• Title/Summary/Keyword: Mixture phenomena

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Variation Characteristics of TSP Ionic Compositions by Meteorological Phenomena in Jeju Island (기상현상에 따른 제주지역 TSP의 이온조성 변화 특성)

  • Ko, Hee-Jung;Kim, Won-Hyung;Lee, Seung-Hoon;Bu, Jun-Oh;Kang, Chang-Hee;Hu, Chul-Goo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.723-733
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    • 2011
  • The ionic compositions were analyzed from the TSP samples collected at Gosan site in Jeju Island between 2000 and 2008, in order to examine the characteristics of atmospheric aerosols in accordance with the meteorological conditions. For the Asian Dust influence on the ionic compositions, the concentration ratios of $NH_4{^+}$, nss-${SO_4}^{2-}$, $NO_3{^-}$, and $K^+$ were about 1.2~2.3 during Asian Dust over Non-Asian Dust periods, noticeably that of nss-$Ca^{2+}$ was 6.8. Meanwhile the concentrations of nss-${SO_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ have increased as 1.8~4.4 times during the haze event periods, and 1.0~1.6 times during the fog and mist events. The ion balance has resulted that the anionic concentrations are relatively lower than the cationic concentrations, and the discrepancy appears more decidedly as a strong Asian Dust effect. The ammonium ion balance has shown that it exists as a mixture of $NH_4HSO_4$ and $(NH_4)_2SO_4$. The concentration ratios of nss-${SO_4}^{2-}/NO_3{^-}$ for Asian Dust, haze, fog-mist, and non-event periods were respectively 1.8, 5.9, 4.6, and 2.9, which were higher values compared to those in urban areas of China as well as other domestic regions. Especially, the high ratios of sulfur oxides could be presumed by the fact that the longrange transport of air pollutants from Asia continent might affect the atmospheric aerosols of Jeju Island.

A Study on the Relationship of Explosion Characteristics and Combustion Heat of Gas Mixtures (가스 혼합물의 폭발압력과 연소열의 상관관계 연구)

  • Oh Khy-hyung;Kim Hong;Yoo Joo-hyun;Kim Tae-Jin
    • Journal of the Korean Institute of Gas
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    • v.1 no.1
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    • pp.49-55
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    • 1997
  • Destruction phenomena of structure by gas explosion is due to the explosion pressure and heat. Explosion pressure is a kind of energy converted from the gas mixture explosion. In this paper, we tried to find the relationship between explosion characteristics and combustion heat of the hydrocarbon-oxygen mixtures. Experiment were carried out with the volume of $5916cm^3$ cylindrical explosion vessel. Hydrocarbon gases which used in this study were methane, ethylene, propane, and buthane Experimental parameter was the concentration of the gas mixtures. Explosion characteristics were measured with strain type pressure transducer through the digital storage oscilloscope. From the experimental result, it was found that explosion pressure depend upon the combustion heat.

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Study on Combustion Performance and Burning Velocity in a Micro Combustor (초소형 연소기에서 연소성능과 연소속도에 대한 연구)

  • Na Hanbee;Lee Dae Hoon;Kwon Sejin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.6 s.237
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    • pp.662-670
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    • 2005
  • The effect of heat loss on combustion performance and burning velocity of micro combustors in various conditions were exploited experimentally. Three different gases were used, and various geometric matrixes were considered to figure out the phenomena of combustion in a micro combustor. The micro combustors used in this study were constant volume combustors and had cylindrical shape. Geometric parameter of combustor was defined as combustor height and diameter. The effect of height was exploited parametrically as 1mm, 2mm and 3 mm and the effect of diameter was parameterized to be 7.5 mm and 15 mm. Three different combustibles which were Stoichiometric mixtures of methane and air, hydrogen and air, and mixture of hydrogen and air with fuel stoichiometry of two were used. By pressure measurement and visualization of flame propagation, characteristic of flame propagation was obtained. Flame propagations which were synchronized with pressure change within combustor were analyzed. From the analysis of images obtained during the flame propagations, burning velocity at each location of flame was obtained. About $7\%$ decrease in burning velocity of $CH_4/Air$ stoichiometric mixture compared with previous a empirical result was observed, and we can conclude that it is acceptable to use empirical equations for laminar premixed flame burning velocity to micro combustions. Results presented in this paper will give fine tool for analysis and prediction of combustion process within micro combustors.

Three-dimensional Numerical Analysis of Dam-break Waves on a Fixed and Movable Bed (고정상 및 이동상 수로에서 댐 붕괴파의 3차원 수치해석)

  • Kim, Dae Geun;Hwang, Gun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.4B
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    • pp.333-341
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    • 2011
  • This study analyzed the propagation of dam-break waves in an area directly downstream of a dam by using 3D numerical modeling with RANS as the governing equation. In this area, the flow of the waves has three dimensional characteristics due to the instantaneous dam break. In particular, the dam-break flows are characterized by a highly unsteady and discontinuous flow, a mixture of the sharp flood waves and their reflected waves, a mixture of subcritical and supercritical flow, and propagation in a dry and movable bed. 2D numerical modeling, in which the governing equation is the shallow water equation, was regarded as restricted in terms of dealing with the sharp fluctuation of the water level at the dam-breaking point and water level vibration at the reservoir. However, in this 30 analysis of flood wave propagation due to partial dam breaking and dam-break in channels with $90^{\circ}$ bend, those phenomena were properly simulated. In addition, the flood wave and bed profiles in a movable bed with a flat/upward/downward bed step, which represents channel aggradation or degradation, was also successfully simulated.

Equations for Water Sorption Isotherms of the Mixture of Dried Soymilk Residue and Wheat Flour (건조(乾燥)한 콩우유 비지와 밀가루 혼합물(混合物)의 등온흡습성질(等溫吸濕性質)과 관계식(關係式))

  • Sohn, Jung-Woo;Kim, Woo-Jung;Kim, Sang-Soon
    • Korean Journal of Food Science and Technology
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    • v.17 no.2
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    • pp.101-106
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    • 1985
  • Dried soymilk residue(SMR) which was prepared by washing with ethanol and acetone, followed by drying at $60^{\circ}C$ was investigated for its sorption characteristics and the relationship between moisture content and water activity when it was mixed with wheat flour. During storage at $20^{\circ}C$ and various RH, an excess sorption phenomena was observed for solvent treated and dried SMR before equilibrium reached. A simple equation of log(dw/dt)=b log t+log a, where t is storage time(hr) and w is %$(H_2O)$ was drived for sorption or desorption rate of dried SMR at RH range of 12%-92%. From sorption isothermifigure, the moisture content(Mi) could be calculated from water activity by the equation of Mi=b Aw+a. The proposed equation was proved to have better fitness than those of the Smith isotherm equation or Lang and Steinberg equation for the mixture of dried SMR and wheat flour.

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OVERVIEW ON HYDROGEN RISK RESEARCH AND DEVELOPMENT ACTIVITIES: METHODOLOGY AND OPEN ISSUES

  • BENTAIB, AHMED;MEYNET, NICOLAS;BLEYER, ALEXANDRE
    • Nuclear Engineering and Technology
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    • v.47 no.1
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    • pp.26-32
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    • 2015
  • During the course of a severe accident in a light water nuclear reactor, large amounts of hydrogen can be generated and released into the containment during reactor core degradation. Additional burnable gases [hydrogen ($H_2$) and carbon monoxide (CO)] may be released into the containment in the corium/concrete interaction. This could subsequently raise a combustion hazard. As the Fukushima accidents revealed, hydrogen combustion can cause high pressure spikes that could challenge the reactor buildings and lead to failure of the surrounding buildings. To prevent the gas explosion hazard, most mitigation strategies adopted by European countries are based on the implementation of passive autocatalytic recombiners (PARs). Studies of representative accident sequences indicate that, despite the installation of PARs, it is difficult to prevent at all times and locations, the formation of a combustible mixture that potentially leads to local flame acceleration. Complementary research and development (R&D) projects were recently launched to understand better the phenomena associated with the combustion hazard and to address the issues highlighted after the Fukushima Daiichi events such as explosion hazard in the venting system and the potential flammable mixture migration into spaces beyond the primary containment. The expected results will be used to improve the modeling tools and methodology for hydrogen risk assessment and severe accident management guidelines. The present paper aims to present the methodology adopted by Institut de Radioprotection et de $S{\hat{u}}ret{\acute{e}}$ $Nucl{\acute{e}}aire$ to assess hydrogen risk in nuclear power plants, in particular French nuclear power plants, the open issues, and the ongoing R&D programs related to hydrogen distribution, mitigation, and combustion.

Performance of fly ash stabilized clay reinforced with human hair fiber

  • Rekha, L. Abi;Keerthana, B.;Ameerlal, H.
    • Geomechanics and Engineering
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    • v.10 no.5
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    • pp.677-687
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    • 2016
  • Industrialization and urbanization are the two phenomena that are going relentless all over the world. The consequence of this economic success has been a massive increase in waste on one hand and increasing demand for suitable sites for construction on the other. Owing to the surplus raw materials and energy requirement needed for manufacturing synthetic fibers, applications of waste fibers for reinforcing soils evidenced to offer economic and environmental benefits. The main objective of the proposed work is to explore the possibilities of improving the strength of soil using fly ash waste as an admixture and Human Hair Fiber (HHF) as reinforcement such that they can be used for construction of embankments and land reclamation projects. The effect of fiber content on soil - fly ash mixture was observed through a series of laboratory tests such as compaction tests, CBR and unconfined compression tests. From the stress - strain curves, it was observed that the UCC strength for the optimised soil - flyash mixture reinforced with 0.75% human hair fibers is nearly 2.85 times higher than that of the untreated soil. Further, it has been noticed that there is about 7.73 times increase in CBR for the reinforced soil compared to untreated soil. This drastic increase in strength may be due to the fact that HHF offer more pull-out resistance which makes the fibers act like a bridge to prevent further cracking and thereby it improves the toughness which in turn prevent the brittle failure of soil-flyash specimen. Hence, the test results reveal that the inclusion of randomly distributed HHF in soil significantly improves the engineering properties of soil and can be effectively utilized in pavements. SEM analysis explained the change of microstructures and the formation of hydration products that offered increase in strength and it was found to be in accordance with strength tests.

The Effect of Fuel Injection Timing on Combustion and Power Characteristics in a DI CNG Engine (직분식 CNG 엔진에서 연료 분사시기의 변화가 연소 및 출력 특성에 미치는 영향)

  • Kang, Jeong-Ho;Yoon, Soo-Han;Lee, Joong-Soon;Park, Jong-Sang;Ha, Jong-Yul
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.1
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    • pp.193-200
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    • 2007
  • Natural gas is one of the most promising alternatives to gasoline and diesel fuels because of its lower harmful emissions, including $CO_2$, and high thermal efficiency. In particular, natural gas is seen as an alternative fuel for heavy-duty Diesel Engines because of the lower resulting emissions of PM, $CO_2$ and $NO_x$. Almost all CNG vehicles use the PFI-type Engine. However, PFI-type CNG Engines have a lower brake horse power, because of reduced volumetric efficiency and lower burning speed. This is a result of gaseous charge and the time losses increase as compared with the DI-type. This study was conducted to investigate the effect of injection conditions (early injection mode, late injection mode) on the combustion phenomena and performances in the or CNG Engine. A DI Diesel Engine with the same specifications used in a previous study was modified to a DI CNG Engine, and injection pressure was constantly kept at 60bar by a two-stage pressure-reducing type regulator. In this study, excess air ratios were varied from 1.0 to the lean limit, at the load conditions 50% throttle open rate and 1700rpm. The combustion characteristics of the or CNG Engine - such as in-cylinder pressure, indicated thermal efficiency, cycle-by-cycle variation, combustion duration and emissions - were investigated. Through this method, it was possible to verify that the combustion duration, the lean limit and the emissions were improved by control of injection timing and the stratified mixture conditions. And combustion duration is affected by not only excess air ratio, injection timing and position of piston but gas flow condition.

Antigenicity of HM10760 in Guinea Pigs

  • Choi, Woo-Hyuck;Lee, Sung-Hak;Lee, Mi-Chael;Chung, Moon-Ku;Kwon, Se-Chang;Lee, Gwan-Sun;Han, Jae-Yong;Koh, Woo-Suk
    • Toxicological Research
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    • v.21 no.3
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    • pp.241-247
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    • 2005
  • HM10760 is a recombinant human erythropoietin that has beer developed as a drug for anemia. In this study, antigenic potential of HM10760 was examined by active systemic anaphylaxis in guinea pigs and passive cutaneous anaphylaxis in a guinea pig-guinea pig system. HM10760 was subcutaneously administered at 0, 2, and $20{\mu}g/kg$ and also as a suspension with adjuvant ($20{\mu}g/kg$ + FCA). Ovalbumin as a suspension with adjuvant was administered to induce positive control responses. In the active systemic anaphylaxis test, no symptoms except rubbing or licking nose and urination that were considered as physiological phenomena were observed at $0{\mu}g/kg$. Four of 5 animals at $2{\mu}g/kg$ and all the 5 animals at $20{\mu}g/kg$ showed cyanosis and lying on side. All animals in the adjuvant mixture group showed relatively mild symptoms such as rubbing or licking nose, urination, and evacuation. In the passive cutaneous anaphylaxis test, 0/5, 3/5, and 5/5 serum samples from the animals immunized with 0, 2, and $20{\mu}g/kg$, respectively, showed positive reactions against HM10760. All 5 sera collected from the animals immunized with an adjuvant mixture contained HM10760-specific antibodies. These results suggest HM10760 have antigenicity in guinea pigs.

Study on Separation of Heavy Metal Ions in A Neutral Macrocycle-Mediated Emulsion Liquid Membrane System

  • Moon-Hwan Cho;Hea-Suk Chun;Jin-Ho Kim;Chang-Hwan Rhee;Si-Joong Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.474-477
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    • 1991
  • The preferential transport phenomena of neutral cation-anion moieties in neutral macrocycle-facilitated emulsion liquid membrane were described in this study. Emulsion membrane systems consisting of (1) aqueous source phase containing 0.001 M M($NO_3$)$_2(M=Mn^{2+},\;Co^{2+},\;Ni^{2+},\;Cu^{2+},\;Zn^{2+},\;Sr^{2+},\;Cd^{2+},\;and\;Pb^{2+})$ (2) a toluene membrane containing 0.01 M ligand $(DBN_3O_2$, DA18C6, DT18C6, TT18C6, HT18C6) and the surfactant span 80 (sorbitan monooleate) (3% v/v) and (3) an aqueous receiving phase containing $Na_2S_2O_3$ or $NaNO_3$ were studied with respect to the disappearence of transition metal ions from the source phase as a function of time. Cation transports for various two component or three component equimolar mixture of transition metal and $Cu^{2+}$ in a emulsion membrane system incorporating macrocyclic ligand (HT18C6) as carrier were determinded. $Cu^{2+}$ was transported higher rates than the other $M^{2+}$ in the mixture solution. Equilibrium constants for cation-source phase co-anion, cation macrocycle and cation-receiving phase reagent interaction are examined as parameters for the prediction of cation transport selectivities.