• Journal of Electrochemical Science and Technology
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• v.11 no.4
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• pp.411-420
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• 2020

Undesirable interfacial reactions between the cathode and sulfide electrolyte deteriorate the electrochemical performance of all-solid-state cells based on sulfides, presenting a major challenge. Surface modification of cathodes using stable materials has been used as a method for reducing interfacial reactions. In this work, a precursor-based surface modification method using Zr and Mo was applied to a LiNi_0.6Co_0.2Mn_0.2O₂ cathode to enhance the interfacial stability between the cathode and sulfide electrolyte. The source ions (Zr and Mo) coated on the precursor-surface diffused into the structure during the heating process, and influenced the structural parameters. This indicated that the coating ions acted as dopants. They also formed a homogenous coating layer, which are expected to be layers of Li-Zr-O or Li-Mo-O, on the surface of the cathode. The composite electrodes containing the surface-modified LiNi_0.6Co_0.2Mn_0.2O₂ powders exhibited enhanced electrochemical properties. The impedance value of the cells and the formation of undesirable reaction products on the electrodes were also decreased due to surface modification. These results indicate that the precursor-based surface modification using Zr and Mo is an effective method for suppressing side reactions at the cathode/sulfide electrolyte interface.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.329-330
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• 2006

본연구에서는 초음파 모터 등의 고출력 액츄에이터에 응용 가능한 $0.4Pb(Ni_{1/3}Nb_{2/3})O_3$-$0.6Pb(Zr_{0.405}Ti_{0.595})O_3$ + 0.25wt% $Fe_2O_3$ 조성시스템에 $MnO_2$ (0~1 wt.%)첨가하여 압전, 유전특성 및 미세구조에 관해 고찰하였다. 본조성을 $1125{\sim}1175^{\circ}C$ 온도에서 2시간 소결하여 시편을 제조하였으며 이의 결정구조 및 미세조직을 분석하였다. $MnO_2$ 첨가량 증가에 따라 압전 상수와 전기기계결함계수는 감소하였으며, 기계적 품질계수는 0.5 wt% 첨가시까지 증가하였으나 첨가량이 그 이상 증가함에 따라 감소하였다. 압전특성은 $1125^{\circ}C$에서 소결한 $MnO_2$ 0.5wt%조성에서 ${\varepsilon}r$ = 2040, kp = 0.66, $d_{33}$ = 504, Qm=438의 우수한 특성을 나타내었다.

• Clean Technology
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• v.21 no.3
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• pp.153-163
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• 2015

The effects of H₂O and residue SO₂ in flue gases on the activity of the Fe/zeolite catalysts for low-temperature NH₃-SCR of NO were investigated. And the addition effect of Mn, Zr and Ce to Fe/zeolite for low-temperature NH₃-SCR of NO in the presence of H₂O and SO₂ was investigated. Fe/zeolite catalysts were prepared by liquid ion exchange and promoted Fe/zeolite catatysts were prepared by liquid ion exchange and doping of Mn, Zr and Ce by incipient wetness impregnation. Zeolite NH₄-BEA and NH₄-ZSM-5 were used to adapt the SCR technology for mobile diesel engines. The catalysts were characterized by BET, X-ray diffraction (XRD), SEM/EDS, TEM/EDS. The NO conversion at 200 ℃ over Fe/BEA decreased from 77% to 47% owing to the presence of 5% H₂O and 100 ppm SO₂ in the flue gas. The Mn promoted MnFe/BEA catalyst exhibited NO conversion higher than 53% at 200 ℃ and superior to that of Fe/BEA in the presence of H₂O and SO₂. The addition of Mn increased the Fe dispersion and prevented Fe aggregation. The promoting effect of Mn was higher than Zr and Ce. Fe/BEA catalyst exhibited good activity in comparison with Fe/ZSM-5 catalyst at low temperature below 250 ℃.

• Journal of the Microelectronics and Packaging Society
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• v.5 no.1
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• pp.63-72
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• 1998

후막 PTC를 제조하기 위하여 BaTiO3 주원료에 Sb2O3와 MnO2를 첨가한 PTC 페이 스트를 ZrO2와 BaTiO3 기판위에 인쇄한후 13$25^{\circ}C$에서 1시간 동안 소결하였다. BaTiO3 기판 위에 형성된 PTC후막은 PTCR 특성을 나타내었다. 그러나 ZrO2기판위에 인쇄된 시편의 경 우 PTCR특성이 나타나지 않았다. 이것은 ZrO2기판과 인쇄된 PTC페이스트간의 열팽창계수 차이에 의한 thermal cracking 때문에 후막 PTC 형성이 불가능함을 보여주었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.257-257
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• 2007

압전 액츄에이터의 효율적 작동을 위해서는 변위량이 크고 이력이 없으며 응답이 빠르고 온도특성이 좋아야 하는 등의 여러 조건들을 만족시켜야 한다. 따라서 본 실험은 압전 효율은 높이고 압전 손실은 낮추기 위하여 Pb$[(Mn_{1/3}Sb_{2/3})_{0.04}\;Zr_x\;Ti_y]O_3$, 세라믹스를 선정하였으며 Zr/Ti의 변화(x=0.47~0.5, y=0.46~0.49)에 따른 각각의 압전 특성 및 강유전 특성을 조사하였다. 일반적인 산화물 합성법을 이용하여 압전 분말을 제조하였고 EMAS standard(6001)에 근거하여 시편을 제조하였다. XRD 관찰결과 모든 조성에서 perovskite구조의 단일상만을 나타내는 소결체를 얻을 수 있었으며 FE-SEM 관찰결과 $1250^{\circ}C$의 소결시편이 $2-3{\mu}m$의 grain size를 갖는 치밀한 미세구조를 나타내었다. 가장 우수한 압전특성을 나타내는 조성은 Zr/Ti의 비가 0.485/0.475 조성이었으며 그때의 전기기계 결합계수(Kp) 값은 62.5%였고, 기계적 품질계수(Qm) 값은 1004였다.

• Applied Microscopy
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• v.47 no.3
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• pp.131-147
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• 2017

In this work further optical and electrical investigations of pure and Zr doped $Mn_3O_4$ (from 0 up to 20 at.%) thin films as a function of frequency. First, the refractive index, the extinction coefficient and the dielectric constants in terms of Zr content are reached from transmittance and reflectance data. The dispersion of the refractive index is discussed by means of Cauchy model and Wemple and DiDomenico single oscillator models. By exploiting these results, it was possible to estimate the plasma pulse ${\omega}_p$, the relaxation time ${\tau}$ and the dielectric constant ${\varepsilon}_{\infty}$. Second, we have performed original ac and dc conductivity studies inspired from Jonscher model and Arrhenius law. These studies helped establishing significant correlation between temperature, activation energy and Zr content. From the spectroscopy impedance analysis, we investigated the frequency relaxation phenomenon and hopping mechanisms of such thin films. Moreover, a special emphasis has been putted on the effect of the oxidation in air of hausmannite thin films to form $Mn_2O_3$ ones at $350^{\circ}C$. This intrigue phenomenon which occurred at such temperature is discussed along with this electrical study. Finally, all results have been discussed in terms of the thermal activation energies which were determined with two methods for both undoped and Zr doped $Mn_3O_4$ thin films in two temperature ranges.

• Journal of the Korean Ceramic Society
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• v.37 no.4
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• pp.395-401
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• 2000

In this study, we chose the basic composition which indicated the best electrical properties by change of x content(0, 0.05, 0.1, 0.15, 0.2, 0.25 mol respectively) in xPb(Mn1/3Sb2/3)O3-(1-x)Pb(Zr0.52Ti0.48)O3 ceramics. And we substituted Cd2+ for Pb2+ site, then observed the sintering behavior, microstructure and electrical propertties according to the various sintering temperature. The basic composition was the 0.05PMS-0.95PZt, and it showed single perovskite phase and excellent properties. In case of Cd2+ substitution, we were able to sinter at 90$0^{\circ}C$ which was lower than conventional sintering temperature(1200~130$0^{\circ}C$). Especially, when the 2mol% substituted PMS-PZT specimens were sintered at 90$0^{\circ}C$ for 2h, we obtained the p=7.6g/㎤, kp=56%, Qm=520 and made sure of a position of Cd2+ substitution by observing lattice parameter, phase transition temperature. From this results, we could infer that because Cd2+ substituted fro A-site, low temperature sintering of Cd2+ substituted PMS-PZT without any loss of electrical properties shows its applicability for the piezoelectric ceramic transformer.

• Electrical & Electronic Materials
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• v.1 no.4
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• pp.311-318
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• 1988

초음파센서(수신기)에 응용가능한 압전세라믹스를 제조하기 위하여 Ba변조된 Pb(ZR, Ti)O$_{3}$계 세라믹스에 MnO$_{2}$를 첨가하여 첨가량과 소성온도에 따른 영향을 조사하였다. 또한 제조된 압전세라믹스를 이용하여 초음파 수신기를 제작하여 수신특성을 확인하여 보았다. 그 겨로가 MnO$_{2}$가 0.4(wt%)첨가되었을 때 압전 g정수가 가장 크고 수신감도가 우수한 것으로 밝혀졌다.

• Journal of the Korean Ceramic Society
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• v.23 no.1
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• pp.60-66
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• 1986

The effect of composition size of sintered body and electrode on resonant characteristics of the system $Pb(Mn_{1/3}Nb_{2/3})O_3 PbTiO_3-PbZrO_3$ has been decribed. Composition ranged from X=40 to X=55 diameter of sintered body ranged from D=6.5 to D=12.5(mm) and diameter of electrode ranged from De=5.5 to De=11 (mm) In the composition of morphotropic phase boundary antiresonant frequency (fa) dcreased slowly whereas resonant frequency (fr) decreased rapidly on the ground of this Δf(fa-fr) and electromechanical coupling fractor Kp increased and Qm showed low value. On the contrary in toward the composition of tetragonal and rhombo-hedral fa increased slowly whereas fr increased rapidly on the ground of this Δf and Kp decreased and Qm increased abruptly. Substance of the above statements have no concern with size of sintered body and ele-ctrode. The other side as the size of electrode decreased Qm fr, fa and Δf increased. Cm and Co dominantly affect the resonant frequency and antiresonant frequency.

• Korean Journal of Materials Research
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• v.3 no.5
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• pp.497-504
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• 1993

Effects of $Ta_2O_5,ZrO_2$ and $SiO_2$ addition on magnetic properties of 0.02wt%$Bi_2O_3$ and 0 . 0 5 wt%$CaCO_3$ doped Mn-Zn ferrites(58.5mol% $Fe_2O_3$, 25.5 mol% ZnO) were investigated. E:lectrlcal resistivity and magnetic properties such as the initial permeability($\mu_i$), loss factor(tan$\delta$), coercive force Hc(m0c) were measured. With lncreasing $Ta_2O_5$ and $ZrO_2$ addition, the following effects were observed: I ) Decreasing of the average grain size; 2) lncreasing of the electrical resistivity and initial permeability; 3) Ilecreasmg of loss factor values. (very low loss esprcially at high frequency region) ; 4 ) Fine and uniform microsrructures were obtamed at O.lwt% nddecl samples. In case of $SiO_2$ addition, anomalous grain growth and degradation of magnetic properties were observed. The obtained maximum initial permeability value was 6260 at IOkHz. $25^{\circ}C$ from 0.02wt%$Bi_2O_3$. 0.05wt%$CaCO_3$, 0.lwt%$Ta_2O_5$ added sample, the corresponded relative loss factor (tan$\delta /\mu_i$)for the sample was $4.2 \times 10^{-6}$.