• Title/Summary/Keyword: Mixed Gases

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Interface Characteristics and Electrical Properties of SiO2 and V2O5 Thin Films Deposited by the Sputtering (스퍼터링 방법으로 증착한 SiO2와 V2O5박막의 전류특성과 계면분석)

  • Li, Xiangjiang;Oh, Teresa
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.4
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    • pp.66-69
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    • 2018
  • This study was researched the electrical properties of semiconductor devices such as ITO, $SiO_2$, $V_2O_5$ thin films. The films of ITO, $SiO_2$, $V_2O_5$ were deposited by the rf magnetron sputtering system with mixed gases of oxygen and argon to generate the plasma. All samples were cleaned before deposition and prepared the metal electrodes to research the current-voltage properties. The electrical characteristics of semiconductors depends on the interface's properties at the junction. There are two kinds of junctions such as ohmic and schottky contacts in the semiconductors. In this study, the ITO thin film was shown the ohmic contact properties as the linear current-voltage curves, and the electrical characteristics of $SiO_2$ and $V_2O_5$ films were shown the non-linear current-voltage curves as the schottky contacts. It was confirmed that the electronic system with schottky contacts enhanced the electronic flow owing to the increment of efficiency and increased the conductivity. The schottky contact was only defined special characteristics at the semiconductor and the interface depletion layer at the junction made the schottky contact which has the effect of leakage current cutoff. Consequently the semiconductor device with shottky contact increased the electronic current flow, in spite of depletion of carriers.

Effects of Powder Property and Sintering Atmosphere on the Properties of Burnable Absorber Fuel : I. $UO_2-Gd_2O_3$ Fuel

  • K. W. Song;Kim, K. S.;H. S. Yoo;Kim, J. H.
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.171-176
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    • 1997
  • UO$_2$-Gd$_2$O$_3$fuel has been sintered to study the effect of powder property and sintering atmospheres on densification and microstructure. Three types of powders have been used; AUC-UO$_2$ powder and ADU-UO$_2$ powder were mixed with Gd$_2$O$_3$ Powder, and co-milled AUC-UO$_2$ and Gd$_2$O$_3$ powder. UO$_2$-(2, 5, 10)wt% Gd$_2$O$_3$pellets have been sintered at 168$0^{\circ}C$ for 4 hours in the mixture of H$_2$ and $CO_2$ gases, of which oxygen potential has been controlled by the ratio of $CO_2$ to H$_2$ gas. Densities of UO$_2$-Gd$_2$O$_3$ fuel pellets are quite dependent on powder types, and UO$_2$-Gd$_2$O$_3$ fuel using co-milled UO$_2$ powder yields the highest density. A long range homogeneity of Gd is determined by powder mixing. As the oxygen potential of sintered atmosphere increases, the sintered densities of UO$_2$-Gd$_2$O$_3$ pellets decrease but grain size increases. In addition, (U, Gd)O$_2$ solid solution becomes more homogeneous. The UO$_2$-Gd$_2$O$_3$fuel having adequate density and homogeneous microstructure can be fabricated by co-milling powder and by high oxygen potential.

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Studies on the Isolation and Identification of Bacillus sp. for the Composting of Swine Manure and the Removal of Malodorous Gases from its Liquid Compost (돈분의 퇴비화를 위한 Bacillus sp.의 분리 동정 및 그 액체 비료의 악취 제거 연구)

  • 김규동;김기연;함영태
    • Korean Journal of Microbiology
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    • v.40 no.2
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    • pp.154-159
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    • 2004
  • Bacillus species were isolated from swine manure to develope the microbial additive suitable for the rapid com-posting. The 3 of 4 isolated strains were identified as Bacillus cereus KD-2, B. pumilus KD-3, and B. licheni-formis KD-4. Bacillus sp. KD-1 was, however, not highly identical with any Bacillus sp. The isolated strains were analyzed their growth rates, enzyme activities, and antibacterial activities. The maximum growth tem-peratures of KD-1, KD-2, KD-3 and KD-4 were $45^{\circ}C$, $50^{\circ}C$, $53^{\circ}C$, and $55^{\circ}C$, respectively. The activities of pro-tease or amylase in mixed culture of 4 strains were similar in the range of $37^{\circ}C$ to $53^{\circ}C$ and activities of lipase in the range of $37^{\circ}C$ to $42^{\circ}C$ were twice higher than those of lipase in the range of $47^{\circ}C$ to $53^{\circ}C$. The antibacterial activity of KD-l, KD-2, or KD-3 against each other was not detected. That of KD-4 against KD-1, KD-2, or KD-3 was, however, detected. The organic compound and C/N ratio of compost fermented by the mixed culture were determined as 61.9% and 22.4%, respectively. The concentration of the ammonia gas was 12.35 mg/l in the liquid compost.

The Study on the Combustion and Ash Deposition Characteristics of Ash Free Coal and Residue Coal in a Drop Tube Furnace (DTF를 이용한 무회분 석탄과 잔탄의 연소 및 회 점착 특성에 관한 연구)

  • Moon, Byeung Ho;Kim, Jin Ho;Sh, Lkhagvadorj;Kim, Gyu Bo;Jeon, Chung Hwan
    • Journal of Energy Engineering
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    • v.24 no.4
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    • pp.89-96
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    • 2015
  • Recently, much research has been put into finding the causes and solutions of slagging/fouling problems that occur at the end of the boiler. This slagging/fouling, caused by low-rank coal's ash, disturbs the thermal power and greatly reduces efficiency. In environmental aspects, such as NOx pollution, governments have been implementing restrictions on the quantity of emission gases that can be released into the atmosphere. To solve these problems, research on Ash Free Coal (AFC), which eliminates ash from low-rank coal, is in progress. AFC has advantages over similar high-rank coals because it increases the heating value of the low grade coal, reduces the contaminants that are emitted, and decreases slagging/fouling problems. In this study, using a DTF, the changes of NOx emissions, unburned carbon, and the characteristics of ash deposition were identified. KCH raw coal, AFC extracted from KCH, residue coal, Glencore, and Mixed Coal (Glencore 85wt% and residue coal 15wt%) were studied. Results showed that AFC had a significantly lower emission of NOx compared to that of the raw coal and residue coal. Also, the residue coal showed a higher reactivity compared to raw coal. And finally, In the case of the residue coal and mixed coal, they showed a lower ash deposition than that of low-rank coal.

Research on Fire Safety of Mortar-Containing Waste Tire Powders and Flame Retardant (폐타이어 분말과 난연제가 혼입된 모르타르의 화재안전에 관한 연구)

  • Park, Jeong-Jin;Son, Ki-Sang
    • Fire Science and Engineering
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    • v.24 no.4
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    • pp.12-17
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    • 2010
  • The purpose of this study is to determine how effectively waste tire recycled material mixed with flame retardant work in combating fire. As discovered in the previous study, waste tire mixed with cement mortar has more insulation capacity. However, this mortar is weak against fire. Therefore flame retardant, with a specific proportional mix, will be added to increase its fire prevention capacity. Tests will be made in accordance with ISO 5657 procedures for measuring fire ignition time, flame and shape variation of test pieces at the Building Material Test Institute. The test piece will be set up with horizontal levels having a constant radiation heat of $1{\sim}5W/cm^2$. Temperature transfers and increases from the surface into the interior. Combustible gases result due to pyrolysis, and regular contact is maintained between the fire source and the center of the test piece for assessment purposes. Ignition has not been occurred without adding retardant meaning that there is almost no possibility of ignition of waste tire particle. This fact can be considered as fire load to appreciate a volume of combustion materials. Flame is not occurred due to heat-absorbing effect by adding non-organic series retardant into waste tire particle. Conclusions have been summarized as follows; 1) Combustion of building material can be decreased by adding retardant to waste tire-mixing mortar. But compressive strength and insulation capacity of the material should be measured later. 2) Firing prevention and ignition are main points of building fire. Reasonable fire engineering assessment of interior material should be made for establishing effective disaster prevention system.

A study on permeation of $CO_2-N_2-O_2$ mixed gases through a NaY zeolite membrane under permeate evacuation mode (진공모드에서 NaY 제올라이트 막의 $CO_2-N_2-O_2$ 혼합기체의 투과거동 연구)

  • Jeong, Su Jung;Yeo, Jeong-Gu;Han, Moon Hee;Cho, Churl Hee
    • Membrane Journal
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    • v.23 no.5
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    • pp.352-359
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    • 2013
  • In the present study, $CO_2$ permeation through a hydrophilic NaY zeolite membrane was studied under permeate evacuation mode for $CO_2$ single gas, $CO_2-N_2$ and $CO_2-O_2$ binary mixtures, and $CO_2-N_2-O_2$ ternary mixture. It was reconfirmed that the $CO_2$ permeation was governed by surface diffusion and the $CO_2$ selectivity was induced from blocking effect of adsorbed $CO_2$ molecules. The $CO_2$ permeance measured in permeate evacuation mode was much lower than that done in He sweeping mode, but was comparable to that obtained under feed pressurization mode. The NaY zeolite membrane showed a considerable $CO_2$ separation for $14%CO_2-80%N_2-6%O_2$ mixture : $CO_2$ permeance was about $1{\times}10^{-7}mol/m^2secPa$ and $CO_2$ selectivity was more than 10. Therefore, it was concluded that NaY zeolite membrane was one of promising membranes for post-combustion CCS process.

Cellulose Nanocrystals Incorporated Poly(arylene piperidinium) Anion Exchange Mixed Matrix Membranes (셀룰로오스 나노 결정을 도입한 폴리아릴렌 피페리디늄 음이온 교환 복합매질분리막)

  • Da Hye Sim;Young Park;Young-Woo Choi;Jung Tae Park;Jae Hun Lee
    • Membrane Journal
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    • v.34 no.2
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    • pp.154-162
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    • 2024
  • Anion exchange membranes (AEMs) are essential components in water electrolysis systems, serving to physically separate the generated hydrogen and oxygen gases while enabling the selective transport of hydroxide ions between electrodes. Key characteristics sought in AEMs include high ion conductivity and robust chemical and mechanical stability in alkaline. In this study, quaternized Poly(terphenyl piperidinium)/cellulose nanocrystals (qPTP/CNC) mixed matrix membrane was fabricated. The polymer matrix, PTP, was synthesized via super-acid polymerization, known for its excellent ion conductivity and alkaline durability. The qPTP/CNC membrane showed a dense and uniform morphology without significant voids or large aggregates at the polymer-nanoparticle interface. The qPTP/CNC membrane containing 2 wt% CNC demonstrated a high ion exchange capacity of 1.90 mmol/g, coupled with low water uptake (9.09%) and swelling ratio (5.56%). Additionally, the qPTP/CNC membrane showed significantly lower resistance and superior alkaline stability (384 hours at 50℃ in 1 M KOH) compared to the commercial FAA-3-50 membrane. These results highlight the potential of hydrophilic additive CNC in enhancing ion conductivity and alkaline durability of ion exchange membranes.

Changes of Blood Gases, Plasma Catecholamine Concentrations and Hemodynamic Data in Anesthetized Dogs during Graded Hypoxia Induced by Nitrous Oxide (아산화질소에 의한 점진적 저산소가스 흡입이 혈중 가스치와 Catecholamine치 및 혈역학에 미치는 영향)

  • Kim, Sae-Yeon;Song, Sun-Ok;Bae, Jung-In;Cheun, Jae-Kyu;Bae, Jae-Hoon
    • Journal of Yeungnam Medical Science
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    • v.15 no.1
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    • pp.97-113
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    • 1998
  • The sympathoadrenal system plays an important role in homeostasis in widely varing external environments. Conflicting findings, however, have been reported on its response to hypoxia. We investigated the effect of hypoxia on the sympathoadrenal system in dogs under halothane anesthesia by measuring levels of circulating catecholamines in response to graded hypoxia. Ten healthy mongreal dogs were mechanically ventilated with different hypoxic gas mixtures. Graded hypoxia and reoxygenation were induced by progressively decreasing the oxygen fraction in the inhalation gas mixture from 21%(control) to 15%, 10% and 5% at every 5 minutes, and then reoxygenated with 60% oxygen. Mean arterial pressure, central venous pressure and mean pulmonary arterial pressure were measured directly using pressure transducers. Cardiac output was measured by the thermodilutional method. For analysis of blood gas, saturation and content, arterial and mixed venous blood were sampled via the femoral and pulmonary artery at the end of each hypoxic condition. The concentration of plasma catecholamines was determined by radioenzymatic assay. According to the exposure of graded hypoxia, not only did arterial and mixed venous oxygen tension decreased markedly at 10% and 5% oxygen, but also arterial and mixed venous oxygen saturation decreased significantly. An increased trend of the oxygen extraction ratio was seen during graded hypoxia. Cardiac output, mean arterial pressure and systemic vascular resistance were unchanged or increased slightly. Pulmonary arterial pressure(PAP) and pulmonary vascular resistance(PVR) were increased by 55%, 76% in 10% oxygen and by 82%, 95% in 5% oxygen, respectively(p<0.01). The concentrations of plasma norepinephrine, epinephrine and dopamine increased by 75%, 29%, 24% in 15% oxygen and by 382%, 350%, 49% in 5% oxygen. These data suggest that the sympathetic nervous system was activated to maintain homeostasis by modifying blood flow distribution to improve oxygen delivery to tissues by hypoxia, but hemodynamic changes might be blunted by high concentration of nitrous oxide except PAP and PVR. It would be suggested that hemodynamic changes might not be sensitive index during hypoxia induced by high concentration of nitrous oxide exposure.

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Estimation of non-CO2 Greenhouse Gases Emissions from Biomass Burning in the Samcheok Large-Fire Area Using Landsat TM Imagery (Landsat TM 영상자료를 활용한 삼척 대형산불 피해지의 비이산화탄소 온실가스 배출량 추정)

  • Won, Myoung-Soo;Koo, Kyo-Sang;Lee, Myung-Bo;Son, Yeong-Mo
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.10 no.1
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    • pp.17-24
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    • 2008
  • This study was performed to estimate non-$CO_2$ greenhouse gases (i.e., GHGs) emission from biomass burning at a local scale. Estimation of non-$CO_2$ GHGs emission was conducted using Landsat TM satellite imagery in order to assess the damage degree in burnt area and its effect on non-$CO_2$ GHGs emission. This approach of estimation was based on the protocol of the 2003 IPCC Guidelines. In this study, we used one of the most severe fire cases occurred Samcheock in April, 2004. Landsat TM satellite imageries of pre- and post-fire were used 1) to calculate delta normalized burn ratio (dNBR) for analyzing burnt area and burn severity of the Samcheok large-fire and 2) to quantify non-$CO_2$ GHGs emission from different size of the burnt area and the damage degree. The analysis of dNBR of the Samcheok large-fire indicated that the total burnt area was 16,200ha and the size of the burnt area differed with the burn severity: out of the total burnt area, the burn severities of Low (dNBR < 152), Moderate (dNBR = 153-190), and High (dNBR = 191-255) were 35%, 33%, and 32%, respectively. It was estimated that the burnt areas of coniferous forest, deciduous forest, and mixed forest were about 11,506ha (77%), 453ha (3%), and 2,978ha (20%), respectively. The magnitude of non-$CO_2$ GHGs emissions from the Samcheok large-fire differed significantly, showing 93% of CO (44.100Gg), 6.4% of CH4 (3.053Gg), 0.5% of $NO_x$ (0.238Gg), and 0.1% of $N_2O$ (0.038Gg). Although there were little changes in the total burnt area by the burn severity, there were differences in the emission of non-$CO_2$ GHGs with the degree of the burn severity. The maximum emission of non-$CO_2$ GHGs occurred in moderate burn severity, indicating 47% of the total emission.

3-D petroleum system modeling of the Jeju Basin, offshore southern Korea (남해 대륙붕 제주분지의 3-D 석유시스템 모델링)

  • Son, Byeong-Kook;Lee, Ho-Young
    • Journal of the Geological Society of Korea
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    • v.54 no.6
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    • pp.587-603
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    • 2018
  • 3-D petroleum system modeling was performed on the Jeju Basin, offshore southern Korea to analyze the hydrocarbon migration and accumulation as well as the generation and expulsion of the hydrocarbon, based on subsurface structure maps of respective sedimentary formations. The lowermost formation deposited in Eocene time was assigned as a source rock, for which a mixed kerogen of type II and III was input in the modeling of oil and gas generation in consideration of the sedimentary environment of fluvio-lacustrine condition. Initial TOC was 4% as an input, based on the analysis of the well data and sedimentary environment. The modeling results show that a considerable amount of hydrocarbons was generated and expelled from the source rocks at the western Joint Development Zone (JDZ) sub-block 4, where the hydrocarbons was migrated to the above reservoir rocks at 20 Ma. The oil and gas in the reservoir rocks of the JDZ sub-block 4 are accumulated into the prospects with closure structures that has already been formed at the nearby areas. Another generation of hydrocarbon occurs from the source rock at the eastern border area of JDZ sub-block 1 and 2, where the expulsion of the hydrocarbons occurs at 10 Ma from the source rock into the above reservoir rocks, in which the accumulation also is expected. The generation, migration and accumulation were retarded at the eastern area of the JDZ sub-block 1 and 2, compared with the area of the western JDZ sub-block 4. Based on the modeling results, it is estimated that gases migrated laterally and vertically in long distance whereas oil migrated laterally in shorter distance than gases. A substantial amount of hydrocarbon could have seeped out of the reservoir formations to the surface since the migration of oil and gas actively occurred in Miocene time before the formation of seals. However, the modeling shows that the hydrocarbon could be accumulated smoothly into the closed structures that can be formed locally by alternation of sand and shale beds.