• Title/Summary/Keyword: Microporous

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Dialysis in parallel-flow rectangular membrane modules with external reflux for improved performance

  • Yeh, Ho-Ming;Cheng, Tung-Wen;Chen, Kuan-Hung
    • Membrane and Water Treatment
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    • v.1 no.2
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    • pp.159-169
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    • 2010
  • The effect of external recycle on the performance of dialysis in countercurrent-flow rectangular membrane modules was investigated both theoretically and experimentally. Theoretical analysis of mass transfer in parallel-flow device with and without recycle is analogous to heat transfer in parallel-flow heat exchangers. Experiments were carried out with the use of a microporous membrane to dialyze urea aqueous solution by pure water. In contrast to a device with recycle, improvement in mass transfer is achievable if parallel-flow dialysis is operated in a device of same size with recycle which provides the increase of fluid velocity, resulting in reduction of mass-transfer resistance, especially for rather low feed volume rate.

Sorption of $Pb^{2+}$ Ions on to Activated Carbons Prepared from Olive Stones

  • Attia, Amina. A.;Shouman, Mona. A.;El-Nabarawy, Th.
    • Carbon letters
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    • v.6 no.3
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    • pp.141-147
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    • 2005
  • The carbon sample "O", phosphoric acid-activated carbon "OP", zinc chloride-activated carbon "OZ", and two steam activated carbons "OS" and "OS2" with different burn-off of 25% and 58% respectively, were prepared from olive stones. The textural properties were determined from the results of nitrogen adsorption at 77 K and by analyzing these results through the application of different adsorption models. The chemistry of the carbon surfaces was determined from the base neutralization capacities, acid neutralization capacity and surface pH. The sorption of $Pb^{2+}$ ions on to the carbons prepared was followed under dynamic and equilibrium conditions. The differences between the values of the textural parameters were attributed to the inapplicability of some adsorption models and to the heterogeneity of the microporous carbons. The sorption of $Pb^{2+}$ ions is favored on carbon and activated carbons. However, chemically activated carbons are more effective compared with steam-activated ones. The sorption of $Pb^{2+}$ ions were related to the chemistry of the surface rather than to the textural properties.

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Volumetric Hydrogen Sorbent Measurement at High Pressure and Cryogenic Condition - Basic Measurement Protocols (부피법을 이용한 고압·극저온 수소 흡착량 측정 방식의 기본 원리)

  • OH, HYUNCHUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.4
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    • pp.349-356
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    • 2016
  • Volumetric capacity metrics at cryogenic condition are critical for technological and commercial development. It must be calculated and reported in a uniform and consistent manner to allow comparisons among different materials. In this paper, we propose a simple and universal protocol for the determination of volumetric capacity of sorbent materials at cryogenic condition. Usually, the sample container volume containing porous sample at RT can be directly determined by a helium expansion test. At cryogenic temperatures, however, this direct helium expansion test results in inaccurate values of the sample container volume for microporous materials due to a significant helium adsorption, resulting significant errors in hydrogen uptake. For reducing this container volume error, therefore, we introduced and applied the indirect method such as 'volume correction using a non-porous material', showing a reliable cold volume correction.

Photocatalytic Epoxidation of Olefins Using Molecular O2 by TiO2 Incorporated in Hydrophobic Y Zeolite

  • Kuwahara, Yasutaka;Magatani, Yasuhiro;Yamashita, Hiromi
    • Rapid Communication in Photoscience
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    • v.4 no.1
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    • pp.19-21
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    • 2015
  • Zeolite is an ideal host material for encapsulating nano-size metal catalyst species because of its defined microporous structure, prominent adsorption/condensation properties, high surface area, chemical/thermal stability, and transparency to light. In this study, $TiO_2$ photocatalyst was incorporated in highly hydrophobic Y zeolite and its photocatalytic activity was examined in the photocatalytic oxidation of olefins under UV-light irradiation using molecular oxygen as an oxygen source. $TiO_2$ nanoparticles incorporated in hydrophobic Y zeolite exhibited a markedly enhanced photocatalytic activity compared with bare $TiO_2$ owing to its excellent affinity toward organic moieties, which facilitates the mass transfer of organic substrates and allows them to efficiently access to the neighboring active $TiO_2$ surface.

A Study on the Comfortable Pesticide-Proof Clothes (농약방제복 개발에 관한 연구)

  • Choi Jeong Wha;Kim Hyun Sik;Jeong Yong Ok
    • Journal of the Korean Society of Clothing and Textiles
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    • v.11 no.2 s.24
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    • pp.91-100
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    • 1987
  • To develop the comfortable pesticid-proof clothes, wearing trials for 7 types of existing pesticide-proof clothes were done measuring skin temperature, pulse rate, humidity and temperature of inside clothing and subjective feeling such as thermal, humid and comfort sensations at $28{\pm}1^{\circ}C$, $75{\pm}5\%$ RH, 2.3 m/sec wind speed. (Experiment 1). On the base of above results, wearing trials of 6 types of new pesticide-proof clothes and 3 types of pesticide-proof clothes as control group were done with the same method as experiment 1. (Experiment 2). The results obtained were as follows 1. Heat stress was lower in newly designed pesticide-proof clothes with mesh running shirts. 2. For the body temperature regulation, it was confirmed that 6 types of new pesticide-proof clothes made of microporous fabric were better than the others.

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Electrochemical and Safety Performances of Polyimide Nano fiber-based Nonwoven Separators for Li-ion Batteries

  • Kim, Yeon-Joo;Lee, Sang-Min;Kim, Seok Hong;Kim, Hyun-Soo
    • Journal of Electrochemical Science and Technology
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    • v.6 no.1
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    • pp.26-33
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    • 2015
  • In this study, cell performance and thermal stability of lithium-ion cells with a polyimide (PI) separator are investigated. In comparison to conventional polyethylene (PE) separator, the PI separator exhibits distinct advantage in microporous structure, leading to superior reliability of the cell. The cells with PI separator exhibit good cell performances as same as the cells with PE separator, but their reliability was superior to the cell with PE separator. Especially in the hot-box test at 150 and 180℃, PI separator showed a contraction percentage close to 0% at 150℃, while the PE separator showed a contraction percentage greater than 10% in both width and length. Therefore, the PI separator can be the promising candidate for separators of the next generation of lithium-ion battery.

Formation of Solution-derived Hydroxyapatite Layer on the Surface of a Shell (용액 반응에 의한 패각 표면의 수산화아파타이트 층 생성 거동)

  • Kim, Hui-Lae;Song, Tae-Woong
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1177-1182
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    • 2002
  • Highly surfaced and porous hydroxyapatite body was artificially formed on the surface of a shell through a reaction with phosphatic solutions. As a result of qualitative observation, hydroxyapatite seemed to be crystallized by solution-precipitation process accelerated by the nucleation surface of a shell. The process of formation of hydroxyapatite layer was as follows. 1. Dense nucleation and growth on the surface of solid phase 2. Formation of microporous layer by contact and entanglement between crystallines 3. diffusion of solution through the porous layer and thickness growth of layer towards inside

Preparation and Properties of Modified PHEMA Hydrogels Containing Thermo-responsive Pluronic Component

  • Hong, Kwang-Hyun;Jeon, Young-Sil;Kim, Ji-Heung
    • Macromolecular Research
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    • v.17 no.1
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    • pp.26-30
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    • 2009
  • To modify and strengthen the properties of PHEMA hydrogel, composite hydrogels containing varying amounts of a Pluronic (PEO-PPO-PEO) component were synthesized by bulk polymerization of HEMA in the presence of Pluronic dimethacrylate under mild photo initiating conditions. The effects of the Pluronic component on gel properties were investigated by measuring the degree of swelling with its temperature responsive behavior, the mechanical properties, and the morphology of the composite hydrogels. With increased Pluronic content, the modified PHEMA hydrogels exhibited an increase in the degree of swelling, and the swelling showed an enhanced thermo-responsive behavior that was completely reversible. In addition, improved mechanical strength and the development of a microporous gel morphology were observed in hydrogels containing Pluronic.

Miscibility of Polysulfone/Poly(1-vinylpyrrolidone-co-styrene) Blends and Their Application to the Ultrafiltration Membrane

  • Kim, Joo-Heun;Yoo, Jung-Eun;Kim, Chang-Keun
    • Macromolecular Research
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    • v.10 no.4
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    • pp.209-214
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    • 2002
  • Miscibility of polysulfone (PSf) with various hydrophilic copolymers was explored. Among these blends, PSf gives homogeneous mixtures with poly(1-vinylpyrrolidone-co-styrene) copolymers [P(VP-S)] when these copolymers contained VP from 68 to 88 wt%. Microporous membranes for the ultrafiltration process were prepared from PSf blends with P(VP-S) copolymers. The membranes prepared from the PSf/(VP-S) blends exhibited higher water flux than the membranes prepared from PSf irrespective of the VP content. The solute rejection examined with the membranes fabricated from the miscible blends was similar to that of PSf membrane. However, the solute rejection examined with the membranes fabricated from the immiscible blends was lower than that of PSf membranes.