• Title/Summary/Keyword: Mn 조성

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Phase Analyses and Magnetic Properties of $Mn-(M,AI)_{1-x}(Bi,Sb)_x$(M=Cu, Fe) Alloy Systems ($Mn-(M, AI)_{1-x}(Bi, Sb)_x$ (M=Cu, Fe)합금계의 상 분석 및 자기적 성질에 관한 연구)

  • Park, Jung-Eon;Go, Gwan-Yeong;Yun, Seok-Gil
    • Korean Journal of Materials Research
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    • v.6 no.1
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    • pp.90-98
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    • 1996
  • Mn((Cu0.66AI0.34)1-x(Bi0.3Sb0.7)x) 및 Mn((Fe0.66AI0.34)1-x(Bi0.3Sb0.7)x) 합금계의 상의 변화와 자기적 특성을 조사하였다. Mn((Cu, SI)(Bi, Sb)) 합금계는 Bi상, MnSb상, MnBi상, k-상, Heuser상, Mn2Sb 및 $\beta$-Mn상의 혼합상으로 이루어졌으며 x가 증가함에 따라 Bi상과 Mn2Sb상이 증가하고 K-상, Heusler상 및 $\beta$-Mn상이 줄어들거나 사라졌다. 자기적 성질은 자성을 띄는 MnSb상, MnBi상, Mn2Sb상, k-상 및 Hseusler상과 비자성인 Bi상과 $\beta$-Mn상의 상대적 분율에 의해 결정됨을 알 수 있었고, 150K-200K 부근에서 그 이하로 온도가 감소함에 따라 자화값이 급격히 감소하는 현상이 나타났다. Mn((Fe, AI)(Bi, Sb))합금계는 Bi상, MnSb상, MnBi상, MnBi상,$\beta$-Mn상, k-상 및 Mn2Sb상의 혼합상으로 나타났으며, 자기적 성질은 조사한 전 조성에서 강자성을 띄고 있음을 알 수 있었다.

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Electrical Conductivity Change of (Mn, X) oxide by Anodic Deposition (Anodic deposition법으로 제조한 (Mn, X)산화물의 전기전도도 변화)

  • Kim, Bong-Seo;Lee, Dong-Yoon;Lee, Hee-Woong;Chung, Won-Sub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.386-387
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    • 2005
  • anodic deposition법으로 제조된 $MnO_2$와 (Mn, Zn) 산화물의 전도도를 측정하였다. 제조된 Mn 산화물의 조성은 XRD와 EDS를 이용하여 $MnO_2$ 와 Mn 복합산화물로 확인되었다. DV-Xa법으로 계산된 이론 전자상태 계산 결과 천이금속을 첨가하게 되면, Mn 복합 산화물의 에너지 갭이 감소하는 것으로 나타났다. anodic deposition법으로 제조된 $MnO_2$와 Mn 복합 산화물의 전기전도도를 비교하면 천이금속이 첨가된 복합 산화물의 특성이 우수한 것으로 나타났다.

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Development of the EM Wave Absorber for ETC of ITS (ITS의 ETC용 전파흡수체 개발)

  • Song, Young-Man;Choi, Chang-Mook;Lee, Dae-Hee;Kim, Dong-Il
    • Journal of Navigation and Port Research
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    • v.31 no.8
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    • pp.671-674
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    • 2007
  • In this paper, the EM wave absorber was designed and fabricated for ETC system, because ETC system has some problems including signal error and system-to-system interference. We fabricated some samples in different composition ratio of MnZn-ferrite, Carbon and CPE, confirmed that optimum composition ratio of Mn2n-ferrite, Carbon, CPE was 40 : 15 : 45 wt%. Complex relative permittivity and complex relative permeability was calculated by the measured data. And absorption abilities were simulated according to different thickness of the EM wave absorbers using complex relative permittivity and permeability. The EM wave absorber was fabricated based on simulated data Simulated and measured values agree well. As a result, the developed EM wave absorber has a thickness of 3.38 mm and absorption ability over 20 dB at 5.8 GHz.

Properties and defects of Mn-Zn Ferrite single crystals grown by the modified process (연속 성장법으로 성장된 Mn-Zn Ferrite 단결정 특성 및 결함)

  • 정재우;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.1 no.2
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    • pp.23-33
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    • 1991
  • Mn - Zn Ferrite has the natural characteristics of incongruent melting and the zinc oxide evaporation while the crystal is being grown. As a result of these, it comes into existence to be a non-uniform distribution of cations along the crystal growth axis and also Pt particles are usually precipitated into the crystals in Bridgman method since the melt zone is maintained for a long time in the crucible. These have bad effects on the magnetic properties of ferrites. But, to overcome these faults and then acquire the better single crystals. new modified growth method was developed and the growth factors were investigated as following: melt height in the crucible, surface tension and density of melt, the behavior of melt at interface, the shapes of crucible and solid -liquid interface, powder feeding rate, and the crystal growing speed. In additon, when we analyzed the compositional fluctuations of grown crystals, they were supressed within 1.5 mol% $Fe_20_3$, 2 mol% MnO, ZnO respectively with comparing to initial composition of crystal and the microstructures of crystals on the(110) plane were observed by optical microscope through the chemical etching technique and the magnetic properties were determined.

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Variations in Morphological and Geochemical Characteristics in Manganese Nodules from the East Siberian Arctic Shelf with Varying Water Depths (동시베리아해 대륙붕에서 산출되는 망가니즈단괴의 수심에 따른 형태학적·지화학적 특성 변화)

  • Hyo-Jin Koo;Hyen-Goo Cho;Sangmi Lee;Gi-Teak Lim;Hyo-Im Kim
    • Economic and Environmental Geology
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    • v.56 no.1
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    • pp.1-11
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    • 2023
  • In this study, we explore the morphological and geochemical characteristics for 440 manganese nodules collected from two different water depths [ARA12B-St52 (150 m, n = 239) and ARA12B-St58i (73 m, n = 201)] on the continental shelf of the East Siberian Sea from the ARA12B expedition in 2021. We also discussed the variations in the characteristics of manganese nodules with varying water depths in the Arctic Sea. The sizes of the nodules are generally greater than 3 cm at both sites. However, there is an obvious difference in the morphology with water depths. For the nodules collected at 150 m, brown-black colored tabular, tube, and ellipsoidal shapes with a rough surface texture are dominant. On the other hand, yellow-brown tabular shapes with a smooth surface texture are common for the nodules collected at 73 m. Furthermore, the slope of trend line between size and weight is significantly different at both sites: particularly, the slopes of nodules at 150 and 73 m are 1.60 and 0.84, respectively. This indicates the difference in the internal structure, porosity, and constituting elements between both nodules. Micro X-ray Flourescence (µ-XRF) results clearly demonstrate that the internal textures and chemical compositions are different with water depths. The nodules at 150 m are composed of a thick Mn-layer and a thin Fe-layer centered on the nucleus, while the nodules at 73 m are alternately grown with thin Mn- and Fe- layers around the nucleus. The average chemical compositions obtained by µ-XRF are 40.6 wt% Mn, 5.2 wt% Fe, and 7.9 Mn/Fe ratio at 150 m, and 10.3 wt% Mn, 19.0 wt% Fe, and 0.6 Mn/Fe ratio at 73 m. The chemical compositions of the nodules at 150 m are similar to those of nodules from the Peru Basin in the Pacific Ocean, while the compositions of the nodules at 73 m are similar to those of nodules from the Cook Islands or the Baltic Sea. The observed morphological and geochemical characteristics of the nodules show a clear difference at the two sites, which indicates that the aqueous conditions and formation processes of the nodules in the Arctic Sea vary with the water depths.

A Study on Phosphor Synthetic and Low Temperature Photoluminescence Spectrum (저온 photoluminescence 스펙트럼 및 형광체 합성에 관한 연구)

  • Kim, Soo-Yong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.4
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    • pp.10-16
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    • 2010
  • In this paper, synthesis here Mn add to Ar injection the state and a vacuum an atomosphere $ZnGa_2O_4$ : Mn, ZnO and $Ga_2O_3$ power of 1 : 1 mole ratio mixture. Manufacture a close examination of oxygen a component variation luminescence a specific character reach an in fluence of $ZnGa_2O_4$ : Mn, luminescence spectrum observation also an explanation of Mn site symmetry and at luminescence spectrum reach an influence from low temperature photoluminescence spectrum.

Solderability and BGA Joint Reliability of Sn-Ag-Cu-In-(Mn, Pd) Pb-free Solders (Sn-Ag-Cu-In-(Mn, Pd) 무연솔더의 솔더링성과 BGA 접합부 신뢰성)

  • Jang, Jae-Won;Yu, A-Mi;Lee, Jong-Hyun;Lee, Chang-Woo;Kim, Jun-Ki
    • Journal of the Microelectronics and Packaging Society
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    • v.20 no.3
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    • pp.53-57
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    • 2013
  • Although the lowering of Ag content in Sn-3.0Ag-0.5Cu is known to improve the mechanical shock reliability of the solder joint, it is also known to be detrimental to the solderbility. In this study, the quaternary alloying effect of In and the minor alloying effects of Mn and Pd on the solderability, thermal cycling and mechanical shock reliabilities of the low Ag content Sn-1.2Ag-0.7Cu solder were investigated using board-level BGA packages. The solderability of Sn-1.2Ag-0.7Cu-0.4In was proved to be comparable to that of Sn-3.0Ag-0.5Cu but its thermal cycling reliability was inferior to that of Sn-3.0Ag-0.5Cu. While the 0.03 wt% Pd addition to the Sn-1.2Ag-0.7Cu-0.4In decreased the solderability and reliabilities of solder joint, the 0.1 wt% Mn addition was proved to be beneficial especially for the mechanical shock reliability compared to those of Sn-3.0Ag-0.5Cu and Sn-1.0Ag-0.5Cu compositions. It was considered to be due that the Mn addition decreased the Young's modulus of low Ag content Pb-free solders.

Development of EM Wave Absorber for Suppression Noise from PCB Using Sendust and Mn-Zn Ferrite (Sendust와 Mn-Zn Ferrite를 이용한 PCB로부터의 전자파 방사 억제용 전파흡수체 개발)

  • Yoon, Sang-Gil;Kim, Dong-Il;Song, Young-Man;Park, Soo-Hoon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.19 no.2
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    • pp.244-249
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    • 2008
  • In this paper, we designed and fabricated the EM wave absorber consists of Sendust and Mn-Zn ferrite for suppressing EM wave noise from PCB in ISM(Industrial, Scientific and Medical) band of 2.4 GHz. We fabricated several samples in different ratios of Sendust to Mn-Zn ferrite with CPE(Chlorinated Ploy-ethylene) as binder and confirmed that optimum composition ratio of absorbing materials was Sendust. Mn-Zn ferrite : CPE=70:5:20 wt.%. The absorbing abilities were simulated according to different thickness of EM wave absorber as the function of material constants calculated by measured data. Measured absorption ability was analyzed and compared with simulated result. The simulated result agree well with the measured ones. As a result, the developed EM wave absorber with thickness of 0.85 mm has absorption ability of 5.4 dB at 2.4 GHz and over 3 dB in frequency rage of 1.4$\sim$4.1 GHz.

Crystal Structure of $\textrm{ZrV}_{x}\textrm{Mn}_{1-x-y}\textrm{Ni}_{1+y}$ Laves Phase Alloys for MH Battery Application (MH전지용 $\textrm{ZrV}_{x}\textrm{Mn}_{1-x-y}\textrm{Ni}_{1+y}$ Laves합금의 결정구조)

  • Kim, Won-Baek;Seo, Chang-Yeol;Choe, Guk-Seon;Kim, In-Gon
    • Korean Journal of Materials Research
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    • v.7 no.3
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    • pp.234-243
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    • 1997
  • The crystal structure of arc melted $ZrV_{x}Mn_{1-x}Ni_{1.0},\;ZrV_{x}Mn_{0.8-x}Ni_{1.2},\;ZrV_{x}Mn_{0.6-x}Ni_{1.4}$ alloys which are known to have AB2 type Laves structure was investigated. They had mixed phases of C14 and C15. The radius ratio ($r_{A}/r_{B}$) of atoms in A site to that of B site was found to be an important parameter in explaining the omposition dependence of the crystal structure The C15 structure showed a linear increase with the ratio in as-cast conditions. However, the annealed alloys revealed a definite ratio at which the stability of both phases are divided distinctly. The composition of the alloys could be closely controlled by maintaining the argon pressure in the chamber over 1 arm during arc melting. In contrast, the alloy ingot melted in VIM showed a significant loss of hln.

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