테나이트 생성과 기계적 성질)

  • Kim D. E.;Park Y. K.;Lee O. Y.;Jin K. G.;Kim S. J.
    • Korean Journal of Materials Research
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    • v.15 no.2
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    • pp.115-120
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    • 2005
  • The aim of this research is to develop the TRIP aided high strength low carbon steels using reverse transformation process. The $4\~8\%$ Mn steel sheets were reversely transformed by slow heating to intercritical temperature region and furnace cooling to room temperature. The stability of retained austenite depends on the enrichment of carbon and manganese by diffusion during the reverse transformation. The amount of retained austenite formed after reversely transformed at $625^{\circ}C$ for 6 hrs was about $50\;vol.\%$ in the $8\%Mn$ steel. The change in volume fraction of retained austenite with a holding temperature was consistent with the changes in elongation and the strength-ductility combination. The maximum strength-ductility combination of 40,000 $MPa{\cdot}\%$ was obtained when the $8\%Mn$ steel reversely transformed at $625^{\circ}C$ for 12 hrs. However, it's property was significantly decreased at higher holding temperature of $675^{\circ}C$ resulting from the decrease of ductility.

Preparation and Electrical Conductivity of Scandia Stabilized Zirconia by using Ultrasonic Spray Pyrolysis (초음파 분무 열분해법을 이용한 스칸디아 안정화 지르니코니아의 제조와 전기 전도도)

  • Choi, Young-Hoon;Peck, Dong-Hyun;Park, Young-Chul;Lim, Kyoung-Tae;Suhr, Dong-Soo;Wackerl, J.;Markus, T.
    • Journal of the Korean Ceramic Society
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    • v.44 no.12
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    • pp.690-695
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    • 2007
  • Scandia stabilized zirconia (ScSZ) is adapted for electrolyte material of solid oxide fuel cell (SOFC) because of its high ionic conductivity and chemical stability. ScMnSZ1 powder having a composition of $((ZrO_2)_{0.89}(Sc_2O_3)_{0.1}(MnO_2)_{0.01})$ is synthesized by ultrasonic spray pyrolysis (USP) method. Porous ScMnSZ1 powder is obtained by using a pore forming agent. Microstructure and morphology, particle size distribution of porous powder synthesized with 3wt% pore forming agent are investigated. Sintered ScMnSZ1 sample with ground fine powder are also investigated their microstructure and electrical conductivity. The electrical conductivity of sintered ScMnSZ1 samples with ground fine powder was 0.082 S/cm, 0.127 S/cm and 0.249 S/cm at $750^{\circ}C$, $800^{\circ}C$ and $900^{\circ}C$, respectively.

The Energy Flow and Mineral Cycles in a Zoysia japonica and a Miscanthus sinensis Ecosystem on Mt. Kwanak 7. The Cycles of Mn and Zn (관악산의 잔디와 억새 생태계에 있어서 에너지의 흐름과 무기물의 순환 7. Mn,Zn의 순환)

  • 강경미;김정석;장남기
    • Asian Journal of Turfgrass Science
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    • v.11 no.1
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    • pp.1-7
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    • 1997
  • This study was performed to find out the mineral cycles of manganese and zinc in dynamic grassland ecosystems in a steady state condition at the northwest side on Mt. Kwanak. The experimental results may be summarized on the communities of a Zoysia japonica and a Miscanthus sincnsis as follows. As compared with some properties of the surface soils among two semi-natural grasslands, manganese and zinc was greater quantity in a Miscanthus sincnsis than in a Zoysia japonica on Mt. Kwana For the case of steady procluction and release, the ratio of annual mineral production to the amount accumulated on the top of mineral soil in a steady state provides the estimates of release constant k. The release constants of Mn and Zn of the litter were 0.19 and 0. 14 in the Zoysia japon- ica grassland, and were 0.44 and 0.41 in a Miscanthus sincnsis grassland, respectively. The halftimes of Mn and Zn required for the release or accumulation of the litter on the grassland were 3. 65 and 4.95 years in the Zoysia japonica, and were 1.57 and 1.69 years in the Miscanthus sincnsis, respectively. The amounts of annual cycles for Mn and Zn in the grassland ecosystem under the steady-state conditions were 58.60 and 21.46 mg /$m^2$ in a Zoysia japonica, and were 372.12 and 321.49 ing /m$^2$ in a Miscanthus sincnsis grassland. Key words: Zoysia japonica. Miscanthus sincnsis, Mt. Kwanak, Manganese, Zinc, Mineral cycles.

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Effects of Manganese Chloride on Chlorophyll, Free Proline and SOD Activity of Rice Seedling (염화망간 처리가 벼 유묘의 엽록소, 유리 Proline 및 SOD 활성에 미치는 영향)

  • 김상국;이상철
    • Korean Journal of Plant Resources
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    • v.12 no.2
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    • pp.166-169
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    • 1999
  • The experiment was conducted to find the changes of early growth and chemical components such as chlorophyll content, superoxide dismutase(SOD) activity, free proline content on the different manganese chloride concentration(2,500, 3,500 and 4,500ppm) in rice seedling. Root growth was decreased in highest concentration, 4,500 ppm of Mn compared with the control and germination rate was also decreased 43% at 4,500 ppm of Mn. Chlorophyll content was decreased at Mn 4,500ppm with 1.16mg. Free proline content at 3 day after germination in Mn 4,500ppm was highest relative to the other manganese chloride concentrations. SOD activity was gradually increased as manganese chloride concentration was increased. As a result, it was suggested that an increment of free proline and SOD activity results from the higher manganese chloride concentration.

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Sintering and Electrical Properties of Mn-doped ZnO-$TeO_2$ Ceramics

  • Hong, Youn-Woo;Baek, Seung-Kyoung;Hwang, Hyun-Suk;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.49-49
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    • 2008
  • ZnO-based varistors have been widely used for voltage stabilization or transient surge suppression in electric power systems and electronic circuits. Recently, It has reported that the varistor behavior with nonlinear coefficient of 6~17 in Mn-doped ZnO. In this study we have chosen the composition of ZnO-$TeO_2-Mn_3O_4$ (ZTM) system to the purpose of whether varistor behavior appeared in doped ZnO by the solid state sintering or not. We investigated the sintering and electric properties of 0.5~3.0 at% Mn doped ZnO-1.0 at% $TeO_2$ system. Electrical properties, such as current-voltage (I-V), capacitance-voltage (C-V), and impedance spectroscopy were conducted. $TeO_2$ itself melts at $732^{\circ}C$ in air but forms the $ZnTeO_3$ phase with ZnO as increasing temperature and therefore retards the densification of ZnO to $1000^{\circ}C$. The average grain size of sintered samples was at about $3{\mu}m$ and decreased with increasing Mn contents. It was found that a good varistor characteristics were developed in ZTM system sintered at $1100^{\circ}C$ (nonlinear coefficient $\alpha$ ~ 60). The results of C-V characteristics such as barrier height ($\Theta$), donor density ($N_d$), depletion layer (W), and interface state density ($N_t$) in ZTM ceramics were $4\times10^{17}cm^{-3}$, 0.7 V, 40 nm, and $1.6\times10^{12}cm^{-2}$, respectively. It will be discussed about the stability and homogeneity of grain boundaries using distribution parameter ($\alpha$) simulated with the Z(T)"-logf plots in ZTM system.

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Effect of CuO Addition on the Microstructural and Electrical Properties of Ni-Mn Oxide NTC Thermistor (Ni-Mn 산화물 NTC 서미스터의 미세구조와 전기적 특성에 미치는 CuO 첨가의 효과)

  • Kim, Kyeong-Min;Lee, Sung-Gap;Lee, Dong-Jin;Park, Mi-Ri
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.337-341
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    • 2016
  • In this study, $ Ni_{0.79}(Mn_{2.21-x}Cu_x)O_4$ (x=0~0.25) specimens were prepared by using a conventional mixed oxide method. All specimens were sintered in air at $1,200^{\circ}C$ for 12 h and cooled at a rate of $2^{\circ}C/min$ to $800^{\circ}C$, subsequently quenching to room temperature. We investigated the structural and electrical properties of $ Ni_{0.79}(Mn_{2.21-x}Cu_x)O_4$ specimens with variation of CuO amount for the application of NTC thermistors. As results of X-ray diffraction patterns, all specimens showed the formation of a complete solid solution with cubic spinel phase. The relationship between ln ${\rho}$ and the reciprocal of absolute temperature(1/T) for the NTC thermistors was shown linearity, which exhibited the typical NTC thermistor properties. With increasing the amount of CuO, resistivity at room temperature, B-value, and temperature coefficient resistance decreased.

Relationship between Serum Levels of Microminerals and Lipids in Korean Adults on Self-Selected Diet (정상 성인의 혈중 미량무기질과 지질과의 관련성에 관한 연구-충남지역 일부 여대생의 혈중 As, Cr, Mn, Se, Ni을 중심으로-)

  • 최미경
    • Korean Journal of Community Nutrition
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    • v.5 no.2
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    • pp.289-296
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    • 2000
  • The purpose of this study was to investigate the relationship and lipids in healthy adults on self-selected diets. These subjects consisted of 40 female college students residing in Chungnam. Anthropometric measure-ments, diet intake measurements, and blood collection were conducted. Serum concentrations of 5 microminerals(As, Cr, Mn, Se, Ni), lipids(triglyceride, total cholesterol, HDL-cholesterol), and glucose were measured by an ICP spectrometer and biochemical analyzer. The results were as follows. The mean age of the subjects was 22.34 years and the mean weight, height, and BMI were 52.89kg, 161.29cm and 20.34, respectively. The mean serum concentrations appeared to be 14.60ug/dl(As), 1.87ug/dl(Cr), 0.18ug/dl(Mn), 23.50ug/dl(Se), 0.21ug/dl(Ni), 60.73mg/dl(triglyceride), 138.49mg/dl(total cholesterol), 65.95mg/dl(HDL-cholesterol), 60.39mg/dl(LDL-cholesterol) and 88.82mg/dl(glucose). When analyzed by Pearson’s correlation coefficient, the serum concentration of Cr was negatively correlated with Ca and vitamin B12 intake(p〈0.05, p〈0.05) respectively, Mn was negatively correlated with Na intake(p〈0.05), Ni, however, was positively correlated with K intake(p〈0.05). The serum concentration of Se was positively correlated with LDL-cholesterol(p〈0.05), Ni, however, negatively correlated with total cholesterol, HDL-cholesterol, LDL-cholesterol, and glucose, respectively(p〈0.001, p〈0.01, p〈0.05). Further studies are needed to clarify the precise micromineral intakes, nutritional assessment of microminerals, and cause-effect relation of microminerals and serum lipids.

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A Study on the Cementation of Cu, Ni and Co Ions with Mn Powders in Chloride Solution (염산용액중에서 망간분말에 의한 구리, 니켈 및 코발트 이온의 세멘테이션에 관한 연구)

  • 안재우;안종관;박경호
    • Resources Recycling
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    • v.9 no.3
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    • pp.3-12
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    • 2000
  • A Study on the cementation for the recovery of Cu, Ni and Co with Mn metallic powders in leaching solution from the manganese nodule that have removed Fe ions was studied. The results showed that the recovery efficiencies of metal ions with Mn powders increased when the temperature, pH and the concentration of chloride ions were increased in mixed solution. And the recovery efficiencies of Cu was 98% and not changed with the addition amounts of Mn powders but, in case of Co and Ni, the recovery efficiencies were increased with the addition amounts. The particle size of precipitate was about $5\mu\textrm{m}$. From the results of experiment we proposed the two-step cementation process for the recovery of Cu, Ni and Co with Mn powders.

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Variation of Li Diffusion Coefficient during Delithiation of Spinel LiNi0.5Mn1.5O4

  • Rahim, Ahmad Syahmi Abdul;Kufian, Mohd Zieauddin;Arof, Abdul Kariem Mohd;Osman, Zurina
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.128-137
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    • 2022
  • For this study, the sol gel method was used to synthesize the spinel LiNi0.5Mn1.5O4 (LNMO) electrode material. Structural, morphological, electrochemical, and kinetic aspects of the LNMO have been characterized. The synthesized LNMO was indexed with the Fd3m cubic space group. The excellent capacity retention indicates that the spinel framework of LNMO has the ability to withstand high rate charge-discharge throughout long cycle tests. The Li diffusion coefficient (DLi) changes non-monotonically across three orders of magnitude, from 10-9 to 10-12 cm2 s-1 determined from GITT method. The variation of DLi seemed to be related to three oxidation reactions that happened throughout the charging process. A small dip in DLi at the beginning stage of Li deintercalation is correlated with the oxidation of Mn3+ to Mn4+. While two pronounced DLi minima at 4.7 V and 4.75 V are due to the oxidation of Ni2+/Ni3+ and Ni3+/Ni4+ respectively. The depletion of DLi at the high voltage region is attributed to the occurrence of two successive phase transformation phenomena.