• 제목/요약/키워드: Mineral Oil

검색결과 531건 처리시간 0.029초

Activation and immobilization of phenol-degrading bacteria on oil palm residues for enhancing phenols degradation in treated palm oil mill effluent

  • Tosu, Panida;Luepromchai, Ekawan;Suttinun, Oramas
    • Environmental Engineering Research
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    • 제20권2호
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    • pp.141-148
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    • 2015
  • The presence of phenols in treated palm oil mill effluent (POME) is an environmental concern due to their phytotoxicity and antimicrobial activity. In this study, phenol-degrading bacteria, Methylobacterium sp. NP3 and Acinetobacter sp. PK1 were immobilized on oil palm empty fruit bunches (EFBs) for removal of phenols in the treated POME. The bacterial exopolysaccharides (EPS) were responsible for cell adhesion to the EFBs during the immobilization process. These immobilized bacteria could effectively remove up to 5,000 mg/L phenol in a carbon free mineral medium (CFMM) with a greater degradation efficiency and rate than that with suspended bacteria. To increase the efficiency of the immobilized bacteria, three approaches, namely activation, acclimation, and combined activation and acclimation were applied. The most convenient and efficient strategy was found when the immobilized bacteria were activated in a CFMM containing phenol for 24 h before biotreatment of the treated POME. These activated immobilized bacteria were able to remove about 63.4% of 33 mg/L phenols in the treated POME, while non-activated and/or acclimated immobilized bacteria could degrade only 35.0%. The activated immobilized bacteria could be effectively reused for at least ten application cycles and stored for 4 weeks at $4^{\circ}C$ with the similar activities. In addition, the utilization of the abundant EFBs gives value-added to the palm oil mill wastes and is environmentally friendly thus making it is attractive for practical application.

마이크로핀관 증발기내 전열 성능에 미치는 냉동기유의 영향 (Effect of refrigeration lubricants on the heat transfer performance in the microfin tube evaporator)

  • 조금남;태상진
    • 설비공학논문집
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    • 제11권1호
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    • pp.61-72
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    • 1999
  • The present study experimentally investigated the effect of refrigeration lubricant on the heat transfer performance in the straight sections and U-bend of a microfin tube evaporator by using R-22/mineral oil and R-407C/POE oil. The apparatus consisted of test section with U-bend, preheater, condenser, oil injection and sampling devices, magnetic pump, mass flow meter etc. The experimental parameters were oil concentration of 0 to 5 wt%, inlet quality of 0.1 to 0.5, mass flux of 219 and $400kg/m^2s$ and heat flux of 10 and $20kW/m^2$. The effects of parameters on the heat transfer coefficients were large in the order of inlet quality, mass flux and heat flux as oil concentration got increased. As oil concentration was increased, heat transfer coefficients were continuously decreased for R-22 and increased by 3% up to the concentration of 1% and then decreased for R-407C under the condition of large inlet quality, and small mass flux and heat flux. But, the heat transfer coefficients were increased up to the concentration of 3% and then decreased for both R-22 and R-407C refrigerants under the opposite conditions. The variation of enhancement factors for R-407C was under 50% of that for R-22 and the variation with respect to the positions in the test section was small. The pressure drops were increased for both R-22 and R-407C refrigerants as oil concentration was increased. The pressure drops for R-407C were smaller by the maximum of 18% than those for R-22.

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다양한 파쇄 유체별 파쇄압력, 투과도 증진 및 균열전파에 관한 실험적 연구 (Experimental Study on Fracture Pressure, Permeability Enhancement and Fracture Propagation using Different Fracture Fluids)

  • 최준형;이현석;김도영;남정현;이대성
    • 터널과지하공간
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    • 제31권1호
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    • pp.41-51
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    • 2021
  • 치밀 저류층의 투과도 증진을 위해 개발된 수압파쇄 기술은 셰일가스와 같은 비전통자원과 심부지열 개발에 필수적인 기술 중 하나이다. 파쇄형태가 단순하고 파쇄효율이 좋지 않은 수압파쇄를 개선하기 위해 다양한 파쇄유체를 이용한 실험적 연구가 진행되었다. 물, N2, CO2 가스를 파쇄유체로 사용하여 치밀 암석에 대한 파쇄형태와 효율성을 분석하였다. 파쇄유체로 물을 일정 주입속도로 주입한 경우 순간적으로 압력이 상승하여 파쇄가 발생하였으나, 파쇄유체로 가스를 주입한 경우 서서히 압력이 증가되면서 물보다 낮은 파쇄압력을 보였다. 3D 단층촬영 기법을 이용하여 물과 가스 주입으로 생성된 균열을 관찰한 결과는 기존 공극부피 대비 파쇄 자극부피가 각각 5.71%(물), 12.72%(N2), 43.82%(CO2) 증가되었다. 또한 파쇄유체의 파쇄 효율성을 검정하기 위한 파쇄 전후 투과도 변화 실험에서는 가스 파쇄에 의해 증가되는 투과도 증가 값이 물을 이용한 파쇄보다 훨씬 높게 측정되었다. 파쇄 이후 인공균열의 생성과 주변응력에 의해 다시 균열이 닫히는 현상을 고려하여 생성된 인공균열에 구속압을 단계별로 증가시켜 투과도 변화를 측정하였다. 구속압이 2MPa에서 10MPa로 증가시켰을 경우 초기 투과도 대비 각각 89%(N2), 50%(CO2) 감소하였다. 본 연구는 가스파쇄기술이 수압파쇄보다 투과도 증진 효과가 크고 이후 주변 응력에 의한 투과도 감소가 적은 것으로 나타났다.

Ni/sand를 이용한 폴리프로필렌 촉매 열분해 연구 (A Study on Catalytic Pyrolysis of Polypropylene with Ni/sand)

  • 김수현;이루세;손정민
    • 청정기술
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    • 제27권3호
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    • pp.232-239
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    • 2021
  • 본 연구는 '열매체 및 가스 순환형 열분해 시스템'이라는 새로운 시스템 개발을 위해 열분해 실험을 수행하기 전에 공정 모사를 위한 기본 데이터를 얻기 위하여 수행되었다. 기초 열분해 실험에서는 폐플라스틱 대신 폴리프로필렌(PP)을 모델 물질로 선택하였고, '열매체 및 가스 순환형 열분해 시스템'에서 열전달 매체로 활용되는 유동사(이하 sand로 표기)를 사용하였다. Ni은 촉매 열분해를 촉진하기 위해 모래에 활성 촉매로 담지하였다. 열중량분석기(thermogravimetric analyzer, TGA)를 이용하여 PP의 기본 물성을 분석하고, N2 분위기 600 ℃에서 열분해하여 액상 오일을 생산하였다. 촉매 열분해 반응을 통해 생성된 액상 오일은 GC/MS를 이용하여 탄소 수 분포를 분석하였다. 이번 연구에서는 열분해 공간 속도와 촉매량의 변화가 열분해 후 생성되는 액상 오일 수율과 액체 연료의 탄소수 분포에 미치는 영향을 조사하였다. Ni/sand를 이용하면 열분해 오일 수율은 공간속도 30,000 h-1에서 10 wt% Ni/sand 하나의 조건을 제외하고 오일 수율이 증가하였고, C6 ~ C12사이의 탄화수소의 비율은 증가하였다. 공간속도가 증가하면 더 높은 열분해 오일 수율을 얻었으나, C6 ~ C12사이의 탄화수소의 비율은 감소하였다. 1 wt% Ni/sand를 이용한 경우, 10 wt% Ni/sand를 사용할 때 보다 액상 오일 수율은 더 높았다. 결론적으로 공간속도 10,000 h-1에서 1 wt% Ni/sand를 이용하였을 경우 오일 수율은 60.99 wt%이고, 42.06 area%의 가장 높은 C6 ~ C12 탄화수소의 비율이 나타났다.

석탄가스화를 위한 중국산 저급 석탄의 광물학적 및 건조 특성 (Mineralogical and Drying Characteristics of Chinese Low Rank Coal for Coal Gasification)

  • 박종력;김병곤;전호석;김상배;박석환;이재령
    • 한국광물학회지
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    • 제23권3호
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    • pp.199-209
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    • 2010
  • 석탄가스화는 청정석탄이용기술의 한 분야로 최근 국제 유가의 급격한 변동과 더불어 매우 각광을 받고 있는 기술이다. 본 연구에서는 중국 내몽고 지역의 저급석탄을 출발물질로 가스화를 위한 광학적 특성, X선 분광특성, X선 회절특성, 광물학적 특성, 건조특성 등을 분석하였다. 분석결과 석탄의 등급은 slagging성과 fouling성이 매우 낮으며 착화온도가 $250^{\circ}C$ 정도인 brown coal인 것으로 조사되었고, 석영, 능철석, 점토광물 등이 주요 불순물로 혼재하는 것을 알 수 있었다. 또한 초기 수분이 28%로 매우 높기 때문에 이를 쉽게 건조하기 위한 방법으로 열풍건조와 마이크로웨이브 건조기술을 적용하여 비교한 결과, 마이크로웨이브를 이용한 건조가 좀 더 효과적인 것을 알 수 있었다.

경계윤활 영역에서 다중벽 탄소나노튜브의 윤활 특성 (Tribological Performance of Multi-Walled Carbon Nanotubes in Mineral Oils under Boundary Lubricated Sliding)

  • 백승현;이규선;윤도경;이영제
    • Tribology and Lubricants
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    • 제21권6호
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    • pp.263-267
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    • 2005
  • The tribological performance of multi-walled carbon nanotubes (MWNT) in mineral oils is investigated at ambient temperature. The frictional forces, wear amounts and cycles to scuffing of the oils with nanotubes and without those were measured using the ball-on-disk tester. It was found that there were little differences in the frictional forces and wear amounts of two oils. However, the scuffing times of oils with nanotubes were much longer than those of oils without nanotubes in sliding tests. The nanotubes were very effective on maintaining the oil gap and protecting the surfaces in boundary lubricated sliding.

진단용 X 선관 절연유의 전기적 특성 (Electrical Properties of Insulating Oils for Diagnostic X-ray Tube)

  • 김건중;이인성;백금문;김두호;김왕곤;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.597-600
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    • 2001
  • In order to investigate the electrical properties of X-ray tube oils for insulating and cooling, the breakdown characteristics in temperature range of $20\sim100[^{\circ}C]$, that of AC breakdown in 0.5~2.5[mm] of gap length, we are made researches. The classification for the physical properties of oil for X-ray tube by FTIR and H-NMR experiments was confirmed to type of mineral oils. As for the dependance of breakdown characteristics due to electrode gap length, breakdown voltage was found nearly uniform by impurity effect according to the increase of gap. As a result the characteristics for AC breakdown, the dielectric strength was increased to $90[^{\circ}C]$ but decreased over $90[^{\circ}C]$ in the temperature range.

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진단용 X 선관 절연유의 전기적 특성 (Electrical Properties of Insulating Oils for Diagnostic X-ray Tube)

  • 김건중;이인성;백금문;김두호;김왕곤;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.597-600
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    • 2001
  • In order to investigate the electrical properties of X-ray tube oils for insulating and cooling, the breakdown characteristics in temperature range of 20∼100[$^{\circ}C$], that of AC breakdown in 0.5∼2.5(mm) of gap length, we are made researches. The classification for the physical properties of oil for X-ray tube by FTIR and $^1$H-NMR experiments was confirmed to type of mineral oils. As for the dependance of breakdown characteristics due to electrode gap length, breakdown voltage was found nearly uniform by impurity effect according to the increase of gap. As a result the characteristics for AC breakdown, the dielectric strength was increased to 90[$^{\circ}C$] but decreased over 90[$^{\circ}C$] in the temperature range.

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국내산과 국외산 참깨의 이화학적 특성 비교 (Physicochemical Properties of Introduced and Domestic Sesame Seeds)

  • 강명화;류수노;방진기;강철환;김동휘;이봉호
    • 한국식품영양과학회지
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    • 제29권2호
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    • pp.188-192
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    • 2000
  • To obtain basic information for the quality evaluation, the introduced or domestic sesame seeds were investigated to measure proximate components (crude protein, ash, mineral and oil) and isolated by preparative HPLC system for lignan contents. Although crude protein contents were the highest in Sudan sesame seeds, lipid, ash and mineral contents were not significantly(p<0.05) different between introduced and domestric sesame seeds. Unsaturated fatty acids such as oleic and linoleic acids were the highest in the domestic sesame seeds. The Mg content of domestic sesame seeds also was larger than that of introduced sesame seeds. A Ca content of domestic sesame seeds, however, was significantly (p<0.05) lower than that of China. Lignan contents, the most important component known as antioxidant, were significantly (p<0.05) higher in domestic sesame seeds than other sesame seeds tested. Our findings suggest that domestic sesame seed has the best quality in terms of the functional components.

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호주 Olympic Dam 사례를 바탕으로 한 MT 기반 심부 지하 광물자원 탐사의 국내 적용성 (Domestic applicability of MT-based deep underground resource exploration based on the Australia Olympic Dam case)

  • 정동호;류경호;오석훈
    • 산업기술연구
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    • 제41권1호
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    • pp.21-24
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    • 2021
  • In this study, the development and production of electric vehicles and hydrogen vehicles are presented as a method for realizing carbon-neutral. Accordingly, the demand and need for development of underground metal mineral resources such as copper and nickel has increased. The research was carried out using MT survey, which is very useful for deep exploration such as mineral resources and oil exploration because of it's low cost and explorable depth. In Korea, there are very few cases of MT exploration in terms of mineral development, so the study was conducted based on the MT exploration conducted previously in AusLAMP, Australia. Through comparative analysis of the MT exploration data conducted to identify the ore body in the deep area of the Olympic Dam in Australia, with the data directly calculated in 2D inversion, it was confirmed that it can have a positive effect on the possibility of resource development and carbon neutrality using MT exploration in Korea.