• Title/Summary/Keyword: Mixed phase

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Effect of Storage Temperature on the Dispersion Stability of O/W Nano-emulsions (O/W 나노에멀젼 분산안정성에 미치는 보관온도의 영향)

  • Lee, Ye-Eun;Yoo, In-Sang
    • KSBB Journal
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    • v.29 no.5
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    • pp.385-391
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    • 2014
  • In this study, the emulsion dispersion stability of optimizing storage temperature was investigated. The system was based on oil/water (O/W) emulsions. In order to evaluate the stability, mean diameter of droplet was measured as a function of temperature with various mixed hydrophilic lipophilic balance (HLB). In addition, the correlations between phase inversion temperature (PIT) and the optimum storage temperature were probed. In this system, majority of the smallest droplet was shown at temperature of $20^{\circ}C$ below PIT. Whether the temperature was increased or decreased from the optimum, size of the droplet increased. According to the mixed HLB, the particle size and optimum storage temperature were also affected. As the concentrations of surfactant were increased, the size of particle decreased with lower optimum temperature for storage. If the surfactant (4 wt%) were mixed with HLB, the optimum storage temperature was $21^{\circ}C$ for maintaining the size of smallest droplet at 108.3 nm in diameter. At above optimum condition, increased size of particle was observed approximately 4 % increases from 108.2 nm to 112.3 nm after 600 hours. The size of particle in emulsion was maintained stably without any considerable effect of Ostwald ripening phenomena at the optimum storage temperature with low polydispersity index.

Effect of Microstructural Design on the Electrical Properties of Y2O3-Stabilized ZrO2 (미세구조 설계에 따른 이트리아 안정화 지르코니아의 전기적 성질 변화)

  • 김선재;김경호;오석진;강대갑;국일현
    • Journal of the Korean Ceramic Society
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    • v.30 no.9
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    • pp.717-722
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    • 1993
  • Effects of microstructures on the electrical properties of ZrO2 based ceramics were analyzed by modeling layer arrangements and mixed phase structures. Single layers and alternating multilayers were made from 3mol% and 8mol% Y2O3 doped ZrO2 powders, while mixed specimen was made by blending and compacting these raw powders. After sintering at 150$0^{\circ}C$ for 2hr in air, AC impedance characteristics were measured. Contributiion of bulk comonent to total resistivity and its temperature-dependence were larger in 8Y-ZrO2 single layer than in 3Y-ZrO2 single layer. The multilayered specimen connected in serial to electrodes showed partial characteristics of both 3Y-ZrO2 and 8Y-ZrO2 single layers. The multilayered specimen connected in parallel to electrodes and the mixed specimen exhibited characteristics mainly of 8Y-ZrO2 single layer. The multilayered specimen connected in parallel to electrodes revealed the highest electrical conductivity near the operating temperature of solid oxide fuel cell. However, it is expected that the mixed specimen is appropriate for the applications because of its relatively high electrical conductivity with high strength expected.

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Effect of NaCl on the Mixed Micellar Properties of Sodium Dodecyl Sulfate(SDS) with Tetraethylene Glycol Monododecyl Ether(TGME) (Sodium Dodecyl Sulfate(SDS)와 Tetraethylene Glycol Monododecyl Ether(TGME)의 혼합미셀화에 미치는 NaCl의 효과)

  • Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.39 no.12
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    • pp.896-901
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    • 1995
  • The critical micelle concentrations(CMC$^*$) of the mixed surfactant systems of Sodium dodecyl sulfate(SDS) with Tetraethylene glycol monododecyl ether(TGME) in the aqueous solutions of NaCl at $25^{\circ}C$ were determined as a function of the overall mole fraction of $SDS(\alpha1)$ by the use of surface tension method. Various thermodynamic parameters for the micellization of SDS/TGME mixed surfactant systems were calculated and analyzed by means of the equations derived from the nonideal mixed micelle model, based on the pseudo-phase separation model.

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Joint Interface Observation of V and 17-4PH Stainless Steel Dissimilar Materials Manufactured by Direct Energy Deposition (직접 에너지 적층방식으로 제조된 V과 17-4PH 스테인리스강 이종재료의 접합계면 분석)

  • Lee, Se-Hwan;Kim, Hobeom;Kim, Jeoung Han
    • Journal of Powder Materials
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    • v.29 no.1
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    • pp.8-13
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    • 2022
  • In this study, we have prepared a Ti-6Al-4V/V/17-4 PH composite structure via a direct energy deposition process, and analyzed the interfaces using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The joint interfaces comprise two zones, one being a mixed zone in which V and 17-4PH are partially mixed and another being a fusion zone in the 17-4PH region which consists of Fe+FeV. It is observed that the power of the laser used in the deposition process affects the thickness of the mixed zone. When a 210 W laser is used, the thickness of the mixed zone is wider than that obtained using a 150 W laser, and the interface resembles a serrated shape. Moreover, irrespective of the laser power used, the expected σ phase is found to be absent in the V/17-4 PH stainless steel joint; however, many VN precipitates are observed.

The Development of a Haptic Interface for Interacting with BIM Elements in Mixed Reality

  • Cho, Jaehong;Kim, Sehun;Kim, Namyoung;Kim, Sungpyo;Park, Chaehyeon;Lim, Jiseon;Kang, Sanghyeok
    • International conference on construction engineering and project management
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    • 2022.06a
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    • pp.1179-1186
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    • 2022
  • Building Information Modeling (BIM) is widely used to efficiently share, utilize and manage information generated in every phase of a construction project. Recently, mixed reality (MR) technologies have been introduced to more effectively utilize BIM elements. This study deals with the haptic interactions between humans and BIM elements in MR to improve BIM usability. As the first step in interacting with virtual objects in mixed reality, we challenged moving a virtual object to the desired location using finger-pointing. This paper presents the procedure of developing a haptic interface system where users can interact with a BIM object to move it to the desired location in MR. The interface system consists of an MR-based head-mounted display (HMD) and a mobile application developed using Unity 3D. This study defined two segments to compute the scale factor and rotation angle of the virtual object to be moved. As a result of testing a cuboid, the user can successfully move it to the desired location. The developed MR-based haptic interface can be used for aligning BIM elements overlaid in the real world at the construction site.

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Fabrication of Poly(L-lactide) Scaffold Membranes through Phase Inversion with Pure and Mixed Solvents (순수용매와 혼합용매를 이용한 상전이를 통한 Poly(L-lactide) 스캐폴드 막의 제조)

  • Kim, Young Kyoung;Cho, Yu Song;Koo, Ja-Kyung
    • Membrane Journal
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    • v.25 no.1
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    • pp.48-59
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    • 2015
  • This paper reports a fabrication of poly(L-lactic acid) (PLLA) scaffold membranes through phase separation process using pure and mixed solvents. Chloroform and 1,4-dioxane were used as pure solvents and mixed solvents were obtained by mixing the pure solvents together. Morphologies, mechanical properties and mass transfer characteristics of the scaffold membranes were investigated through SEM, stress-strain test and glucose diffusion test. Scaffold membranes from the solution with pure chloroform showed solid-wall pore structure. In contrast, nano-fibrous membranes were fabricated from the solution with pure 1,4-dioxane. In case of mixed solvents, the scaffold membranes showed various structures with changing composition of the solvents. When 1,4-dioxane content was lower than 20 wt% in the solvent, scaffold membrane showed solid-wall pore structure. When the content was 20 wt%, scaffold membranes with macropores with the maximum size of $100{\mu}m$ was obtained. In the concentration range of 1,4-dioxane over 25 wt%, the scaffold membranes showed nano-fibrous structures. In this range, the fibers showed different diameters with changing composition of the solvent. The minimum fiber diameter was about $15{\mu}m$, when 1,4-dioxane composition was 80 wt%. These results indicate that the composition of the solvent showed a significant effect on the structure of scaffold membrane.

Scalable Fabrications of Mixed-Matrix Membranes via Polymer Modification-Enabled In Situ Metal-Organic Framework Formation for Gas Separation: A Review (고분자 변형으로 가능해진 MOF의 원위치 형성을 이용한 혼합기질 기체분리막의 대면적화 가능한 제막)

  • Sunghwan Park;Young-Sei Lee
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.213-220
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    • 2023
  • Mixed-matrix membranes (MMMs), which are composed of a polymer matrix filled with high-performance fillers as a dispersed phase, have been intensively studied for gas separations for the past 30 years. It has been demonstrated that MMMs exhibit superior gas separation performance compared to polymer membranes and are more scalable than polycrystalline membranes. Despite their potential, the commercialization of MMMs has yet to be reported due to several challenging issues. One of the major challenges of MMMs is the non-ideal interface between the continuous polymer phase and dispersed phase, which can result in defect formation (i.e., interfacial voids, etc.). With respect, many MMM studies have focused on addressing the issues through scientific approaches. The engineering approaches for facile and effective large-scale fabrication of MMMs, however, have been relatively underestimated. In this review paper, a novel strategy for fabricating MMMs in a facile and scalable manner using in situ metal-organic framework (MOF) formation is introduced. This new MMM fabrication methodology can effectively address the issues facing current MMMs, likely facilitating the commercialization of MMMs.

Synthesis of TiC/Co Composite Powder by the Carbothermal Reduction Process (환원/침탄공정에 의한 TiC/Co 복합분말 합성)

  • Lee, Gil-Geun;Ha, Gook-Hyun
    • Journal of Powder Materials
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    • v.16 no.5
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    • pp.310-315
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    • 2009
  • Ultra-fine TiC/Co composite powder was synthesized by the carbothermal reduction process without wet chemical processing. The starting powder was prepared by milling of titanium dioxide and cobalt oxalate powders followed by subsequent calcination to have a target composition of TiC-15 wt.%Co. The prepared oxide powder was mixed again with carbon black, and this mixture was then heat-treated under flowing argon atmosphere. The changes in the phase, mass and particle size of the mixture during heat treatment were investigated using XRD, TG-DTA and SEM. The synthesized oxide powder after heat treatment at 700$^{\circ}C$ has a mixed phase of TiO$_2$ and CoTiO$_3$ phases. This composite oxide powder was carbothermally reduced to TiC/Co composite powder by the solid carbon. The synthesized TiC/Co composite powder at 1300$^{\circ}C$ for 9 hours has particle size of under about 0.4 $\mu$m.

Integrated mathematical programming Approach of Cell formation and facility layout in cellular manufacturing (셀형제조시스템에서 셀형성과 설비배치를 통합한 수리계획모형에 관한 연구)

  • Lee Sang-Wan;Kim Hae-Sik;Cho Sung-Youl
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.28 no.2
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    • pp.94-100
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    • 2005
  • This paper presents the application of integrated mathematical programming approach for the design of cellular manufacturing. The proposed approach is carried out in two phases The first phase concerning exceptional elements(EEs) in cell formation and the second phase facilities layout design. This paper considers the total costs of three important costs for (1) intercellular transfer (2) machine duplication and (3) subcontracting. One of Important issue is the calculation of the number of machines considering the maximum utilization of machines and the available capacity of a machines that can be transferred between cells. Facilities layout design is considered to reflect the real field data taking in to account the operational sequence of the parts to be manufactured. The model is formulated as mixed integer programming that is employed to find the optimal solution.

Physical Properties of Microencapsulated Phase Change Material Slurries (미립잠열슬러리의 물성에 관한 실험적 연구)

  • 이효진;홍재창;이재구
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.9
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    • pp.860-869
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    • 2000
  • The thermal conductivity and density of slurries entrained with the particles of Micro-PCM are measured with respect to its temperatures as well as concentrations. For the thermal conductivity of slurries, a device made from P.A. Hilton (Model No. H470) is adopted. There is a well-scaled 0.3 mm gap between shells into which the slurry is injected. The temperatures of the slurry are changed to $5~25^{\circ}C$ , for which it is controled by the supplied voltage and cooling water circulated around the outer shell. The concentrations of Micro-PCM slurries are varied from 5 wt% to 50 wt%. Some general equations such as Maxwell's equation, are evaluated for their applicability with Micro-PCM slurry. As a result, it happens to be some 20% discrepancy between the experiment and the applied equations. The density measurements of Micro-PCM slurry to its temperature and concentration are peformed by hydrometer. For the experiment, tetradecane encapsulated slurry (($t_m≒6^{\circ}C$) and a mixed wax ($t_m≒50^{\circ}C$) are tested. The temperature changes of tetradecane are applied for $0^{\circ}C\;to\;$20^{\circ}C$and a mixed wax for $20^{\circ}C\;to\;$60^{\circ}C$ and its concentrations are changed from 5 wt% to 30 wt%. The results are compared with a general equation and the referenced data. For the conclusion, the experimental result and a general equation are well agreed.

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