• Title/Summary/Keyword: Mineral processing

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Synthesis of Ag-Cu Composite Powders for Electronic Materials by Electroless Plating Method (무전해 도금법을 이용한 전자소재용 은-구리 복합분말의 제조)

  • Yoon, C.H.;Ahn, J.G.;Kim, D.J.;Sohn, J.S.;Park, J.S.;Ahn, Y.G.
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.221-226
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    • 2008
  • Silver coated copper composite powders were prepared by electroless plating method by controlling the activation and deposition process variables such as feeding rate of silver ions solution, concentration of reductant and molar ratio of activation solution $(NH_4OH/(NH_4)_2SO_4)$ at room temperature. The characteristics of the product were verified by using a scanning electron microscopy (SEM), X-ray diffraction (XRD) and atomic absorption (A.A.). It is noted that completely cleansing the copper oxide layers and protecting the copper particles surface from hydrolysis were important to obtain high quality Ag-Cu composite powders. The optimum conditions of Ag-Cu composite powder synthesis were $NH_4OH/(NH_4)_2SO_4$ molar ratio 4, concentration of reductant 15g/l and feeding rate of silver ions solution 2 ml/min.

Experimental study on the mechanical property of coal and its application

  • Jiang, Ting T.;Zhang, Jian H.;Huang, Gang;Song, Shao X.;Wu, Hao
    • Geomechanics and Engineering
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    • v.14 no.1
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    • pp.9-17
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    • 2018
  • Brazilian splitting tests, uniaxial compression tests and triaxial compression tests are carried out on the coal samples cored from Shanxi group $II_1$ coal seam of Jiaozuo coal mine, Henan province, China, to obtain their property parameters. Considering the bedding has notable effect on the property parameter of coal, the samples with different bedding angles are prepared. The effects of bedding on the anisotropic characteristics of the coal seam are investigated. A geological geomechanical model is built based on the geology characteristics of the Jiaozuo coal mine target reservoir to study the effects of bedding on the fracture propagations during hydraulic fracturing. The effects of injection pressure, well completion method, in-situ stress difference coefficient, and fracturing fluid displacement on the fracture propagations are investigated. Results show bedding has notable effects on the property parameters of coal, which is the key factor affecting the anisotropy of coal. The hydraulic cracks trends to bifurcate and swerve at the bedding due to its low strength. Induced fractures are produced easily at the locations around the bedding. The bedding is beneficial to form a complicated fracture network. Experimental and numerical simulations can help to understand the effects of bedding on hydraulic fracturing in coalbed methane reservoirs.

Taguchi's Robust Design Method for Optimization of Grinding Condition by Hammer Mill (다구치 방법을 활용한 해머밀 분쇄공정의 최적화 연구)

  • Choe, Hong-Il;Kim, Byoung-Gon;Park, Chong-Lyuck;Jeong, Soo-Bok;Jeon, Ho-Seok;Jang, Hee-Dong
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.3
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    • pp.219-225
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    • 2010
  • Optimal grinding condition was examined by changing only the size of screen opening with fixing other factors to produce coal fines of particle sizes required for circulating fluidized bed gasifier. At least 85 wt% of the coal particles should fall into the size range of 0.045~1.0 mm for efficient gasification. In this study, hammer mill was used to grind Chinese low rank lignite coal following grinding condition designed by Taguchi method. The analysis of signal to noise ratio showed that optimum grinding condition for the gasifier was 3 mm in primary screen size and 1.3 mm in secondary screen size on the 95% level of significance.

Precipitation of Cu as the sulphide from Sulphate solution containing Cu, Ni and Co (구리, 니켈, 코발트 혼합용액으로부터 침전법에 의한 구리의 분리)

  • Park Kyung-Ho;Jung Sun-Hee;Park Jin-Tae;Nam Chul-Woo;Kim Hong-In
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.16-20
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    • 2005
  • The selective sulphide precipitation of copper from sulphate solution containing nickel and cobalt was studied with adding $Na_{2}S$ solution. Precipitation efficiency of copper increased with raising pH of solution and increasing the amount of $Na_{2}S$ added and lowing its concentration. The increase in reaction time and temperature also improved the precipitation of copper. However, attempts to selectively precipitate copper met with limited success because of co-precipitation of nickel and cobalt. With adding $20\%$ $Na_{2}S$, 3 times equivalent of Cu, at pH 1.0 of solution, $25^{\circ}C$ and 30 minutes of reaction time, precipitation efficiencies of copper, nickel and cobalt were $94.1\%$, $4.3\%$ and $4.5\%$ respectively.

Development of Triboelectrostatic Separation Technique for Material Separation of EVA & PET Mixture Plastic Wastes (EVA와 PET 혼합(混合) 폐플라스틱의 재질분리(材質分離)를 위한 마찰하전형(摩擦荷電形) 정전선별(靜電選別) 기술개발(技術開發))

  • Jeon, Ho-Seok;Park, Chul-Hyun;Baek, Sang-Ho;Kim, Byoung-Gon;Kim, Hyung-Seok
    • Resources Recycling
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    • v.18 no.1
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    • pp.13-21
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    • 2009
  • A research on material separation of EVA and PET mixture plastic waste using a triboelectrostatic separator has been carried out. It was found that PP was the best charging material to give the highest charge on the surface of EVA and PET mixture plastics with an opposite polarity. Therefore, a charger of pipe line type using PP material was manufactured for separation of EVA and PET mixture plastic waste. At optimum test conditions that used PP cyclone charger developed in this study, we could separate out PET with a glade of 98.7% and a recovery of 89.7%.

Precious Metals Extraction Processing in Chloride Media by Using Ionic Liquids as Novel Extractant Systems

  • Kumar, Jyothi Rajesh;Choi, In-Hyeok;Lee, Jin-Young
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.503-509
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    • 2017
  • The present experimental study proposed two ionic liquids (ILs) namely [Aliquat 336] [$HSO_4$] (prepared and characterized at our laboratory) and Cyphos 101 IL (supplied by Cytec Company) dissolved in two different diluents such as DCM (di-chloro-methane) and toluene applied for PMs extraction. The first IL [Aliquat 336] [$HSO_4$] prepared and confirmed the formation of final product by using FT-IR and TGA studies. The primary experiment in solvent extraction processing is kinetic effect; 0 to 30 time varied for PMs by using two ILs and confirmed the optimized extraction equilibrium time. This study was conducted for PMs (Pt, Rh and Cu) extraction and separation from each other by using proposed ILs. This is the primary study of the utilizing green solvents such as ILs as an extractant system for Pt, Rh and Cu extraction and possible separation.

The characteristics of mineral hydrate insulation material using activated cement prepared from pilot plant activation system

  • Seo, Sung Kwan;Chu, Yong Sik;Kim, Tae Yeon;Kim, Yoo
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.428-433
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    • 2018
  • In this study, using the pilot plant activation system, the activated cement has been manufactured and then applied to the manufacturing process of mineral hydrate insulating material. The fineness of the activated cement is controlled at $5,000cm^2/g$ and $7,500cm^2/g$ and the features of mineral hydrate insulating material, using OPC and the activated cement for each degree of fineness, has been analyzed. As the result of analyzing the crystal habit of the manufactured mineral hydrate insulting material, it is analyzed that the main crystal phase of specimen is tobermorite and some quartz peak has been detected. As the degree of fineness of the activated cement increases, the height of bubble of slurry increases as well, whereas the tendency for the density character to decrease has been detected. Along with it, as the density character decreases, the compression strength has decreases, whereas the tendency for the thermal characteristic to increases has been detected. The main features of mineral hydrate insulating material, using the activated cement with the fineness of $7,500cm^2/g$, the compression strength of 0.36 MPa, and the thermal conductivity of $0.044W/m{\cdot}K$, presents the excellent features as insulation.

Technical and Financial evaluation for mineral project (광물자원 프로젝트의 기술성 및 경제성 평가 기법)

  • Cho, Seong-Jun
    • 한국지구물리탐사학회:학술대회논문집
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    • 2009.05a
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    • pp.101-118
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    • 2009
  • In order to invest in overseas mineral projects, it is necessary to have a ability of technical and financial evaluation. Reserve estimation is the most important for mineral appraisal. Geostatistical evaluation of tonnage and grade promises more accurate reserve estimation than traditional methods such as polygon, inverse distance method and so on even if it has some uncertainty. Selection of a mining method and a mineral processing is also important because capex and opcosts of a mineral project is due to the selection. Mineral project is usually evaluated financially using NPV and IRR which are calculated through DCF(Discount Cash Flow). Uncertainty of a mineral project is analyzed statistically using sensitivity analysis and montecarlo simulation.

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Leaching of copper using electro-generated chlorine in hydrochloric acid solution (전해생성된 염소에 의한 구리 침출 연구)

  • Kim, Eun-Young;Kim, Min-Seuk;Lee, Jae-Chun;Jung, Jin-Ki
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2006.05a
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    • pp.86-89
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    • 2006
  • 전해 생성된 염소를 이용하여 구리를 침출하는 연구를 수행하였다. 염산농도 $1molL^{-1}$, 반응온도 $25^{\circ}C$, 교반속도 400rpm 조건에서 전류밀도 $10mA/cm^{2}$의 경우 반응온도에 상관없이 구리의 침출속도가 동일하였으나 $Cl_{2}$ 생성량이 충분한 $40mA/cm^{2}$의 경우 온도가 높을수록 구리의 침출속도가 증가하였다. 침출된 구리농도가 6g/L 부근에 도달하면 염소의 공급속도에 상관없이 구리의 침출이 둔화되었다. 이는 구리-염소 착화물의 형성과 관련된 것으로 생각된다.

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Preparation of Needle like Aragonite Precipitated Calcium Carbonate (PCC) from Dolomite by Carbonation Method

  • Ramakrishna, Chilakala;Thenepalli, Thriveni;Huh, Jae-Hoon;Ahn, Ji Whan
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.7-12
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    • 2016
  • In this paper, we have developed a simple, new and economical carbonation method to synthesize a pure form of aragonite needles using dolomite raw materials. The obtained aragonite Precipitated Calcium Carbonate (PCC) was characterized by XRD and SEM, for the measurement of morphology, particle size, and aspect ratio (ratio of length to diameter of the particles). The synthesis of aragonite PCC involves two steps. At first, after calcinated dolomite fine powder was dissolved in water for hydration, the hydrated solution was mixed with aqueous solution of magnesium chloride at $80^{\circ}C$, and then $CO_2$ was bubbled into the suspension for 3 h to produce aragonite PCC. Finally, aragonite type precipitated calcium carbonate can be synthesized from natural dolomite via a simple carbonation process, yielding product with average particle size of $30-40{\mu}m$.