• Title/Summary/Keyword: Mn and Cu addition

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Dielectric and Piezoelectric Properties of Low temperature sintering PSN-PZT ceramics with $CeO_2$ addition ($CeO_2$첨가에 따른 저온소결 PSN-PZT세라믹스의 유전 및 압전 특성)

  • Chung, Kwang-Hyun;You, Ju-Hyun;Oh, Dong-On;Song, Hyun-Seon;Jeong, Hye-Seung;Park, Chang-Yub;Lee, Duck-Chool
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.300-303
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    • 2003
  • [ $0.91(PSN-PZT)-0.05BF-0.04PNW+0.3wt%MnO_2+0.6wt%CuO+xwt%CeO_2$ ] ceramics were fabricated with the variations of $CeO_2$ addition at the sintering temperature of $950^{\circ}C$ and their microstructure and dielectric and piezoelectric characteristics were investigated. As the amount of $CeO_2$ addition increased, the grain size, density and electromechanical coupling factor(kp) were increased and the mechanical quality factor(Qm) was decreased. At the $0.3wt%CeO_2$, density, grain size and electromechanical factor(kp) showed the maximum value of $7.87g/cm^3$, $3.22{\mu}m$ and 0.5, respectively. However, mechanical quality factor(Qm) showed the minimum value of 807 at the $0.5wt%CeO_2$.

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Dielectric and Piezoelectric Properties of Low Temperature Sintering PSN-PZT Ceramics with CeO2 Addition (CeO2첨가에 따른 저온소결 PSN-PZT세라믹스의 유전 및 압전 특성)

  • 류주현;정광현;정영호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.5
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    • pp.481-485
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    • 2004
  • 0.91 (PSN-PZT) -0.05BF -0.04PNW+0.3wt%MnO$_2$+0.6wt%CuO+xwt%CeO$_2$ ceramics were fabricated with the variations of CeO$_2$addition at the sintering temperature of 95$0^{\circ}C$ and their microstructure, dielectric and piezoelectric characteristics were investigated. As the amount of CeO$_2$ addition increased, the grain size, density and electromechanical coupling factor(k$_{p}$) were increased and the mechanical quality factor(Q$_{m}$ ) was decreased. At the 0.3 wt% CeO$_2$, the density, grain size, electromechanical coupling factor(k$_{p}$), and pizoelectric constants(d$_{33}$, g$_{33}$) showed the maximum value of 7.87 g/㎤, 3.22 $\mu\textrm{m}$, 0.5, 289 pC/N, and 22.2 ㎷ㆍm/N, respectively. However, mechanical quality factor(Q$_{m}$ ) showed the minimum value of 807 at the 0.5 wt% CeO$_2$.$.EX>.EX>.

Characterization of Extracellular Protease Secreted from Chryseobacterium sp. JK1 (Chryseobacterium sp. JK1이 분비하는 세포외 단백질분해효소 특성)

  • Lee, Yu-Kyong;Oh, Ji-Sung;Roh, Dong-Hyun
    • Korean Journal of Microbiology
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    • v.49 no.1
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    • pp.78-82
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    • 2013
  • A novel Chryseobacterium sp. JK1 strain isolated from soil had been reported that this isolate produced large amount of extracellular protease at mesophilic temperature in previous study. The optimal temperature and pH of extracellular protease were $40^{\circ}C$ and 7.0, respectively, showing narrow range of optimal temperature and relatively broad activity from pH 6.0 to 9.0. In addition, the protease showed greatest activity against skim milk and lowest against bovine serum albumin (BSA). The protease strongly inhibited by ethylenediaminetetraacetic acid (EDTA), ethylene glycol tetraacetic acid (EGTA) or phenylmethylsulfonyl fluoride (PMSF), and addition of cation $Ag^+$ or $Cu^{2+}$, and slightly inhibited by $Al^{3+}$. No significant inhibition was found with pepstatin, and addition of cation, $K^+$, $Ca^{2+}$, $Na^+$, $Fe^{2+}$ or $Mg^{2+}$. On the contrary, protease was enhanced by addition of divalent cation $Mn^{2+}$ (5 mM). Zymography analysis of concentrated culture supernatant revealed two major bands at 67 and 145 kDa. These results suggest that Chryseobacterium sp. JK1 strain produced extracellular neutral serine proteases which could apply in food industry.

Effect of Brown Algae (Undaria pinnatifida)-Noodle on Oxygen Radicals and Their Scavenger Enzymes in Liver of Sprague-Dawley Rats (미역 (Undaria pinnatifida) 국수의 투유가 랫트 간장중의 활성산소 및 제거효소에 미치는 영향)

  • CHOI Jin-Ho;KIM Dae-Ik;PARK Soo-Hyun;KIM Dong-Woo;BEAK Yeong-Ho;KIM Chang-Mok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.2
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    • pp.87-92
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    • 2000
  • This study was designed to investigate the effects og $10{\%},\;20{\%}\;and\;40{\%}$-addition of functional brown algae (FBA)-noodles on oxygen radicals and their scavenger enzymes in liver of Sprague-Dawley(SD) male rats. Hydroxyl radicals$({\cdot}OH)$ formations were significantly inhibited$(20{\~}35{\%}\;and\;12{\~}20{\%})$ in liver mitochondria and microsomes of rats administered $0{\%},\;20{\%}\;and\;40{\%}$ FBA-noodles compared with that of control group. Significant differences in $H_2O_2$ formations of liver microsome in these FBA-noodles fed groups could not be obtained, but superoxide-radical $(O_2^({\cdot}-))$ formations of liver cytosol resulted in a significant decrease about $10{\%}\;in\;20{\%}\;and\;40{\%}$ FBA-noodles compared with control group. Mn-SOD activities in liver mitochondria were significanlty increased $(10{\~}15{\%})$ in the groups fed $10{\%},\;20{\%}\;and\;40{\%}$ FBA-noodles, while a group administered $40{\%}$ FBA-noodle only resulted In a significant increases $(about 12{\%})$ in Mn-SOD activity of liver microsomes compared with control group. Cu, Zn-SOD activities in liver cytosol were significantly increased $(10{\~}20{\%})\;in\;10{\%},\;20{\%}\;and\;40{\%}$ FEA-noodles compared with control group. Administration of $10{\%},\;20{\%}\;and\;40{\%}$ FBA-noodles resulted in a marked increases$(20{\~}40{\%})$ in liver cytosolic glutathione peroxidase (GSHPx) compared with control group. Significant differences in lipid peroxide (LPO) levels of mitochondria and microsomes in $10{\%}$ FBA-noodle could not be obtained, while LPO levels of $20{\%} and 40{\%}$ FBA-noodles were significantly inhibited about $10{\%}$ in mitochondria and microsomes compared with control group. These results suggest that these FBA-noodles may play a desirable role in attenuating an oxygen radical formations and increasing a scavenger enzymes activity by some brown algae (Undaria pinnatifida) components.

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Change of Heavy Metals and Sediment Facies in Surface Sediments of the Shihwa Lake (시화호 표층퇴적물의 중금속 및 퇴적상 변화)

  • 최만식;천종화;우한준;이희일
    • Journal of Environmental Science International
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    • v.8 no.5
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    • pp.593-600
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    • 1999
  • In order to determine the changes of sediment facies and metal levels in surface sediments after the construction of Shiwha Lake, surface sediments were sampled at 8 sites located on the main channel monthly from June, 1995 to August, 1996 and analysed for 12 metals (Al, Fe, Mn, V, Cr, Co, Ni, Cu, Zn, Cd, As and Pb) by ICP/AES and ICP/MS. Two groups of sampling sites(the inner lake with 3 sites and the outer lake with 5 sites) are subdivided by the surface morphology ; the inner lake is a shallow channel area with a gentle slope, while the outer lake is relatively deep and wide channel with a steep slope which has many small distributaries. After the construction of dam, fine terrestrial materials were deposited near the outer lake, which resulted in the change of major sediment facies from sandy silt to mud. With the deposition of fine sediments in the outer lake, anoxic water column induced the formation of sulfide compounds with Cu, Cd, Zn and part of Pb. Metal (Cr, Ni, Cu, Zn and Cd) contents in sediments increased up to twice within 2 years after the construction of dam. This is due to the direct input of industrial and municipal wastes into the lake and the accumulation of metals within the lake. In addition, frequent resuspension of contaminated sediments in a shallow part of the lake may make metal-enriched materials transport near the outer lake with fine terrestrial materials. As the enrichment of Cu, Zn, Cd and part of Pb in the Shiwha Lake may be related to the formation of unstable sulfide compounds by sulfate reduction in anoxic water or sediment column, the effect of mixing with open coastal seawater is discussed.

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Change of Optical Properties in Zinc Oxide-Based Glasses including Metal Oxides for Transparent Dielectric

  • Seo, Byung-Hwa;Kim, Hyung-Sun;Suh, Dong-Hack
    • Korean Journal of Materials Research
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    • v.19 no.10
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    • pp.533-537
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    • 2009
  • This paper presents a new method for the improvement of color temperature without the change of the driving scheme using transparent dielectric layers with various metal oxides (CeO$_2$, Co$_3$O$_4$, CuO, Fe$_2$O$_3$, MnO$_2$, NiO) in plasma display panels (PDP). In this study, we fabricated ZnO-B$_2$O$_3$-SiO$_2$-Al$_2$O$_3$ glasse with various metal oxides and examined the optical properties of these glasses. As the metal oxides were added to the glasses, the visible transmittances of the dielectric layers decreased and the transmittances in special wavelength regions were reduced at different rates. The change of the transmittance in each wavelength range induced the variation of the visible emission spectra and the change of the color temperature in the PDP. The addition of Co$_3$O$_4$ and CuO slightly decreased the intensity of the blue light, but the intensities of the green and the red light were significantly decreased. Therefore, the color temperature can be improved from 6087K to 7378K and 7057K, respectively.

Purification and Characterization of an Extracellular Alkaline Protease from Aspergillus niger C-15

  • Kim, Jeong-Dong
    • Mycobiology
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    • v.32 no.2
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    • pp.74-78
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    • 2004
  • An alkaline protease produced by Aspergillus niger C-15 was purified and characterized. The enzyme was purified 19.41-fold with a specific activity of 74150 U/mg and a recovery of 34.4% by gel filtration and ion exchange chromatography. The molecular weight of the enzyme was estimated to be 34 kDa. The optimum pH and temperature for the protease activity were pH 8.0 and $60^{\circ}C$, respectively. The enzyme activity inhibited by EDTA suggests that the preparation contains a metalloprotease. The enzyme activity of the metalloprotease was completely inhibited by 5 mM $HgCl_2$ and $FeCl_3$, while partially inhibited by $CuSO_4$, and $MnCl_2$. When polyols such as glycerol, mannitol, sorbitol and xylitol, were added to the reaction medium, most polyols tested enhanced protease activity. Especially, glycerol showed the highest effect. The alkaline metalloprotease was stable at high temperature and retained more than 90% of the initial activity at $60^{\circ}C$ and 86.4% under addition of glycerol.

Changes of chemical components and antioxidant activities in Hizikia fusiformis(Harvey) OKAMURA with blanching times (데침시간에 따른 톳의 주요성분 및 항산화 활성의 변화)

  • 김진아;이종미
    • Korean journal of food and cookery science
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    • v.20 no.2
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    • pp.219-226
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    • 2004
  • This study was performed to investigate the change of chemical components and antioxidant activities in Hizikia fusiformis(Harvey) OKAMURA with blanching times. For chemical composition, the contents of minerals (K, Ca, Na, Mg, Fe, Cu, Mn and Zn), vitamins (vitamin C, ${\beta}$-carotene and ${\alpha}$-tocopherol) and total polyphenol were analyzed. The antioxidant activity was determined through free radicals (DPPH radical, superoxide anion radical, hydroxyl radical and hydrogen peroxide) scavenging activity and linoleic acid peroxidation inhibitory activity. As the blanching time increased, the contents of all minerals, vitamin C and total polyphenol decreased. However ${\beta}$-carotene and ${\beta}$-tocopherol were not affected by the blanching time. In addition antioxidant activities decreased with increasing blanching time.

Characteristics of Ni/3d Series Transition Metal/γ-Al2O3 Catalysts and their Hydrogen Production Abilities from Butane Steam Reforming

  • Lee, Jun-Su;Choi, Byung-Hyun;Ji, Mi-Jung;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3281-3289
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    • 2011
  • The materials composed of the 3d series transition metals are introduced into the hydrocarbon steam-reforming reaction in order to enhance the $H_2$ production and abruptly depress the catalytic deactivation resulting from the strong sintering between the Ni component and the ${\gamma}-Al_2O_3$ support. The conventional impregnation method is used to synthesize the Ni/3d series metal/${\gamma}-Al_2O_3$ materials through the sequentially loading Ni source and the 3d series metal (Ti, V, Cr, Mn, Fe, Co, Cu, and Zn) sources onto the ${\gamma}-Al_2O_3$ support. The Mnloaded material exhibits a significantly higher reforming reactivity than the conventional Ni/${\gamma}-Al_2O_3$ and the other Ni/3d series metal/${\gamma}-Al_2O_3$ materials. Particularly the addition of Mn selectively improves the $H_2$ product selectivity by eliminating the formation of $CH_4$ and CO. The $H_2$ production is maximized at a value of 95% over Ni(0.3)/Mn(0.3)/${\gamma}-Al_2O_4$(1.0) with a butane conversion of 100% above $750^{\circ}C$ for up to 55 h.

Enzymatic Properties of Intracellular Adenosine Deaminase from Nocardioides sp. J-326TK

  • Hong-Ki Jun;Tae-Sook Kim
    • Journal of Life Science
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    • v.9 no.1
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    • pp.64-68
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    • 1999
  • The properties of purified intracellular adenosine deaminase (adenosine aminohydrolase, EC 3.5.4.4) of Nocardioides sp. J-326TK isolated from soil have been studied. The enzyme deaminated adenosine and 2`-deoxyadenosine and the respective {TEX}$K_{M}${/TEX} values were 4.0×{TEX}$10^{-4}${/TEX} M and 5.0× {TEX}$10^{-4}${/TEX} M, but the enzyme was not active on 8-bromoadenosine, 6-methylaminopurine riboside, ATP, ADP, 2`-AMP, 3`-AMP, 5`-AMP, dAMP, cAMP, NAD, FAD, NADP and adenine. The enzyme activity was strongly inhibited by the addition of {TEX}$Hg^{2+}${/TEX} and {TEX}$Ag^{+}${/TEX}, {TEX}$Cu^{2+}${/TEX}, {TEX}$Co^{2+}${/TEX} and {TEX}$Mn^{2+}${/TEX} also inhibited the activity but much less extent. The effect of alkyl reagents, metal chelating reagents and certain other compounds on the enzyme activity were also examined. No reagent activated the enzyme. On the contrary, the enzyme reaction was slightly inhibited by o-phenanthroline and 6-benzyladenosine.

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