• Title/Summary/Keyword: Microporous

Search Result 259, Processing Time 0.027 seconds

Preparation and Characterization of the Asymmetric Microporous Poly(vinylidene fluoride) (PVDF) Blend Membranes with Hydrophilic Surfaces

  • Hwang, Jeong-Eun;JeGal, Jong-Geon
    • Korean Membrane Journal
    • /
    • v.9 no.1
    • /
    • pp.1-11
    • /
    • 2007
  • To prepare chemically stable asymmetric microporous membranes with a hydrophilic surface, which would be expected to have better antifouling properties, poly(vinylidene fluoride) (PVDF) blend membranes were prepared by the phase inversion process. PVDF mixture solutions in N-methylpyrrolidone (NMP) blended with several polar potential ionic polymers such as polyacrylonitrile (PAN), poly(methylmethacrylate) (PMMA) and poly(N-isopropylacrylamide) (NIPAM) were used for the formation of the PVDF blend membranes. They were then characterized with several analytical methods such as FESEM, FTIR, contact angle measurement, pore size distribution and permeability measurement. Regardless of different polar polymers blended, they all showed a finger-like structure with more hydrophilic surface than the pristine PVDF membrane. For all the PVDF blend membrane, due to the polar potential ionic polymers used, the flux of those was improved. Especially the PVDF blend membrane with NIPAM showed the highest flux among the membranes prepared. Also antifouling property of the PVDF membrane was improved by the use of the polar polymers.

Investigation of Water Transport in Newly Developed Micro Porous Layers for Polymer Electrolyte Membrane Fuel Cells

  • Alrwashdeh, Saad S.;Markotter, Henning;Haussmann, Jan;Hilger, Andre;Klages, Merle;Muller, Bernd R.;Kupsch, Andreas;Riesemeier, Heinrich;Scholta, Joachim;Manke, Ingo
    • Applied Microscopy
    • /
    • v.47 no.3
    • /
    • pp.101-104
    • /
    • 2017
  • In this investigation, synchrotron X-ray imaging was used to investigate the water distribution inside newly developed gas diffusion media in polymer electrolyte membrane fuel cells. In-situ radiography was used to reveal the relationship between the structure of the microporous layer (MPL) and the water flow in a newly developed MPL equipped with randomly arranged holes. A strong influence of these holes on the overall water transport was found. This contribution provides a brief overview to some of our recent activities on this research field.

Systemic-Pulmonary Shunts Using Microporous Expanded Polytetrafluoroethylene (Polytetrafluoroethylene 을 이용한 체-폐동맥 단락술)

  • Ahn, Hyuk
    • Journal of Chest Surgery
    • /
    • v.18 no.2
    • /
    • pp.314-319
    • /
    • 1985
  • Nineteen patients with various types of cyanotic congenital heart disease underwent systemic-pulmonary artery shunts with a microporous polytetrafluoroethylene [PTFE] graft between September, 1983, and April, 1985. Age ranged from 3 months to 18 years, and seven of them were less than 12 months old. There were seventeen Great Ormond Street type of modified Blalock-Taussig shunts, and two central polytetrafluoroethylene shunt [ascending aorta-right pulmonary artery]. There was one postoperative death [1/19=5.3%] in a 10 Kg child born with pulmonary atresia and ventricular septal defect associated with patent ductus arteriosus. He had another anomaly of imperforated anus. Relief from cyanosis was achieved in other eighteen patients with variable degree. Eighteen survivors have been followed up from 1 month to 19 months. Clinical status, auscultation, oxygen partial pressure of arterial blood, and hemoglobin have been used to establish shunt patency in all survivors. By above criteria, all survivors have good patent shunt.

  • PDF

Pore Condensation-Based Separation of VOCs by a Microporous Ceramic Membrane (미세다공성 세라믹 막에서의 가공응축기구에 의한 휘발성 유기화합물의 분리)

  • Cha, Jun-Seok
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.12 no.E
    • /
    • pp.19-28
    • /
    • 1996
  • A pore concensation-based separation technique was studied experimentally using toluene and xylene in a nitrogen stream. The removal rate of toluene and xylene on a microporous ceramic membrane was enhanced by increasing the partial pressure difference across the membrane, but the selectivity was reduced with increasing flux of nitrogen. This was found both in vacuum and pressure modes of operation. The experimental results from this study suggest that the pores mear the inlet portion of the module were filled with the organic solvent while the pores near the exit section of the module were slightly opened as the solvent concentration was depleted along the module. In the case of xylene, the rate of N$_{2}$ permeation was reduced considerably relative to toluene, resulting in a much higher separation gactor. Condensibility of xylene appeared to be higher than that of toluene, the potential for pore condensation-based separation of xylene was also found to be higher than that for toluene.

  • PDF

Effects of Nucleating Agents on Preparation of Polypropylene Hollow Fiber Membranes by Melt Spinning Process

  • Kim, Bong-Tae;Kigook Song;Kim, Sung-Soo
    • Macromolecular Research
    • /
    • v.10 no.2
    • /
    • pp.127-134
    • /
    • 2002
  • Microporous polypropylene hollow fiber membrane was fabricated from isotactic polypropylene-soybean oil system by melt spinning process. Addition of nucleating agent accelerated the crystallization rate and elevated the crystallization temperature. Nucleating agent increased the number of nuclei and spherulites, which offered more inter-spherulitic amorphous sites for stretching. Benzoic acid, adipic acid, and dibenzylidene sorbitol were selected as nucleating agents, and their characteristics and effects were investigated by thermal and optical analyses. Spherulite growth and micropore formation characteristics were correlated with the kind of nucleating agent. Benzoic acid and adipic acid showed the remarkable nucleating effect, while dibenzylidene sorbitol was less effective than those. Nucleating agents also helped the sample have uniform microporous structure. Increase of nucleating agent composition enhanced the nucleation effect to some extent. Nucleating agents played very important roles in enhancing the membrane porosity and water flux.