• Journal of the Korea Concrete Institute
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• v.14 no.1
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• pp.118-125
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• 2002

Hydration is the main reason for the growth of the material properties. An exact parameter to control the chemical and physical process is not the time, but the degree of hydration. Therefore, it is reasonable that development of all material properties and the formation of microstructure should be formulated in terms of degree of hydration. Mathematical formulation of degree of hydration is based on combination of reaction rate functions. The effect of moisture conditions as well as temperature on the rate of reaction is considered in the degree of hydration model. This effect is subdivided into two contributions: water shortage and water distribution. The former is associated with the effect of W/C ratio on the progress of hydration. The water needed for progress of hydration do not exist and there is not enough space for the reaction products to form. The tatter is associated with the effect of free capillary water distribution in the pore system. Physically absorption layer does not contribute to progress of hydration and only free water is available for further hydration. In this study, the effects of chemical composition of cement, W/C ratio, temperature, and moisture conditions on the degree of hydration are considered. Parameters that can be used to indicate or approximate the real degree of hydration are liberated heat of hydration, amount of chemically bound water, and chemical shrinkage, etc. Thus, the degree of heat liberation and adiabatic temperature rise could be determined by prediction of degree of hydration.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.8
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• pp.531-536
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• 2017

Nano/micro technology is currently applied to improve solid surface wettability, with recent research studies indicating that nanostructures can improve surface wettability in the hydrophilic direction, and liquid spreading (propagation) is generated by capillary wicking. The majority of the existing research involves qualitative analysis of the spreading phenomena, owing to the difficulty in conducting small-scale analysis (nanostructures). In this study, the droplet interfacial behavior on silicon surfaces with micro/nano/micro-nano structures is experimentally investigated. The interfacial behavior is directly visualized using synchrotron X-ray imaging (side view). The spreading phenomena occur on structured surfaces, and the liquid interface behaviors on the surfaces differ. The liquid film thickness is uniform during spreading on the microstructured surface, but not on the nano case which shows a gentle slope. These combined spreading shapes were observed on a micro-nano structured surface, and liquid propagation was enhanced when the micro- and nano-structures are combined.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.8
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• pp.1783-1788
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• 2009

We newly propose that we may reuse scrap powders ($Z_rO_2$+8 mol%-$Y_2O_3$) as $Y_2O_3$-stabilized zirconia (YSZ) sintered products through sintering process at 1550$^{circ}C$ for 2hrs. We also prepared the reference specimen from fresh $Z_rO_2$+30 mol%-$Y_2O_3$ powder mixture (celluar type with 1㎛-length). The reference sample showed a dense microstructure with grains of $\sim$10㎛ in diameter, while the sintered sample from scrap powder showed irregular grains of 1$\sim$30 ㎛ in diameter. Through XRD analysis, we confirmed that the reference sample has mixed phases of $Y_2O_3$(cubic), $Z_{r0.8}O_{1.9}$(cubic), and $Z_rO_2$(monoclinic), while the sintered YSZ sample from scrap powder has only tetragonal phase. Moreover, the sintered YSZ from scrap powder showed vickers hardness and apparent density more than 70 and 4.11 g/cc, which implies that it can be suitable for structural material application.

• Conservation Science in Museum
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• v.3
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• pp.65-69
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• 2001

Scientific analysis are carried on gilded ornamental shoes, which have been excavated from tomb No 1. and No 4. in Beopcheon-ri, Wonju dated from Baekje Period. This object is a very important because it provides valuable information on the development of metal-making techniques of that period. Thus, this article illustrates the investigation conducted to reveal how the object was created using what materials and techniques. Instead of the spikes-attached to the bottom plate of the object-that couldn't be sampled, a sample of a decorative rivet showing a similar structure to the spikes-attached to the other parts of the shoes-was prepared for a cross-section examination. Using radiography and microscopes, it was found that the head of a spike was placed and then punched to the gilded plate, so it can be held to the shoes. Under the SEM-EDS, the cross-section of the rivet shows that the gilding layer was applied before the attachment of the rivets. It also shows that the gilding layer is distributed unevenly and there are empty spaces indicating amalgam gilding was employed. This was confirmed as Mercury was detected on the SEM-EDS analysis of the object. The examination of the microstructure of the plate using the SEM-EDS revealed that the object is made of a single copper alloy plate with recrystallized twining and non-metallic white inclusions, which found to be lead in this case.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.5
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• pp.3336-3344
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• 2014

The purpose of this study is small scale coagulation module is developed and demonstrated through a lab-scale test. Recent as a sewage treatment rate increases, have heightened the interest in the necessity on the nonpoint source and developing a small processing unit has been increased. Coagulation sedimentation module in this study is additional growth of floc through swirling in the outside zone, reduction of microstructure floc number and the internal settling zone through vertical/level flow complex sedimentation method after the coagulation process precipitation method as an effective high separation efficiency can be divided was also assessed. Coagulation sedimentation module can increase the load factor was 4.4 times compared to conventional clarifier base on the same volume and surface area through vertical/level flow. In this study, this process was selected formation and maintenance of swirling and uniform flow distribution in the internal settling zone as an important design factor, to derive its FLUENT was used to characteristics of the flow model. Through the simulation of swirling, influent velocity, dimensions of external basin, hopper depth of bottom cone was determined and through analysis of velocity distribution, flow distribution detailed specifications are derived like as diameter and number of effluent hole. Lab-scale($120{\ell}/hr$) test results, influent of 300~800 NTU to less than 10 NTU without polymer feeding was able to operate in the 20minutes retention time(surface loading rate $37.3m^3/m^2$-day), and through analysis FLUENT the possibility of using design parameters were derived.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.3
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• pp.83-88
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• 2015

Coating materials used in the electron beam (EB) deposition method, which is being studied as one of the fabrication methods of thermal barrier coating, are exposed to high power electron beam at focused area during the EB deposition. Therefore the coating source for EB process is needed to form as ingot with appropriate density and microstructure to sustain their shape and stable melts status during EB deposition. In this study, we tried to find the optimum powder condition for fabrication of ingot of 8 wt% yttria stabilized zirconia which can be used for EB irradiation. It seems that the ingot, which is fabricated through bi-modal type initial powder mixture which consists of tens of micro and nano size particles, was shown better performance than the ingot which is fabricated using monolithic nanoscale powder when exposed to high power EB.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.34 no.1
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• pp.51-58
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• 2021

In this paper, a multi-scale finite element (FE) modeling methodology for three-dimensional (3D) needle-punched (NP) C/SiC with a complex microstructure is presented. The variations of the material properties induced by the needle-punching process and complex geometrical features could pose challenges when estimating the material behavior. For considering these features of composites, a 3D microscopic FE approach is introduced based on micro-CT technology to produce a 3D high fidelity FE model. The image processing techniques of micro-CT are utilized to generate discrete-gray images and reconstruct the high fidelity model. Furthermore, a subcell modeling technique is developed for the 3D NP C/SiC based on the high fidelity FE model to expand to the macro-scale structural problem. A numerical homogenization approach under periodic boundary conditions (PBCs) is employed to estimate the equivalent behavior of the high fidelity model and effective properties of subcell components, considering geometry continuity effects. For verification, proposed models compare excellently with experimental results for the mechanical behavior of tensile, shear, and bending under static loading conditions.

• Nuclear Engineering and Technology
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• v.26 no.4
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• pp.484-492
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• 1994

Microstructures of Nb$_2$O$_{5}$-doped UO$_2$ pellets have been investigated during sintering under H$_2$ and $CO_2$ atmospheres. Pellets are sintered at 1$700^{\circ}C$ in H$_2$ atmosphere and at 130$0^{\circ}C$ in $CO_2$ atmosphere for 1 to 41 hr. The addison of Nb$_2$O$_{5}$ causes the formation of large pores, which shrink to some extent in H$_2$ atmosphere but very little in $CO_2$. Fine pores in the Nb$_2$O$_{5}$-doped UO$_2$ pellet are almost annihilated when sintered under H$_2$ atmosphere but little changed under $CO_2$ atmosphere. The increase in grain size due to Nb$_2$O$_{5}$ addition is much larger in H$_2$ atmosphere than in $CO_2$. Thus the enhancement of uranium diffusion in UO$_2$ due to the Nb$_2$O$_{5}$ addition is thought to be more significant in H$_2$ atmosphere. Microstructures of Nb$_2$O$_{5}$-doped UO$_2$ pellets sintered in H$_2$ atmosphere are discussed from the viewpoint of in-reactor performance. Possible defects formation due to Nb$_2$O$_{5}$ addition is discussed to explain the enhancement of uranium diffusion in H$_2$ and $CO_2$ atmospheres.> atmospheres.

• Journal of the Korea Institute of Building Construction
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• v.23 no.3
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• pp.231-240
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• 2023

In this research, our goal was to explore the potential use of cement mortar augmented with liquid red mud. To facilitate this, we neutralized liquid red mud(LR) - exhibiting a pH of 10-12 - using sulfuric acid to yield sulfuric acid neutralized red mud(SR). We then evaluated the flow, setting time, and compressive strength of the cement mortar combined with liquid red mud, while also performing a thorough examination of its chemical properties through X-ray diffraction(XRD) and scanning electron microscopy(SEM). The flow tests indicated a decrease in flow values for both MS-LR and MS-SR in comparison to the Plain. Analogously, the setting time for MS-LR and MS-SR was found to be abbreviated when juxtaposed with the Plain. With regards to compressive strength, MS-LR demonstrated a surge in strength at the 1-day mark, while MS-SR displayed a diminution at the 1-day and 3-day timepoints compared to the Plain. XRD analysis illustrated that after 28 days, the XRD patterns of Plain and MS-SR bore significant resemblance, though a new peak was detected in MS-LR. SEM imagery highlighted that the microstructures of Plain and MS-SR were alike, but MS-LR manifested a distinct microstructure, characterized by a finely fibrous formation. Based on these observations, we infer that the replacement of cement mortar with liquid red mud neutralized with sulfuric acid contributes to a noticeable enhancement in strength, thereby verifying its suitability for this application.

• Korean Journal of Materials Research
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• v.33 no.10
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• pp.406-413
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• 2023

This study used optical and scanning electron microscopy to analyze the surface oxidation phenomenon that accompanies a γ'-precipitate free zone in a directional solidified CM247LC high temperature creep specimen. Surface oxidation occurs on nickel-based superalloy gas turbine blades due to high temperature during use. Among the superalloy components, Al and Cr are greatly affected by diffusion and movement, and Al is a major component of the surface oxidation products. This out-diffusion of Al was accompanied by γ' (Ni₃Al) deficiency in the matrix, and formed a γ'-precipitate free zone at the boundary of the surface oxide layer. Among the components of CM247LC, Cr and Al related to surface oxidation consist of 8 % and 5.6 %, respectively. When Al, the main component of the γ' precipitation phase, diffused out to the surface, a high content of Cr was observed in these PFZs. This is because the PFZ is made of a high Cr γ phase. Surface oxidation of DS CM247LC was observed in high temperature creep specimens, and γ'-rafting occurred due to stress applied to the creep specimens. However, the stress states applied to the grip and gauge length of the creep specimen were different, and accordingly, different γ'-rafting patterns were observed. Such surface oxidation and PFZ and γ'-rafting are shown to affect CM247LC creep lifetime. Mapping the microstructure and composition of major components such as Al and Cr and their role in surface oxidation, revealed in this study, will be utilized in the development of alloys to improve creep life.