• Title/Summary/Keyword: Mixture layer

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Characteristics of CIGS film fabricated by non-vacuum process (비 진공으로 제작한 CIGS 박막 특성)

  • Park, Myoung-Guk;Ahn, Se-Jin;Yoon, Jea-Ho;Gwak, Ji-Hye;Kim, Dong-Hwan;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.19-22
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    • 2009
  • A non-vacuum process for fabrication of $CuIn_xGa_{1-x}Se_2$ (CIGS) absorber layer from the corresponing Cu, In, Ga solution precursors was described. Cu, In, Ga precursor solution was prepared by a room temperature colloidal route by reacting the starting materials $Cu(NO_3)_2$, $InCl_3$, $Ga(NO_3)$ and methanol. The Cu, In, Ga precursor solution was mixed with ethylcellulose as organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of Cu, In, Ga solution with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents and to burn the organic binder material. Subsequently, the resultant CIG/Mo/glass sample was selenized in Se evaporation in order to get a solar cell applicable dense CIGS absorber layer. The CIGS absorber layer selenized at $530^{\circ}C$ substrate temperature for 1h with various metal organic ratio.

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Dehydration of Alcohol Solutions Through Crosslinked Chitosan Composite Membranes III. Effects of Substrate, Neutralization and Active Layer Thickness on Pervaporation of Water/Ethanol Mixture (가교키토산 복합막을 통한 알콜수용액의 탈수 III. 화학가교시 지지체, 중화에 의한 효과와 이온가교시 활성층두께 변화에 의한 효과)

  • 이영무;남상용;유제강;류경옥
    • Membrane Journal
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    • v.6 no.4
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    • pp.250-257
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    • 1996
  • Surface crosslinked chitosan composite membranes were prepared with glutaraldehyde and surfuric acid. Effects of neutralization for complex between chitosan and acetic acid and of water permeability for substrate membranes on pervaporation performance were investigated. For ionically crosskinked membranes, effect of active layer thickness on separation factor of water/ethanol mixture was studied. With increasing the water permeability of the substrate, the membrane showed an increased separation factor, while it maintained a constant permeate flux. Neutralized chitosan composite membranes revealed a decreased separation factor and a constant permeate flux. When the thickness of the active layer increased, an optimum crosslinking time to achieve higher separation factor shifted to a prolonged times.

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Effect of Alumina Content on the Hot Corrosion of SiC by NaCl and Na2SO4 (NaCl과 Na$_2$SO$_4$에 의한 SiC 고온 부식에 미치는 Alumina 첨가량의 영향)

  • 이수영;고재웅;김해두
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.626-634
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    • 1991
  • The specimens for the corrosion test were made by hot-pressing of SiC power with 2 wt% Nl2O3 and 10wt% Al2O3 additions at 200$0^{\circ}C$ and 205$0^{\circ}C$. The specimens were corroded in 37 mole% NaCl and 63 mole% Na2SO4 salt mixture at 100$0^{\circ}C$ up to 60 min. SiO2 layer was formed on SiC and then this oxide layer was dissolved by Na2O ion in the salt mixture. The rate of corrosion of the specimen containing 10 wt% Al2O3 was slower than that of the specimen containing 2 wt% Al2O3. This is due to the presence of continuous grain boundary phase in the specimen containing 10 wt% Al2O3. The oxidation of SiC produced gas bubbles at the SiC-SiO2 interface. The rate of corrosion follows a linear rate law up to 50 min. and then was accelerated. This acceleration is due to the disruption oxide layer by the gas evolution at SiC-SiO2 interface. Pitting corrosion has found at open pores and grain boundaries.

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Fabrication of CIGS Thin Film Solar Cell by Non-Vacuum Nanoparticle Deposition Technique (비진공 나노입자 코팅법을 이용한 CIGS 박막 태양전지 제조)

  • Ahn, Se-Jin;Kim, Ki-Hyun;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.222-224
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    • 2006
  • A non-vacuum process for $Cu(In,Ga)Se_2$ (CIGS) thin film solar cells from nanoparticle precursors was described in this work CIGS nanoparticle precursors was prepared by a low temperature colloidal route by reacting the starting materials $(CuI,\;InI_3,\;GaI_3\;and\;Na_2Se)$ in organic solvents, by which fine CIGS nanoparticles of about 20nm in diameter were obtained. The nanoparticle precursors were mixed with organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of CIGS with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents ud to burn the organic binder material. Subsequently, the resultant (porous) CIGS/Mo/glass simple was selenized in a two-zone Rapid Thermal Process (RTP) furnace in order to get a solar ceil applicable dense CIGS absorber layer. Complete solar cell structure was obtained by depositing. The other layers including CdS buffer layer, ZnO window layer and Al electrodes by conventional methods. The resultant solar cell showed a conversion efficiency of 0.5%.

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Layered Object Detection using Gaussian Mixture Learning for Complex Environment (혼잡한 환경에서 가우시안 혼합 모델을 이용한 계층적 객체 검출)

  • Lee, Jin-Hyeong;Kim, Heon-Gi;Jo, Seong-Won;Kim, Jae-Min
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 2007.11a
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    • pp.435-438
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    • 2007
  • 움직이는 객체를 검출하기 위해서 정확한 배경을 사용하기 위해 널리 사용되는 방법으로는 가우시안 혼합 모델이다. 가우시안 혼합 모텔은 확률적 학습 방법을 사용하는데, 이 방법은 움직이는 배경일 경우와 이동하던 물체가 정지하는 경우 배경을 정확히 모델링하지 못한다. 본 논문에서는 확률적 모델링을 통해 혼잡한 배경을 모델링하고 객체의 계층적 처리를 통해 보다 정확한 배경으로 갱신할 수 있는 학습 방법을 제안한다.

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Optimum Condition for Xe Gas Excitation in Plasma Display Panels through Ternary Gas of He, Ne, Xe

  • Khorami, Alireza;Ghanbari, Shirin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.744-747
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    • 2009
  • Plasma Display Panels (PDPs) have illustrated impressive results in terms of light emission efficiency of the Ne-Xe mixture compared with the He-Xe mixture. However, He-Xe has shown to achieve superior color purity. This paper presents the optimization of excitation efficiency and color purity for He-Ne-Xe ternary gas mixtures. Furthermore, we investigate the effect that a protective dielectric layer has on UV photon efficiency in a matrix known as electrode type PDP.

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Estimation of Air Voids in Asphalt Mixtures Using Ground-Penetrating Radar (지표투과레이더를 이용한 아스팔트 혼합물의 공극률 예측에 관한 연구)

  • Kim, Je Won;Kim, Yeon Tae;Kim, Booil;Park, Hee Mun
    • International Journal of Highway Engineering
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    • v.18 no.4
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    • pp.55-61
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    • 2016
  • PURPOSES : The objective of this study was to determine the relationship between the dielectric characteristics of asphalt mixtures and the air voids present in them using ground penetrating radar (GPR) testing. METHODS : To measure the dielectric properties of the asphalt mixtures, the reflection coefficient method and the approach based on the actual thickness of the asphalt layer were used. An air-couple-type GPR antenna with a center frequency of 1 GHz was used to measure the time for reflection from the asphalt/base layer interface. A piece of aluminum foil was placed at the interface to be able to determine the reflection time of the GPR signal with accuracy. An asphalt pavement testbed was constructed, and asphalt mixtures with different compaction numbers were tested. After the GPR tests, the asphalt samples were cored and their thicknesses and number of air voids were measured in the laboratory. RESULTS : It was found the dielectric constant of asphalt mixtures tends to decrease with an increase in the number of air voids. The dielectric constant values estimated from the reflection coefficient method exhibited a slight correlation to the number of air voids. However, the dielectric constant values measured using the approach based on the actual asphalt layer thickness were closely related to the asphalt mixture density. Based on these results, a regression equation to determine the number of air voids in asphalt mixtures using the GPR test method was proposed. CONCLUSIONS : It was concluded that the number of air voids in an asphalt mixture can be calculated based on the dielectric constant of the mixture as determined by GPR testing. It was also found that the number of air voids was exponentially related to the dielectric constant, with the coefficient of determination, $R^2$, being 0.74. These results suggest that the dielectric constant as determined by GPR testing can be used to improve the construction quality and maintenance of asphalt pavements.

A Study on the Laser Melting Deposition of Mixed Metal Powders to Prevent Interfacial Cracks (레이저 용융 금속 적층 시 결함 방지를 위한 혼합 분말 적층에 관한 연구)

  • Shim, D.S.;Lee, W.J.;Lee, S.B.;Choi, Y.S.;Lee, K.Y.;Park, S.H.
    • Transactions of Materials Processing
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    • v.27 no.1
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    • pp.5-11
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    • 2018
  • Direct energy deposition (DED) technique uses a laser heat source to deposit a metal layer on a substrate. Many researchers have used the DED technique to study the hardfacing of molds and dies. The aim of this study is to obtain high surface hardness and a sound bonding between the AISI M4 deposits and a substrate utilizing a mixed powder that contains M4 and AISI P21 powders. To prevent interfacial cracks between the M4 deposits and the substrate, the mixed powder is pre-deposited onto a JIS S45C substrate, before the deposition of M4 powders. Interfacial defects occurring between the deposits and substrate and changes in the microhardness of the intermediate layer were examined. Observations of the cross-sections of deposited specimens revealed that the interfacial cracks appeared in samples with one and two mixed layers regardless of the mixture ratio. However, the crack was removed by increasing the mixture ratio and the number of intermediate layers. Meanwhile, the microhardness in the mixed layer was found to decrease with increasing ratio of P21 powder in the mixture and that in the upper region of the deposited layers was approximately 800 HV, which was attributed to various alloying elements in the M4 powder.

Heat Treatment of Cu0.9In0.7Ga0.3Se2 Powder Layer with a Mixture of Selenium and Ceramic Powder (셀레늄과 세라믹 혼합분말을 사용한 Cu0.9In0.7Ga0.3Se2 분말층의 소결거동 연구)

  • Song, Bong-Geun;Hwang, Yoonjung;Park, Bo-In;Lee, Seung Yong;Lee, Jae-Seung;Park, Jong-Ku;Lee, Doh-Kwon;Cho, So-Hye
    • Current Photovoltaic Research
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    • v.2 no.3
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    • pp.115-119
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    • 2014
  • $Cu(In,Ga)Se_2$ (CIGS) thin films have been used as a light absorbing layer in high-efficiency solar cells. In order to improve the quality of the CIGS thin film, often selenization step is applied. Especially when the thin film was formed by non-vacuum powder process, selenization can help to induce grain growth of powder and densification of the thin film. However, selenization is not trivial. It requires either the use of toxic gas, $H_2Se$, or expensive equipment which raises the overall manufacturing cost. Herein, we would like to deliver a new, simple method for selenization. In this method, instead of using a costly two-zone furnace, use of a regular tube furnace is required and selenium is supplied by a mixture of selenium and ceramic powder such as alumina. By adjusting the ratio of selenium vs. alumina powder, selenium vaporization can be carefully controlled. Under the optimized condition, steady supply of selenium vapor was possible which was evidently shown by large grain growth of CIGS within a thin powder layer.

The effect of reactive gases on the propertise of TiCN layer synthesized by Arc Ion plating process (Arc Ion Plating 방식에 의한 TiCN 증착시 반응가스가 코팅층에 미치는 영향)

  • Seo, Chang-Min;Kim, Chang-Geun;;Yu, Im-Jun
    • Journal of Ocean Engineering and Technology
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    • v.11 no.3
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    • pp.56-68
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    • 1997
  • This work was intended to study the effect of a partial pressure ratio and a total pressure of reactive gases on the properties of TiC$_{x}$N$_{1-x}$ . coated layer. In this regard, various TiC$_{x}$N$_{1-x}$ coatings were synthesized with C2112 and N2 Mixture gas of different compositions by Arc Ion Plating process which has been highlighted for an industrial purpose. It was revealed from colors and X-ray diffraction patterns that the concentration of carbon of a TiC$_{x}$N$_{1-x}$ coating increases with a partial pressure ratio (PC$_{2}$H$_{2}$/PN$_{2}$) as well as a total pressure Of $C_{2}$H$_{2}$ and N$_{2}$ mixture gas. Accordingly, the hardness of TiC$_{x}$N$_{1-x}$ coated layer increased but the adhesion to the substrate of SKH 51 was degraded. On the other hand, the deposition rate was independent of a partial pressure ratio and a total pressure of mixture gas. It was found that a uniform gas distribution is critical for an industrial application since the composition of a coating depends strongly on the location of a substrate inside of the furnace. As a result of milling tests with different TiC$_{x}$N$_{1-x}$ coated end mills, the one which has a low carbon concentration was better than others studied in this work.d in this work.

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