• Bulletin of the Korean Chemical Society
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• 제25권11호
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• pp.1657-1660
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• 2004

Several critical geometries associated with the rearrangement of $CH_3SNO_2\;to\;CH_3SONO$ are calculated with the density functional theory (DFT) method and compared with those of the ab initio molecular orbital methods. There are two probable pathways for this rearrangement, one involving the transition state of an oxygen migration and the other through the homolytic decomposition to radicals. The reaction barrier via the transition state is about 60 kcal/mol and the decomposition energy into radicals about 35 kcal/mol, suggesting that the reaction pathway via the homolytic cleavage to radical species is energetically favorable. Since even the homolytic cleavage requires large energies, the rearrangement reaction is unlikely without the aid of catalysts.

• Journal of Korean Neurosurgical Society
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• 제54권6호
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• pp.515-517
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• 2013

Coexistence of cranial and spinal subdural hematomas is rare and only a few cases have been reported in the literature. Herein, we report a case of cranial and spinal subdural hematomas after previous head trauma. As the pathogenesis of simultaneous intracranial and spinal subdural hematoma yet remains unclear, we developed an alternative theory to those proposed in the literature for their coexistence, the migration of blood through the subdural space.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2002년도 ICCAS
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• pp.42.1-42
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• 2002

A model to predict population by sex, age and district over a long-range period is proposed based on fuzzy theories. First, a fuzzy model is described. Second, a method to estimate the social increase by sex and age in each district is proposed based on a fuzzy clustering method for dealing with long-range socioeconomic changes in population migration. By the proposed methods, it became possible to predict the population by sex, age and district over a long-range period. Third, the structure and characteristics of the three models of employment model, time distance model, and land use model constructed to predict various socioeconomic indicators, which are require...

• 통합자연과학논문집
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• 제15권4호
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• pp.171-177
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• 2022

ROS1 (c-ros oncogene) is one of the gene with mutation in NSCLC (non-small cell lung cancer). The increased expression of ROS1 is leading to the increase proliferation of cell, cell migration and survival. Crizotinib and Entrectinib are the drugs that have been approved by FDA against ROS1 protein, but recently patients started to develop resistance against Crizotinib and there is a need of new drug that could act as an effective drug against ROS1 for NSCLC. In this study, we have performed virtual screening, where compounds are taken from Zinc 15 dataset and molecular docking was performed. The top compounds were taken based upon their binding affinity and their interactions with the residues. The compounds stability and chemical reactivity was also studied through Density Functional theory and their properties. Further study of these compounds could reveal the required information of ROS1-inhibitor complex and in the discovery of potent inhibitors.

• 한국IT서비스학회지
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• 제16권1호
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• pp.99-118
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• 2017

Growing importance of online security on certification, many of the web-related security technology introduced day by day. Especially, using smart certificate (USIM) is recognized as one of the most safe and convenient method for the security of public certificate. The purpose of this study is to find the factors that affect the Intention of switching to smart certificate for the general public who use public certificate service. Based on migration theory, this study determined the relationship between pull factors, push factors and mooring factors which can affect the intention of switching to smart certificate. To empirically analyze the proposed hypothesis, the statistical analysis were conducted based on the response from 350 public certificate service users using SPSS 22.0 and Smart PLS 2.0. The results of this study can be summarized as follows. First, system quality, one of the pull factors has positive influence on perceived ease of use. On the other hand, the other pull factor, service quality has positive influence on both perceived ease of use and perceived usefulness. Second, push factors, user experience and information security awareness have positive influence on perceived ease of use only. Third, mooring factor, switching cost does not have influence on switching intention while perceived usefulness has positive influence on. The results of this research can be used for whom has interest to the switching intention of public certificate service for online security and provide the proper understanding about smart certificate service mechanism.

• Membrane and Water Treatment
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• 제6권5호
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• pp.393-409
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• 2015

Zinc and lead pollution are public environmental issues that have attracted lots of attention for a long time. Landfill leachate contains heavy metals, such as Zn(II) and Pb(II), which are usually related to the pollution of groundwater, especially in developing countries. Bentonite has been proven to be effective in enhancing the membrane property of clay, by which landfill liners can have better barrier performance towards the migration of contaminants. In this study, 5% sodium bentonite amended with locally available Fukakusa clay was utilized to evaluate the membrane behavior towards the heavy metals zinc and lead. The chemico-osmotic efficiency coefficient, ${\omega}$, was obtained through Zn(II) and Pb(II) solutions with different concentrations of 0.5, 1, 5, 10, and 50 mM. According to the results, ${\omega}$ continually decreased as the Zn(II) and Pb(II) concentrations increased, which is consistent with the Gouy-Chapman theory. Compared to normal inorganic ions, the membrane behavior towards heavy metal ions was lower. The migration of heavy metal ions was not observed based on experimental results, which can be attributed to the adsorption or ion exchange reaction. The mechanisms of the membrane performance change were discussed with the assistance of XRD patterns, free swelling results, XRF results, and SEM images.

• 대한금속재료학회지
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• 제49권12호
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• pp.977-982
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• 2011

Migration and interaction of multi-protons in a zinc-doped barium zirconate (Zn-doped $BaZrO_3$) super cell were investigated using a density functional theory. O ions in the super cell form interconnected octahedrons with Zr or Zn ions positioned in their centers and Ba ions positioned among the eight octahedrons. When one proton was added to the super cell, the energy barrier of 0.80 eV for proton transfer from the first to second nearest O ion sites from the Zn ion reached its highest value. When two protons were added to the super cell, the two protons preferred the first nearest O ions from the Zn ion. The two protons were accommodated by pushing the neighboring Zn ion further away from the center of the octahedron. Energy barriers for proton transfer from the Zn-octahedron to the neighboring Zr-octahedron were spread in the range of 0.36 ~ 1.02 eV.

• 한국정보과학회논문지:시스템및이론
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• 제35권12호
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• pp.568-575
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• 2008

서버 가상화 기술에 의한 서버 통합은 효율적인 자원 사용에 따른 비용적인 장점이 있다. 그러나 하나의 물리적 장치에 여러 개의 서버가 가상머신으로 함께 동작함으로써 더욱 복잡한 부하특성을 가지게 되었다. 따라서 이를 해결하기 위한 효율적인 자원관리 방법이 요구된다. 이러한 문제에 대한 해결방법으로 제안된 것이 가상머신 이동(live migration)[1,2]을 이용한 가상머신 동적 재배치 기법이다[3,4]. 본 논문은 가상머신 동적 재배치 알고리즘에 있어서 각 자원요소(CPU, network I/O, memory)들의 활용률을 다차원 공간상에서 분석하여 조율함으로써 서버통합의 자원 효율성을 증가시키는 방법(Server consolidation optimizing algorithm)을 제안하고 있다. 실험을 위해서 여러 대의 통합서버와 수많은 서비스를 생성하여야 하는 어려움이 있기 때문에 본 논문에서는 기업환경에서의 서버 가상화 프로젝트 경험을 바탕으로 서버의 부하변화와 유사한 패턴의 모니터링 데이타들을 정의하여 수치적인 시뮬레이션을 통해 sandpiper[3]와 SCOA 알고리즘의 부하 균형에 대한 효율성을 비교하였다.

• 한국정보과학회논문지:시스템및이론
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• 제28권11호
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• pp.581-591
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• 2001

본 논문은 이동 컴퓨팅 환경에서 다중 이동 클라이언트를 위한 원격 파일 접근 문제를 다루었다. 이러한 환경에서 사용자의 이동성은 파일 접근에 영향을 미치며 이동 호스트는 제한된 용량의 비휘발성 저장 장치를 가진다는 점에서 자원에 대한 심각한 제약이 따른다. 따라서, 통신 및 연산 부하가 파일접근 지연을 야기할 수 있다. 본 논문은 이러한 문제를 해결하기 위하여 파일 이주 기법을 이용하여 접근 지연을 줄일 수 있는 기법을 제안한다. 이 기법의 목표는 모든 이동 호스트들에게 가능하면 신속하게 요청한 파일을 전달하여 접근지연을 최소화하는데 있다. 우리는 이동 호스트의 파일 요청이 있을 때 서버가 파일 이주를 결정하는 주문형 기법을 개발하였다. 시뮬레이션을 통하여 파일 접근 빈도, 파일 크기, 이동성 등이 파일시스템 접근 지연에 미치는 영향을 실험하였다. 시뮬레이션 결과에서 제안된 이주 기법은 파일 접근 빈도가 높고 이동성이 작은 이동 호스트가 요청한 파일에 대한 접근 지연을 줄이는데 효율적이라는 것을 보였다.

• Journal of Korea Trade
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• 제26권6호
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• pp.20-40
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• 2022

Purpose - In recent times, the international trade environment has been changing rapidly, centering on the online market. In the post-COVID-19 era, small and medium-sized trading companies are facing the problem of not being properly provided with overseas market research, market trend analysis, and trade-related information. Cloud-based digital trade is being sought as an alternative to solve these problems; however, there is a lack of research on the intention to switch to digital trade among small and medium-sized trading companies. Therefore, this study empirically analyzes the intention to switch to digital trade based on the migration theory, and through this, attempts to identify each factor that affects the intention to switch to digital trade. Design/methodology - In this study, in order to identify factors influencing intention to switch to digital trade and innovation resistance of small and medium-sized trading companies, through previous research on migration theory and the PPM (Push, Pull, Mooring) model, each variable was selected for the purpose of the study. Based on this, a research model was established for the factors affecting switching to digital trade of small and medium-sized trading companies and empirically analyzed. In addition, considering the differences in the innovation propensity and maturity of information infrastructure of trading companies as the recipients of innovation, this study analyzes the moderating effect of the mooring effect and seeks ways to establish specific strategies according to the degree. Findings - As a result of empirical analysis, the pull effect was found to have the greatest influence on intention to switch to digital trade. However, the pull factor was found to have an effect on user resistance, and it was confirmed that it was a factor simultaneously inducing positive and negative consumption behaviors among users. In addition, it was found that the higher the company's innovation propensity, the higher the pull effect's influence on the intention to switch, and analysis showed that the push effect had no influence. In addition, companies with high information infrastructure maturity were expected to have a relatively high level of intention to switch compared to companies with low information infrastructure maturity, and the difference between the two groups was found not to be statistically significant. Originality/value - This study is a timely study in that it demonstrated the effect on the switching to cloud-based digital trade for small and medium-sized trading companies and that the cloud system related to digital trade is in full swing. There are academic implications in that it revealed that the pull effect is an important factor in the intention to switch to cloud service. Practical implications were presented in that small and medium-sized trading companies suggested ways to increase the value of the cloud system for switching to digital trade and a way to increase the switching ratio by minimizing the mooring effect. In addition, the study argues that active institutional support from the government is needed to activate cloud service.