• Title/Summary/Keyword: Mixed phase

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Investigation of Mix Design Method in Concrete Mixed with SSPCM Based on Mechanical Behaviors (SSPCM 혼입 콘크리트의 역학적 성능 기반 배합설계기법 연구)

  • Min, Hae-Won;Kim, Hee-Sun
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.2
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    • pp.1-7
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    • 2015
  • As energy consumption of building and the reduction of carbon dioxide emissions have been emphasized, phase change materials(PCM) have been introduced as building materials due to its high heat storage performance. Using shape-stabilizing technique, octadecane/xGnP shape-stabilized PCM(SSPCM) can prevent leakage and improve heat storage performance. The objectives of this study are to propose mix design method of concrete mixed with SSPCM and to evaluate mechanical behaviors of the concrete mixed with SSPCM manufactured according to the proposed mix design. Based on the previously reported material test result, the existing mix design of plain concrete(Concrete standard specification, 2009) is modified to consider reduction of strength in concrete due to the addition of SSPCM. To verify the proposed mix design, specimens are fabricated according to the proposed mix design and axial strength tests and three-point loading tests are performed. Test results show that compressive strengths of the tested specimens reach the designed strength even when two different mix ratios of SSPCM are used. From three-point loading tests, flexural stresses decrease as mix ratio of SSPCM increases.

Low temperature sintering and dielectric properties of $Sr_2(Ta_{1-x}Nb_x)_2O_7$ ceramics by the flux method (용융염합성법에 의한 $Sr_2(Ta_{1-x}Nb_x)_2O_7$ 세라믹스의 저온소성과 유전특성)

  • 남효덕
    • Electrical & Electronic Materials
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    • v.8 no.2
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    • pp.158-164
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    • 1995
  • Solid solutions Sr$_{2}$(Ta$_{1-x}$ Nb$_{x}$)$_{2}$O$_{7}$, (x=0.0-1.0), composed of strontium tantalate(Tc=-107.deg. C) and strontium-niobate(Tc=1342.deg. C) were prepared by the conventional mixed oxide method and the flux method(molten salt synthesis method). Phase relation, sintering temperature, grain-orientation and dielectric properties for sintered ceramic samples were investigated with different compositions. Both Curie temperature and dielectric constant at Curie temperature were increased, and sintering behavior and the degree of grain-orientation were improved with the increase of Nb content. The single phase Sr$_{2}$(Ta/sib 1-x/Nb$_{x}$)$_{2}$O$_{7}$ powder was synthesized by using the flux method at lower temperatures, and sintering temperature was also reduced by using the flux method-derived powder than using the mixed oxide-derived powder. Sintering characteristics and dielectric properties of the specimens prepared by the flux method were better than those derived through the conventional mixed oxide method.thod.hod.

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Bifurcation Phase Studies of Belousov-Zhabotinsky Reaction Containing Oxalic Acid and Acetone as a Mixed Organic Substrate in an Open System

  • Basavaraja, C.;Huh, Do-Sung;Park, Sung-Hyun;Jeon, Un-Ji;Pierson, R.;Vishnuvardhan, T.K.;Kulkarni, V.R.
    • Bulletin of the Korean Chemical Society
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    • v.28 no.9
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    • pp.1489-1492
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    • 2007
  • Belousov-Zhabotinsky (BZ) reaction containing oxalic acid and acetone as a mixed organic substrate catalyzed by Ce(IV) in a flow system has been investigated. The reaction system is analyzed by varying flow rate, inflow concentrations, and temperature. Interchangeable oscillating patterns are observed in a certain range of concentrations, and above or below the condition a steady state is obtained. The increase in temperature increases the frequency and decreases the amplitude of oscillations. The apparent activation energy for the system is calculated by using the Arrhenius equation, which means that temperature has a greater effect on the reaction. Bifurcation phase diagrams for the system show the region of oscillations or steady states along with a small region of multistability. Further the behavioral trend observed in this system is discussed by mechanistic character of the system.

A Study on the Stabilization of Asphalt Emulsion with Phase Inversion Emulsification Method (반전유화법에 의한 유화아스팔트의 안정성 연구)

  • Heo, Woo-Sung;Lee, Eun-Kyoung;Choi, Sei-Young
    • Elastomers and Composites
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    • v.44 no.2
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    • pp.143-149
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    • 2009
  • In this study, asphalt emulsion was manufactured by phase inversion emulsification method with nonionic surfactants(Span 80, Span 60, Tween 80, and Tween 60), anionic surfactant(SLS) and cationic surfactant(Imidazole) in different feeding ratio to make up for the week points of asphalt. Its stabilization was carefully investigated with respect to droplet size, viscosity, zeta potential, and water-proofing property. When the surfactants mixed with nonionic and anionic surfactant were used into the asphalt, a stabilization of the asphalt emulsion was good. As the amount of the mixed surfactant was increased, the droplet size of asphalt emulsion were decreased, while the viscosity and zeta potential were increased. When the surfactants mixed with nonionic and anionic surfactant were used into the asphalt, a stabilization of asphalt emulsion was good.

Failure Path of the Brown-oxide-coated Copper-based Leadframe/EMC Interface under Mixed-Mode Loading (혼합하중 조건하에서 갈색산화물이 입혀진 구리계 리드프레임/EMC 계면의 파손경로)

  • 이호영
    • Journal of the Korean institute of surface engineering
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    • v.36 no.6
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    • pp.491-499
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    • 2003
  • Copper-based leadframe sheets were oxidized in a hot alkaline solution to form brown-oxide layer on the surface and molded with epoxy molding compound (EMC). The brown-oxide-coated leadframe/EMC joints were machined to form sandwiched double-cantilever beam (SDCB) specimens and sandwiched Brazil-nut (SBN) specimens for the purpose of measuring the fracture toughness of leadframe/EMC interfaces. The SDCB and the SBN specimens were designed to measure the fracture toughness of the leadframe/EMC interfaces under nearly mode-I loading and mixed-mode (mode I + mode II) loading conditions, respectively. Fracture surfaces were analyzed by various equipment such as glancing-angle XRD, SEM, AES, EDS and AFM to elucidate failure path. Results showed that failure occurred irregularly in the SDCB specimens, and oxidation time of 2 minutes divided the types of irregular failures into two classes. The failure in the SBN specimens was quite different from that in the SDCB specimens. The failure path in the SBN specimens was not dependent on the phase angle as well as the distance from tips of pre-cracks.

Low cost 2.4-GHz VCO design in 0.18-㎛ Mixed-signal CMOS Process for WSN applications (저 가격 0.18-㎛ 혼성신호 CMOS공정에 기반한 WSN용 2.4-GHz 밴드 VCO설계)

  • Jhon, Heesauk;An, Chang-Ho;Jung, Youngho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.24 no.2
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    • pp.325-328
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    • 2020
  • This paper demonstrated a voltage-controlled oscillator (VCO) using cost-effective (1-poly 6-metal) mixed signal standard CMOS process. To have the high-quality factor inductor in LC resonator with thin metal thickness, patterned-ground shields (PGS) was adopted under the spiral to effectively reduce the ac current of low resistive Si substrate. And, because of thin top-metal compared with that of RF option (2 ㎛), we make electrically connect between the top metal (M6) and the next metal (M5) by great number of via array along the metal traces. The circuit operated from 2.48 GHz to 2.62 GHz tuned by accumulation-mode varactor device. And the measured phase noise of LC VCO has -123.7 dBc/Hz at 1MHz offset at 2.62 GHz and the dc-power consumption shows 2.07 mW with 1.8V supply voltage, respectively.

A Study on in-situ Electrolytic Stripping of a Metal Ion by Using a Highly Packed Glassy Carbon Fiber Column Electrode System (고밀집 Glassy Carbon 섬유 다발체 전극 전해계를 이용한 금속 이온의 in-situ 전해 역추출 특성 연구)

  • Kim, Kwang-Wook;Kim, Young-Hwan;Lee, Eil-Hee;Yoo, Jae-Hyung
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.475-480
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    • 1998
  • A study on the electrochemical reduction of uranium (VI) to uranium (IV) was carried out in the mixed phases of an organic phase with uranium (VI) and aqueous phase of nitric acid by use of a highly packed glassy carbon (GC) fiber column electrode system, and a model for in-situ electrolytic stripping of uranium (VI) was suggested. The electrochemical reduction of uranium (VI) occurred faster in organic phase than in aqueous phase of the mixed phases. The uranium stripping yield increased and then became constant with the increase of organic flow rate of the electrolytic system due to the increase of diffusion resistance of uranium ions in the organic phase into the aqueous phase. Aqueous flow rate, on the other hand, didn't affect the total uranium (VI) reduction current in the system. The system combined with electrochemical reduction was confirmed to be much more effective than the simple system without it in stripping uranium.

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Turbulent properties in a mixed statistically stationary flow

  • Baek, Tae-Sil;Doh, Deog-Hee
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.7
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    • pp.729-736
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    • 2013
  • The turbulent properties in a mixed statistically stationary flow were investigated experimentally by a pseudo stereoscopic PIV. In order to validate the experimental results, the profiles of the turbulent kinetic energy were evaluated with the flow features. A mechanical agitator having 6 blades was installed at the bottom of the mixing tank (D=60cm, H=60cm). The agitator was rotated with 80rpm clockwise and counter-clockwise. For the measurements, three cameras were used and all were synchronized. The images captured by one of the three cameras was used for the measurement of rotational speed, and the images captured by the other two cameras were used to measure three dimensional components of velocity vectors. All vectors captured at the same rotational angle were phase averaged to construct three-dimensional vector fields to reconstruct the spatial distribution of the flow properties. It was seen that the jet scrolling along the tank was the main source of mixing.

RF-Sputted Vanadium Oxide Thin Films:Effect of Oxygen Partial Pressure on Structural and Electrochemical Properties

  • Park, Yong Jun;Park, Nam Gyu;Ryu, Gwang Seon;Jang, Sun Ho;Park, Sin Jong;Yun, Seon Mi;Kim, Dong Guk
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.1015-1018
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    • 2001
  • Vanadium oxide thin films with thickness of about 2000 $\AA$ have been prepared by radio frequency sputter deposition using a V2O5 target in a mixed argon and oxygen atmosphere with different Ar/O2 ratio ranging from 99/1 to 90/10. X-ray diffraction and X-ray absorption near edge structure spectroscopic studies show that the oxygen content higher than 5% crystallizes a stoichiometric V2O5 phase, while oxygen deficient phase is formed in the lower oxygen content. The oxygen content in the mixed Ar + O2 has a significant influence on electrochemical lithium insertion/deinsertion property. The discharge-charge capacity of vanadium oxide film increases with increasing the reactive oxygen content. The V2O5 film deposited at the Ar/O2 ratio of 90/10 exhibits high discharge capacity of 100 ${\mu}Ah/cm2-{\mu}m$ along with good cycle performance.

Amorphous Silicon Carbon Nitride Films Grown by the Pulsed Laser Deposition of a SiC-$Si_3N_4$ Mixed Target

  • Park, Nae-Man;Kim, Sang-Hyeob;Sung, Gun-Yong
    • ETRI Journal
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    • v.26 no.3
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    • pp.257-261
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    • 2004
  • We grew amorphous SiCN films by pulsed laser deposition using mixed targets. The targets were fabricated by compacting a mixture of SiC and $SiC-{Si_3}{N_4}$ powders. We controlled the film stoichiometry by varying the mixing ratio of the target and the target-to-substrate distance. The mixing ratio of the target had a dominant effect on the film composition. We consider the structures of the SiCN films deposited using 30~70 wt.% SiC in the target to be an intermediate phase of SiC and $SiN_x$. This provides the possibility of growing homogeneous SiCN films with a mixed target at a moderate target-to-substrate distance.

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