• Title/Summary/Keyword: Mineral Cycles

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BIOGEOCHEMICAL ACTIVITIES OF MICROORGANISMS IN MINERAL TRANSFORMATIONS: CONSEQUENCES FOR METAL AND NUTRIENT MOBILITY

  • Gadd, Geoffrey M.
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 2002.10a
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    • pp.39-61
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    • 2002
  • Bacteria and fungi are fundamental biotic components of natural biogeochemical cycles for metals and metalloids and play important roles in dissolution, precipitation, oxidation and reduction processes. Some processes catalyzed by microorganisms also have important applications in environmental biotechnology in the areas of ore leaching and bioremediation.

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Biogeochemical Activities of Microorganisms in Mineral Transformations: Consequences for Metal and Nutrient Mobility

  • Gadd, Geoffrey-M.;Burford, Euan-P.;Fomina, Marina
    • Journal of Microbiology and Biotechnology
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    • v.13 no.3
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    • pp.323-331
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    • 2003
  • Bacteria and fungi are fundamental biotic components of natural biogeochemical cycles for metals and metalloids, and play important roles in dissolution, precipitation, oxidation and reduction processes. Some processes catalyzed by microorganisms also have important applications in environmental biotechnology in the areas of ore leaching and bioremediation.

CLSM [Confocal Laser Scanning Microscope] Observation of the Surface Roughness of Pressurized Rock Samples During Freeze/Thaw Cycling

  • Kim, Hye-jin;Choi, Junghae;Chae, Byung-gon;Kim, Gyo-won
    • The Journal of Engineering Geology
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    • v.25 no.2
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    • pp.165-178
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    • 2015
  • Physical and chemical weathering degrades rock, affecting its structural properties and thus the stability of stone buildings or other structures. Confocal laser scan microscopy (CLSM) is used here to observe temporal changes in the surface roughness of rock samples under simulated accelerated weathering. Samples were pressurized to 50, 55, or 70 MPa using a pressure frame, and subjected to freeze/thaw cycling controlled by a thermostat. The temperature was cycled from -20℃ to 40℃ and back. After each 20 cycles, CLSM was used to assess the change in surface roughness, and roughness factors were calculated to quantify the progression of the surface condition over time. Variations in cross-section line-roughness parameters and surface-roughness parameters were analyzed for specific parts of the sample surfaces at 5× and 50× magnification. The result reveals that the highest and lowest values of the roughness factors are changed according to elapsed time. Freezing/thawing at high pressure caused larger changes in the roughness factor than at low pressure.

Determining Characteristics of Groundwater Inflow to the Stream in an Urban Area using Hydrogeochemical Tracers (222Rn and Major Dissolved Ions) and Microbial Community Analysis (수리지화학적 추적자(222Rn, 주요용존이온)와 미생물 군집 분석을 통한 도심 지역 하천에서의 지하수 유출 특성 평가)

  • Oh, Yong Hwa;Kim, Dong-Hun;Lee, Soo-Hyoung;Moon, Hee Sun;Cho, Soo Young
    • Journal of Soil and Groundwater Environment
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    • v.25 no.2
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    • pp.16-23
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    • 2020
  • In this work, 222Rn activity, major dissolved ions, and microbial community in ground- and surface waters were investigated to characterize groundwater inflow to the stream located in an urban area, Daejeon, Korea. The measured 222Rn activities in groundwater and stream water ranged from 136 to 231 Bq L-1 and 0.3 to 48.8 Bq L-1, respectively. The spatial distributions of 222Rn activity in the stream strongly suggested groundwater inflow to the stream. The change of geochemical composition of the stream water indicated the effect of groundwater discharge became more pronounced as the stream flows downstream. Furthermore, microbial community composition of the stream water had good similarity to that of groundwater, which is another evidence of groundwater discharge. Although groundwater inflow could not be estimated quantitatively in this study, the results can provide useful information to understand interactions between groundwater and surface water, and determine hydrological processes governing groundwater recharge and hydrogeological cycles of dissolved substances such as nutrients and trace metals.

Preparation of Silicon-Carbon-Graphene Composites and their Application to Lithium Ion Secondary Battery (실리콘-탄소-그래핀 복합체 제조 및 리튬이온 이차전지 응용)

  • Kim, SunKyung;Kim, ChanMi;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.15 no.4
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    • pp.127-137
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    • 2019
  • Recently, high electrochemical performance anode materials for lithium ion secondary batteries are of interest. Here, we present silicon-carbon-graphene (Si-C-GR) composites for high performance anode materials of lithium ion secondary battery (LIB). Aerosol process and heat-treatment were employed to prepare the Si-C-GR composites using a colloidal mixture of silicon, glucose, and graphene oxide precursor. The effects of the size of the silicon particles in Si-C-GR composites on the material properties including the morphology and crystal structure were investigated. Silicon particles ranged from 50 nm to 1 ㎛ in average diameter were employed while concentration of silicon, graphene oxide and glucose was fixed in the aerosol precursor. Morphology of as-fabricated Si-C-GR composites was generally the shape of a crumpled paper ball and the Si particles were well wrapped in carbon and graphene. The size range of composites was about from 2.2 to 2.9 ㎛. The composites including silicon particles larger than 200 nm in size exhibited higher performance as LIB anodes such as capacity and coulombic efficiency than silicon particles less than 100 nm, which were about 1500 mAh/g at 100 cycles in capacity and 99% in coulombic efficiency, respectively.

Biomechanical analysis of pullout strength of the pedicle screws in relation to change bone mineral density (반복 하중 후 골밀도 감소에 따른 척추경 나사못의 고정력(Pullout Strength)감소 형태 분석)

  • Jung, D.Y.;Lee, S.J.;Kim, D.S.;Shin, J.W.;Kim, W.J.;Suk, S.I.
    • Proceedings of the KOSOMBE Conference
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    • v.1998 no.11
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    • pp.155-156
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    • 1998
  • Screw loosening and subsequent pullout can be attributed to the reduction in bone mineral density in the vertebrae manifested by osteoporosis in which the decrease in fixation strength between the cancellous bone and screw threads are accelerated by repeated loads exerted by patients own weight and activities following the surgery. In this study, the change in pullout strength of the pedicle screws was investigated before and after repeated loads were imparted. For this purpose. Diapason pedicle screws $(6.7\times40mm)$ were inserted onto fresh porcine spine specimens (T1-L5) after bone mineral density was measured using a DEXA. With an MTS, an axial load was applied at a loading rate of 0.33mm/sec until failure to measure the maximum pullout strength. Flexion moment of 7.5N-m was then imparted at 0.5Hz for 2000 cycles. It was found that the maximum pullout strength was exponentially related to BMD regardless of load types ($107.71\;\times\;\exp^{(1.43{\times}BMD)}r^2=0.93$, P<0.0001 without repeated load; ($107.71\;\times\;\exp^{(2.19{\times}BMD)}r^2=0.78$, P<0.0001 with repeated load). The results suggest that the reduction in pullout strength for pedicle screws is far more prominent in osteoporotic spine than in normal spine especially as number of repeated load was increased. More importantly, it was demonstrated that the level of bone mineral density and the activity level of the patient should be evaluated in more detail for successful implementation of pedicle screw systems in spinal surgery.

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Evaluation on Steel Bar Corrosion Embedded in Antiwashout Underwater Concrete

  • Moon Han-Young;Shin Kook-Jae
    • Journal of the Korea Concrete Institute
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    • v.17 no.2 s.86
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    • pp.303-309
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    • 2005
  • This study aims the evaluation of the corrosion of steel bar embedded in antiwashout underwater concrete, which has rather been neglected to date. To that goal, accelerated steel bar corrosion tests have been performed on three series of steel bar-reinforced antiwashout underwater concrete specimens manufactured with different admixtures. The three series of antiwashout underwater concrete were: concrete constituted exclusively with ordinary portland cement (OPC), concrete composed of ordinary portland cement mixed with fly-ash in $20\%$ ratio (FA20), and concrete with ground granulated blast furnace slag mixed in $50\%$ ratio (BFS50). The environment of manufacture was in artificial seawater. Measurement results using half-cell potential surveyor showed that, among all the specimens, steel bar in OPC was the first one that exceeded the threshold value proposed by ASTM C 876 with a potential value below -350mv after 14 cycles. And, the corresponding corrosion current density and concentration of water soluble chloride were measured as $30{\mu}A/mm^2$ and $0.258\%$. On the other hand, for the other specimens that are FA20 and BFS50, potential values below -350mV were observed later at 18 and 20 cycles, respectively. Results confirmed the hypothesis that mineral admixtures may be more effective on delay the development of steel bar corrosion in antiwashout underwater concrete.

The Energy Flow and Mineral Cycles in a Zoysia japonica and a Miscanthus sinensis Ecosystem on Mt. Kwanak 11. The Cycles of Al (관악산의 잔디와 억새 생태계에 있어서 에너지 흐름과 무기물의 순환 11.알루미늄의 순환)

  • 심규철;장남기
    • Asian Journal of Turfgrass Science
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    • v.11 no.4
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    • pp.303-309
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    • 1997
  • The investigation was cycle of aluminum of surface soil elements in dynamic grassland ecosystems at a steady state in a Zoysia japonica and a Miscanthus sinensis ecosystem in Mt. Kwanak, Korea. Average amounts of total storage for aluminum in Z japonica and M. sinensis grasslands were 8,426mg /$m^2$ and 7,849mg /$m^2$ respectively. Decay constants estimated on the base of experimental and mathematical model, were 0.04 in Z japonica grassland, and 0.08 in M. sinensis grassland. Half time to decay aluminum of litter soils were 17.33 years in Z japonica grass-land, and 8.66 years in Al. sinensis grassland. 95% decay times in Z japonica, and in M. sinensis grassland were 75.0 years and 35.0 years respectively. Needed times to lose almost all of elements in Z japonica and M. sinensis grassland were 125.0 years, and 62.50 years respectively. The metals were losed more rapidly in M. sinensis than in Z japonica grassland. The cycle of aluminum was investigated to be related with soil acidity. Key words: Cycle of aluminum, Zoysia japonica. Miscanthus sinensis, Mt. Kwanak, Decay constants, Soil acidity.

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Life Prediction of Hydraulic Concrete Based on Grey Residual Markov Model

  • Gong, Li;Gong, Xuelei;Liang, Ying;Zhang, Bingzong;Yang, Yiqun
    • Journal of Information Processing Systems
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    • v.18 no.4
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    • pp.457-469
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    • 2022
  • Hydraulic concrete buildings in the northwest of China are often subject to the combined effects of low-temperature frost damage, during drying and wetting cycles, and salt erosion, so the study of concrete deterioration prediction is of major importance. The prediction model of the relative dynamic elastic modulus (RDEM) of four different kinds of modified concrete under the special environment in the northwest of China was established using Grey residual Markov theory. Based on the available test data, modified values of the dynamic elastic modulus were obtained based on the Grey GM(1,1) model and the residual GM(1,1) model, combined with the Markov sign correction, and the dynamic elastic modulus of concrete was predicted. The computational analysis showed that the maximum relative error of the corrected dynamic elastic modulus was significantly reduced, from 1.599% to 0.270% for the BS2 group. The analysis error showed that the model was more adjusted to the concrete mixed with fly ash and mineral powder, and its calculation error was significantly lower than that of the rest of the groups. The analysis of the data for each group proved that the model could predict the loss of dynamic elastic modulus of the deterioration of the concrete effectively, as well as the number of cycles when the concrete reached the damaged state.

Effect of chemical concentrations on strength and crystal size of biocemented sand

  • Choi, Sun-Gyu;Chu, Jian;Kwon, Tae-Hyuk
    • Geomechanics and Engineering
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    • v.17 no.5
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    • pp.465-473
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    • 2019
  • Biocementation due to the microbially induced calcium carbonate precipitation (MICP) process is a potential technique that can be used for soil improvement. However, the effect of biocementation may be affected by many factors, including nutrient concentration, bacterial strains, injection strategy, temperature, pH, and soil type. This study investigates mainly the effect of chemical concentration on the formation of calcium carbonate (e.g., quantity, size, and crystalline structure) and unconfined compressive strength (UCS) using different treatment time and chemical concentration in the biotreatment. Two chemical concentrations (0.5 and 1.0 M) and three different treatment times (2, 4, and 8 cycles) were studied. The effect of chemical concentrations on the treatment was also examined by making the total amount of chemicals injected to be the same, but using different times of treatment and chemical concentrations (8 cycles for 0.50 M and 4 cycles for 1.00 M). The UCS and CCC were measured and scanning electron microscopy (SEM) analysis was carried out. The SEM images revealed that the sizes of calcium carbonate crystals increased with an increase in chemical concentrations. The UCS values resulting from the treatments using low concentration were slightly greater than those from the treatments using high concentration, given the CCC to be more or less the same. This trend can be attributed to the size of the precipitated crystals, in which the cementation efficiency increases as the crystal size decreases, for a given CCC. Furthermore, in the high concentration treatment, two mineral types of calcium carbonate were precipitated, namely, calcite and amorphous calcium carbonate (ACC). As the crystal shape and morphology of ACC differ from those of calcite, the bonding provided by ACC can be weaker than that provided by calcite. As a result, the conditions of calcium carbonate were affected by test key factors and eventually, contributed to the UCS values.