• Title/Summary/Keyword: Mixture layer

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Study on the Analysis of Water-Soluble Dyes by Use of the Thin-Layer Chromatography. -1. Separation and Identification of Xanthene Dyes- (Thin-Layer chromatcgraphy에 의한 수용성 색소의 분석에 관한 고찰 -1. Xanthene 계 색소의 분리 및 대안-)

  • 구성회;이성호
    • Journal of Environmental Health Sciences
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    • v.2 no.1
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    • pp.5-9
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    • 1975
  • For analysis of Xanthene dyes according to the developing solvent and adsorbent was applied to Thin-layer chromatography with silicagel and cellulose plate. Silicagel chromato-plate used were prepared under different condition of activation. Using eight developing solvent, the influence of the condition for activation upon the separation of Xanthene dyes was investigated. The results are shown in Table 3. Methyl ethyl ketone+Acetone+$H_2O$ (10:0.1:0.4) mixture and n-butanol+Ammonia water (4:1) mixture gave clear separation for Xanthene dyes, including Fluorescein, Erythrosine Rhodamin B, Eosine, Rose bengale, phloxine and Acid red those Rf values decrease in the described ordor. Methyl ethyl ketone+Acetone+$H_2O$ (10:0.1:0.4) was applied to two adsorbents which were purchased from different manufactures. The results of Chromatograms are obtained Figure 6.

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A Study on the Epidermal Structure and Mucosubstance Histochemistry of Spotty Belly, Devil Stinger, Stone Fish, Cubed Snailfish, and Japanese Bluefish

  • Jeong, Gil-Nam
    • Animal cells and systems
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    • v.12 no.2
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    • pp.85-91
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    • 2008
  • Structure and mucosubstance histochemistry in the epidermis of five teleostean species, i. e., spotty belly, Agrammus agrammus, devil stinger, Inimicus japonicus, stone fish, Erosa erosa, cubed snailfish, Liparis tessellatus, and Japanese bluefish, Scombrops boops were investigated. The epidermis of five species studied is composed of three layers: superficial, middle, and basal layer. The superficial layer is comprised of rather flattened cells. Mucous cells, the type commonly found in fishes are completely lacking in the epidermis of devil stinger, stone fish, and cubed snailfish. The epidermis of devil stinger and stone fish have multicellular glands which do not have mucosubstances. The skin surface of them is covered with mucous layer. The superficial cells in the epidermis of devil stinger, stone fish, and cubed snailfish are mucus-secreting cells. The composition and the amount of the mucosubstances vary in species and body regions. The mucous layer on the skin surface and superficial epidermal cells of devil stinger contain a mixture of neutral and acidic(sulfated and nonsulfated) mucosubstances. In stone fish, the mucous layer has acidic(sulfated and non-sulfated) mucin and the superficial epidermal cells contain neutral mucin. In cubed snailfish, the type of epidermal mucosubstances is identified as a mixture of neutral and acidic(non-sulfated) mucin. The mucous cells of the epidermis in spotty belly and Japanese bluefish contain neutral mucin.

Mixture Fraction Analysis on the Combustion Gases of the Full-Scale Compartment Fires (실규모 구획화재의 연소가스에 대한 혼합분율 분석)

  • Ko, Gwon-Hyun;Hwang, Cheol-Hong
    • Fire Science and Engineering
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    • v.24 no.5
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    • pp.128-135
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    • 2010
  • In this study, a mixture fraction analysis was performed to investigate the characteristics of chemical species production in compartment fires burning hydrocarbon fuels such as methane, heptane, and toluene. A series of fire experiments was conducted in the ISO 9705 standard room, and gas species concentration and soot fraction were measured at two locations in the upper layer of the compartment. The mass fractions of measured chemical species, such as unburned hydrocarbons (UHC), carbon monoxide (CO), carbon dioxide ($CO_2$), oxygen ($O_2$), and soot were presented as a function of mixture fraction and compared with state relationships based on the idealized reaction of hydrocarbon fuels. The mixture fraction analysis made it possible to rearrange hundreds of species measurements, which were done under various fire conditions and at two locations of the upper layer, in term of the unified parameter, i.e. the mixture fraction. The results also showed that inclusion of soot in the mixture fraction calculation could improve the performance of analysis, especially for the sooty fuels such as heptane and toluene.

Selective Laser Sintering of WC-Co Mixture (텅스텐 카바이드와 코발트 혼합물의 선택적 레이저 소결)

  • 김광희;조셉비만
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2001.10a
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    • pp.269-274
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    • 2001
  • This paper describes the experimental results on direct selective laser sintering of WC-Co mixture. The experiments were carried out within an air, argon and nitrogen atmosphere. The main problem occurred during sintering within an air atmosphere was oxidation of WC-Co mixture. As the power of laser is increased and scanning speed is decreased, more severe oxidation takes place. Within an argon and nitrogen atmosphere the oxidation is reduced significantly. As the energy density is increased the thickness of the sintered layer is increased.

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Effect of Dietary Formic and Propionic Acids Mixture on Limiting Salmonella pullorum in Layer Chicks

  • Al-Tarazi, Y.H.;Alshawabkeh, K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.1
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    • pp.77-82
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    • 2003
  • This investigation was conducted to study the effect of dietary formic acid (FA) and propionic acid (PA) mixture on inhibitory effect of Salmonella pullorum in layer chicks. Nine groups of one day-old layer chicks in addition to positive and negative controls, were fed with acids treated feed containing mixture of different acids concentrations, from 0.5% and 0.5% up to 1.5% and 1.5% FA and PA, respectively. Positive and negative controls were fed untreated feed. Groups except the negative control were challenged orally on day three with $10^4$ cfu/ml S. pullorum. Cloacal swabs were taken at three successive days and at 7, 14 and 21 days of challenge. After 1, 2 and 3 weeks after challenge, 4 chicks from each group were sacrificed and crop and cecal contents were examined for S. pullorum and pH. The numbers of S. pullorum positive culture from the excretion of all treated groups except groups treated with mixture of 0.5% and 0.5%, 1% and 0.5%, 0.5% and 1% FA and PA decreased significantly (p<0.05) as compared with the positive control. The mortality rates of all treated groups except the group treated with 0.5% FA and 0.5% PA were decreased significantly (p<0.05) as compared with the positive control. The treatment significantly (p<0.05) lowered the pH of the crop and cecal contents in all groups except the group treated with 0.5% FA and 0.5% PA as compared with the control. Also, the treatment significantly (p<0.05) lowered the pH of the crop and cecal contents in all groups after three weeks of treatment compared to the first and second weeks. The treatments significantly (p<0.05) lowered the frequency of S. pullorum recovery from crop and cecal contents in six groups treated with 1.5 and 0.5, 1 and 1, 1.5 and 1, 0.5 and 1.5, 1 and 1.5, 1.5% and 1.5% FA and PA respectively. These results indicate that addition of FA and PA mixture in a total concentration of 2 % or more to the diet of newly hatched infected layer chicks significantly decreases the crop and cecal colonization by S. pullorum and significantly decreases S. pullorum fecal excretion and reduced the chick mortality rate.

Effect of Solvent Mixture Ratio on Rheology Property of Slurry and Thickness Control of Ceramic Green Sheets (유기 용매 혼합비에 따른 슬러리의 유동 특성과 세라믹 그린 쉬트의 두께 제어)

  • Kim, Jun-Young;Kim, Seung-Taek;Park, Jong-Chul;Yoo, Myong-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.3
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    • pp.236-241
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    • 2008
  • The effect of organic solvent mixture ratio on the rheology property of slurry and thickness control of ceramic green sheet was investigated. For selecting a suitable dispersant multiple light scattering method was used to evaluate the particle migration velocity and variation of clarification layer thickness. Using the selected dispersant the dispersion property of solution according to solvent mixture ratio was investigated. Binder and plasticizers were added to formulate slurries and their viscosity was evaluated according to solvent mixture ratio. Ceramic green sheets with average thickness of 30, 50 urn were fabricated via tape casting and their thickness tolerances measured. As a result according to solvent mixture ratio the solution and slurry properties varied and for the mixture ratio of ethanol/toluene of 80/20 the ceramic green sheet with the lowest thickness tolerance was obtained.

A Study on the Optimal Mixture Ratio for Stabilization of Surface Layer on Ultra-soft Marine Clay (초연약 해성점토의 표층고화처리를 위한 최적배합에 관한 연구)

  • 천병식;고경환;김진춘
    • Journal of the Korean Geotechnical Society
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    • v.18 no.4
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    • pp.33-43
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    • 2002
  • Recently, as large constructions on the coast increase, an application of a surface layer stabilization method which is one of the improvement methods for dredged soft clay has increased. However, there are few studies about this. The purpose of this study is clarifying characteristics of ultra-soft marine clay and hardening agent. Also, it is verifying an optimal mixture ratio of hardening agent through the laboratory tests according to designed experiments and proving by statistical analysis and pilot tests. Laboratory tests were performed with proper hardening agent and test soil in accordance with the design of experiments. Regression equations between hardening agents materials and unconfined compressive strength were derived from the tests. The applicability of regression equations were also verified by pilot tests. From the test results, it was found that hardening agent materials(cement, slag, fly-ash, inorganic salts, arwin, gypsum etc.) have some effect upon compressive strength. The optimal mixture ratio which satisfies the required compressive strength was derived from the statistical analysis. The effect of ground improvement by cements and hardening agents was confirmed through the pilot tests. This study will suggest data for design or construction criteria of stabilization of surface layer on ultra-soft marine clay.

EFFECT OF ADDED Si ON DENSIFICATION OF Ni-AI INTERMETALLIC COATING ON SPHEROIDAL GRAPHITE CAST IRON SUBSTRATES

  • Kim, Tetsuro ata;Keisuke Uenishi;Akira Ikenaga;Kojiro F. Kobayashi
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.726-731
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    • 2002
  • Reaction synthesis is a process to form ceramics, intermetallics and their composites from elemental powder mixture. Application of this process to a surface modification techniques has a possibilities to enable the process at a lower temperature or for a shorter time, although synthesized materials are likely to include voids and unreacted elements. This paper intend to examine the effect of Si addition to the mixture of Al and Ni on the densification of synthesized Ni-Al intermetallic compounds and to evaluate the surface properties of obtained coatings. By the Si addition, exothermic reaction temperature to form Ni-Al intermetallic was lowered to be below the melting point of Al. Si soluted $Al_3$Ni$_2$, $Al_3$Ni and $Al_{6}$Ni$_3$Si were mainly formed in the coating layer when powder mixture was heated to 973K for 300s. Besides, densification was enhanced by increasing hot press pressure, Si additions and heating rate. When the composition of eutectic Al-Si reaches 78%, void ratio of sintered compact reduced to 0.4%. It is caused by higher flowability of Al-Si liquid phase generated and its infiltration into the void. Since the hardness of NiAl(Si) compound (about 600HV) formed in the coating layer is higher than that of Ni-Al compound (about 400HV), coating layer with high density and superior wear property is obtained by hot press using reaction synthesis from Al-Ni-Si powder mixture.

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The influence of treatment time on the microstructure of plasma nitrocarburised compound layer (플라즈마 침질탄화처리시 처리시간이 화합물층의 특성에 미치는 영향)

  • 박율민;신평우;조효석;남기석;이구현
    • Journal of the Korean Vacuum Society
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    • v.9 no.4
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    • pp.436-441
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    • 2000
  • Plasma nitrocarburising is a thermochemical heat treatment, and can be used for plain carbon steels and low alloy steels to improve wear, corrosion and fatigue resistance. The process is performed on automotive parts, machinery parts and engineering tools. However, it is still facing problems in obtaining a mono $\varepsilon$ phased compound layer. Therefore, the aim of this research is to investigate the possibility of forming a mono $\varepsilon$ phased compound layer using a gas mixture of nitrogen and methane. It was found that high nitrogen contents were essential for the production of $\varepsilon$ phase compound layer and with increasing methane content in the gas mixture, $\varepsilon$ phase compound layer was favoured. In addition, when the methane content was further increased, cementite was observed in the compound layer. $\gamma$' phase was produced after 10 minutes treatment time and cementite was formed in the compound layer resulting in decreasing the thickness of the compound layer.

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Study of the Curing Time of Cementless Cold Central Plant Recycled Asphalt Base-Layer through Field-Application Review (무시멘트 상온 재활용 아스팔트 기층의 현장 적용성을 통한 양생기간에 관한 연구)

  • Choi, Jun Seong;Jung, Chul Ho;Lee, Chan Hee;Lim, in su
    • International Journal of Highway Engineering
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    • v.19 no.2
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    • pp.67-74
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    • 2017
  • PURPOSES : The objective of this study is to ascertain the curing period of cementless cold central plant recycled asphalt base-layer, using mechanical analyses and specimen quality tests on the field. METHODS : Cold central plant recycled asphalt base-layer mixture was produced in the plant from reclaimed asphalt, natural aggregate, filler for the cold mix, and the modified emulsion AP using asphalt mix design and plant mix design. In order to examine the applicability of the curing period during the field test, the international standards for the possibility of core extraction and the degree of compaction and LFWD deflection were analyzed. Moreover, Marshall stability test, porosity test, and indirect tensile strength test were performed on the specimens of asphalt mix and plant mix design. RESULTS : The plant production process and compaction method of cementless cold central plant recycled asphalt base-layer were established, and the applicability of the optical moisture content for producing the mixture was verified through the field test. In addition, it was determined that the core extraction method of the conventional international curing standard was insufficient to ensure performance, and the LFWD test demonstrated that the deflection converges after a two-day curing. However, the back-calculation analysis reveals that a three-day curing is satisfactory, resulting in a general level of performance of dense asphalt base-layer. Moreover, from the result of the specimen quality test of the asphalt mix design and plant mix design according to the curing period, it was determined that the qualities satisfied both domestic and international standards, after a two-day curing. However, it was determined that the strength and stiffness after three-day curing are higher than those after a two-day curing by approximately 3.5 % and 20 %, respectively. CONCLUSIONS:A three-day curing period is proposed for the cementless cold central plant recycled asphalt base-layer; this curing period can be demonstrated to retain the modulus of asphalt-base layer in the field and ensure stable quality characteristics.