• 한국환경농학회지
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• 제30권2호
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• pp.99-104
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• 2011

BACKGROUND: Application of urea may increase $CO_2$ emission from soils due both to $CO_2$ generation from urea hydrolysis and fertilizer-induced decomposition of soil organic carbon (SOC). The objective of this study was to investigate the effects of increasing urea application on $CO_2$ emission from soil and mineralization kinetics of indigenous SOC. METHODS AND RESULTS: Emission of $CO_2$ from a soil amended with four different rates (0, 175, 350, and 700 mg N/kg soil) of urea was investigated in a laboratory incubation experiment for 110 days. Cumulative $CO_2$ emission ($C_{cum}$) was linearly increased with urea application rate due primarily to the contribution of urea-C through hydrolysis to total $CO_2$ emission. First-order kinetics parameters ($C_0$, mineralizable SOC pool size; k, mineralization rate) became greater with increasing urea application rate; $C_0$ increased from 665.1 to 780.3 mg C/kg and k from 0.024 to 0.069 $day^{-1}$, determinately showing fertilizer-induced SOC mineralization. The relationship of $C_0$ (non-linear) and k (linear) with urea-N application rate revealed different responses of $C_0$ and k to increasing rate of fertilizer N. CONCLUSION(s): The relationship of mineralizable SOC pool size and mineralization rate with urea-N application rate suggested that increasing N fertilization may accelerate decomposition of readily decomposable SOC; however, it may not always stimulate decomposition of non-readily decomposable SOC that is protected from microbial decomposition.

• 한국토양비료학회지
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• 제44권4호
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• pp.527-533
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• 2011

Decomposition of compost applied to soils is affected basically by its biological stability; but, many other chemical properties of the compost may also influence compost organic-C mineralization. This study was conducted to investigate the principal substrate quality factors of composts that determine C mineralization of compost with similar stability degree (SD). Three composts samples with similar SD but different chemical properties such as pH, C/N, $K_2SO_4$-extractable C, and molar ratio of $NH_4^+$ to $NO_3^-$ were mixed with an acid loamy soil and $CO_2$ emission was monitored during the laboratory incubation for 100 days. Temporal pattern of cumulative compost organic-C mineralization expressed as % of total organic C ($C_{%\;TOC}$) followed double exponential first order kinetics model and the $C_{%\;TOC}$ ranged from 4.8 to 11.8% at the end of incubation. The pattern of C%TOC among the composts was not coincident with the SD pattern (40.1 to 58.6%) of the composts; e.g. compost with the lowest SD resulted in the least $C_{%\;TOC}$ and vice versa. This result indicates that SD of compost can not serve as a concrete predictor of compost mineralization as SD is subject not only to maturity of compost but also to characteristics of co-composting materials such as rice hull (low SD) and sawdust (high SD). Meanwhile, such pattern of $C_{%\;TOC}$ collaborated with pH, C/N, $K_2SO_4$-extractable C, and molar ratio of $NH_4^+$ to $NO_3^-$ of the composts that are regarded as chemical indices of the progress of composting. Therefore, for better prediction of compost mineralization in soils, it is necessary to consider both SD and other chemical indices (pH, C/N, and molar ratio of $NH_4^+$ to $NO_3^-$).