• Title/Summary/Keyword: Mn composition

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Microstructural Properties of (Pb)(La,Ce)$TiO_3$ ceramics as a function of $MnO_2$ addition ($MnO_2$ 첨가에 따른 (Pb)(La,Ce)$TiO_3$ 세라믹스의 미세구조특성)

  • Oh, D.U.;Min, S.K.;Yoon, K.H.;Yoo, J.H.;Park, C.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.442-445
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    • 2001
  • In this study, microstructural and dielectric properties of $Pb_{0.83}(La_{0.2}Ce_{0.8})_{0.08}TiO_3$(PCT) ceramics as a function of $MnO_2$ addition were investigated for 30MHz ceramic resonator application. Grain size was gradually increased according to the increase of $MnO_2$ addition amount and showed the highest value of $1.502{\mu}m$ at the 0.9wt% $MnO_2$. Moreover, density showed the highest value of $7.582 g/cm^3$ at the 0.7wt% $MnO_2$.All the composition ceramics,curie temperature was nearly constant around $330^{\circ}C$

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Microstructural Properties of (Pb)(LaCe)$TiO_3$ ceramics as a function of $MnO_2$ addition ($MnO_2$첨가에 따른 (Pb)(La,Ce)$TiO_3$세라믹스의 미세구조특성)

  • 오동언;민석규;윤광희;류주현;박창엽
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.442-445
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    • 2001
  • In this study, microstructural and dielectric properties of P $b_{0.83}$(L $a_{0.2}$C $e_{0.8}$)$_{0.08}$Ti $O_3$PCT ceramics as a function of Mn $O_2$ addition were investigated for 30MHz ceramic resonator application. Grain size was gradually increased according to the increase of Mn $O_2$ addition amount and showed the highest value of 1.502${\mu}{\textrm}{m}$ at the 0.9wt% Mn $O_2$. Moreover, density showed the highest value of 7.582 g/$\textrm{cm}^2$ at the 0.7wt% Mn $O_2$. All the composition ceramics, curie temperature was nearly constant around 33$0^{\circ}C$.EX>.>.>.

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Electrical Properties of Cu/Mn Alloy Resistor with Low Resistance and Thermal Stability (낮은 저항과 열안정성을 가지는 Cu/Mn 합금저항의 전기적 특성)

  • Kim, Eun Min;Kim, Sung Chul;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.365-369
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    • 2016
  • In this paper, we fabricated Cu/Mn alloy shunt resistor with low resistance and thermal stability for use of mobile electronic devices. We designed metal alloy composed of copper (Cu) and manganese (Mn) to embody in low resistance and low TCR which are conflict each other. Cu allows high electrical conductivity and Mn serves thermal stability in this Cu/Mn alloy system. We confirmed the elemental composition of the designed metal alloy system by using energy dispersive X-ray (EDX) analysis. We obtained low resistance below $10m{\Omega}$ and low temperature coefficient of resistance (TCR) below $100ppm/^{\circ}C$ from the designed Cu/Mn alloy resistor. And in order to minimize resistance change caused by alternative frequency on circuit, shape design of the metal alloy wire is performed by rolling process. Finally, we conclude that design of the metal alloy system was successfully done by alloying Cu and 3 wt% of Mn, and the Cu/Mn alloy resistor has low resistance and thermal stability.

Effect of Composition in Cu-Al-Mn Shape Memory Alloys on the Shape Memory Properties and Cold Workability (Cu-Al-Mn계 형상기억합금에서 조성이 형상기억특성 및 냉간가공성에 미치는 영향)

  • Park, Jong Bae;Park, Hyun Gyoon
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.2
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    • pp.59-64
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    • 2014
  • Cu-Al-Mn shape memory alloys of a variety of composition were characterized in terms of shape memory properties and cold workability. Cold workability tested by cold rolling indicated that the alloys solution treated in the ${\alpha}+{\beta}$ region have a higher ductility than those solution treated in the ${\beta}$ region. Also it is known that cold workability increased with the decrease in Al content in the ${\beta}$ region. This seems to be resulted from the fact that Mn addition causes to expand ${\beta}$ region toward lower Al content and lower order-disorder transition temperature, consequently, ${\beta}$ of excellent workability being frozen even at room temperature. Experimental results regarding shape memory showed that the properties were better with a higher Al contents at a given Mn content, which is closely related with martensitic transformation. It is also shown that super elasticity limit was enhanced with decrease in the yield strength of alloys because a lower yield strength seems to initiates slip at the lower applied stress.

A Study on Optimization of Manufacturing Condition for LiNi1/3Mn1/3Co1/3O2-based Cathode Electrode (LiNi1/3Mn1/3Co1/3O2계 정극활물질을 적용한 전극 제조조건 최적화 연구)

  • Kim Hyun-Soo;Kim Sung-Il;Lee Chang-Woo;Moon Seong-In;Kim Woo-Seong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.2
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    • pp.139-144
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    • 2006
  • A fabrication condition of the cathode electrode was optimized in a lithium secondary battery. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ powders were used as a cathode material. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$/Li cells were prepared with a certain formulation and their cycleability and rate-capability were evaluated. Optimum electrode composition simulated from the evaluated value was 86.3: 5.6: 8.1 in mass $\%$ of active material: binder: conducting material. Discharge capacity decreased markedly as the press ratio exceeded $30\%$ during preparation of the electrode. Discharge performance at a high current rate deteriorated abruptly as the electrode thickness was over $120{\mu}m$.

Mechanical Properties of Beta-Sialon Ceramics Prepared from TEOS and Kaolin (TEOS와 카올린으로부터 제조한 $\beta$-Sialon의 기계적 성질)

  • 임헌진;이홍림
    • Journal of the Korean Ceramic Society
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    • v.26 no.5
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    • pp.637-644
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    • 1989
  • Beta-sialon powder(Z=1) was synthesized by the simultaeous reduction and nitridation of the mixed powders of Hadong kaolin and silica. Silicon hydroxide was prepared from Si-alkoxide by a hydrolysis method and amorphous silica was obtained from the calcination of the prepared silicon hydroxide. Hadong kaolin was mixed with both the silicon hydroxide and amorphous silica, respectively. The average particle size was 4${\mu}{\textrm}{m}$ and the morphology of particle was rod-like and equiaxed in the case of beta-sialon powder prepared form Hadong kaolin and silicon hydroxide(COMPOSITION A), whereas the average particle size was 3${\mu}{\textrm}{m}$ and the morphology of particle was equiaxed in the case of beta-sialon powder prepared from Hadong kaolin and amorphous silica(COMPOSITION B). The synthesized beta-sialon powders were hot-pressed at 175$0^{\circ}C$ for 2 hours under 30 MPa in a nitrogen atmosphere after YAG composition(8wt%) was added to these powders as a sintering agent. The hot-pressed specimens were annealed a 140$0^{\circ}C$ for 4 hours in a nitrogen atmosphere. The mechanical properties of sintered bodies were investigated in terms of M.O.R., fracture toughness and hardness. The measured values are as follows. COMPOSITION A : M.O.R. 508MPa, KIC 3.5MN/m3/2, hardness 13.6GPa. COMPOSITION B : M.O.R. 653MPa, KIC 5.4MN/m3/2, hardness 13.5GPa.

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Effect of Chemical Composition on the Microstructure and Tensile Property in TRIP-assisted Multiphase Steels (TRIP형 복합조직강의 미세조직 및 인장성질에 미치는 화학조성의 영향)

  • Lee, K.Y.;Jang, W.Y.;Kang, J.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.16 no.3
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    • pp.127-133
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    • 2003
  • The effect of chemical composition on the microstructural change and tensile property in TRIP-assisted steels with different chemical composition was investigated by using SEM, TEM, XRD and UTM. As a result of microscopic observation, the morphology of retained austenite could be identified as two types; a granular type in a steel containing higher Si and a film type in a steel having higher C. For the case of higher C-containing steel with a tensile strength of 860 MPa and a total elongation of 38%, film-typed retained austenite could be observed between lath bainitic ferrite. Actually, metastable retained austenite was a requisite for the good formability, which means that chemical composition plays a significant role in the microstructure and tensile property of TRIP-assisted steels. With respect to tensile property, the steels containing suitable Si and Mn, respectively, showed a typical TRIP effect in stress-strain curve, while a steel containing higher Mn content exhibited the similar behavior shown in dual phase steel.

Comparison of Metal Contents in Respirable Particulate Mass by Particle Size and Season in Seoul and Asan City (서울.아산지역 호흡성먼지의 금속함량에 관한 연구)

  • Choi, Yun-Na;Jeon, Yong-Taek;Jang, Bong-Ki;Yang, Won-Ho;Yom, Yoon-Ki;Son, Bu-Soon
    • Journal of environmental and Sanitary engineering
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    • v.23 no.1
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    • pp.33-48
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    • 2008
  • The purpose of this study was to characterize background mass concentration of $PM_{10},\;PM_{2.5}$ and metallic composition from June 2004 to June 2005 in comparison with Seoul and Asan city. The results were as follows: 1. Annual mean of $PM_{10}$ concentrations in Seoul and Asan were $56.95({\pm}25.63){\mu}g/m^3,\;57.02({\pm}27.22){\mu}g/m^3$ respectly. 2. Annual mean of $PM_{2.5}$ concentrations in Seoul and Asan were $46.97({\pm}40.36){\mu}g/m^3,\;42.16({\pm}21.79){\mu}g/m^3$ respectly. 3. The average $PM_{2.5}/PM_{10}$ ratio was 0.82 in Seoul and 0.74 in Asan city. 4. The concentration of $PM_{10},\;PM_{2.5}$ were the highest in spring and the lowest in summer. Asan was higher than Seoul in spring and summer. 5. The results showed that average $PM_{10}$ composition order as Si>Fe>Pb>Zn>Mn in Seoul and Si>Fe>Zn>Pb>Mn in Asan. The concentration of metals in $PM_{10}$ of Seoul that Cr, Cu, Fe, Mn were high in spring and Zn was low in Fall. Fe, Mn were high in spring of Asan. 6. The results showed that average $PM_{2.5}$ composition order as Si>Pb>Fe>Zn>Mn in Seoul and Si>Fe>Pb>Zn>Cr in Asan. The concentration of metals in $PM_{2.5}$ of Seoul that Cr was high in spring. 7. The result showed that relation between Cr and Cu, Cu and Fe, Fe and Mn, Mn and Zn, Zn and Si in Seoul, Cr and Zn, Cu and Pb, Zn and Pb, Pb and Mn in Asan. The result showed that $PM_{10}$ concentration exceeding $50{\mu}g/m^3$(US-EPA Standard) and $PM_{2.5}$ concentration exceeding $15{\mu}g/m^3$(US-EPA Standard). In urban area, the monitoring of $PM_{2.5}$ permits the anthropogenic sources and the interference of natural sources with respect to $PM_{10}$ measurements.

Fabrication and characterization of Mn-Si thermoelectric materials by mechanical alloying (MA법에 의한 Mn-Si계 초미세 열전재료의 제조 및 평가)

  • Lee, Chung-Hyo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.6
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    • pp.246-252
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    • 2011
  • The semiconducting $MnSi_{1.73}$ compound has been recognized as a thermoelectric material with excellent oxidation resistance and stable characteristics at elevated temperature. In the present work, we applied mechanical alloying (MA) technique to produce $MnSi_{1.73}$ compound using a mixture of elemental manganese and silicon powders. The mechanical alloying was carried out using a Fritsch P-5 planetary mill under Ar gas atmosphere. The MA powders were characterized by the X-ray diffraction with Cu-$K{\alpha}$ radiation, thermal analysis and scanning electron microscopy. Due to the observed larger loss of Si relative to Mn during mechanical alloying of $MnSi_{1.73}$, the starting composition of a mixture Mn-Si was modified to $MnSi_{1.83}$ and then $MnSi_{1.88}$. The single $MnSi_{1.73}$ phase has been obtained by mechanical alloying of $MnSi_{1.88}$ mixture powders for 200 hours. It is also found that the grain size of $MnSi_{1.73}$ compound powders analyzed by Hall plot method is reduced to 40 nm after 200 hours of milling.

A Study on the Rroperties of the Dusts from Ferroally Manufacture (합금철제조공정에서 발생되는 분진의 물성)

  • Shin, Kang-Ho;Song, Young-Jun;Hyun, Jong-Yeong;Cho, Young-Keun;Suh, Soon-Il;Park, Charn-Hoon;Cho, Dong-Sung
    • Resources Recycling
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    • v.8 no.3
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    • pp.9-17
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    • 1999
  • The study investrgated the properti es of lh$\xi$ dust~ from felToalloy manufacture, The chemical composition, composItron material, particle size and shapes of the bulk dust, sized dust and magnetically separated dust were llivestigated. As the result, we s suppose that the dust from HLgh Carbon Fenomauganesc Manufacturing Process is not sufficient as soource material of Mn because of the low Mn conteut (13.5%) aud complicated composition material The dust from Bag Filter of AOD Process is m mainly made up of $0.2~2\mu\textrm{m}$ $Mn_3O_4$ (Hausmatmite) particle in spherical shape and the Mn content is 63.1%. The dust from Cooler of AOD Process is mainly made up of coarse $Ca(OH)_2$ Mn, $Fe_yO_2$ $SiO_2$ and fine $Mn_3O_1$.

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