• 지구물리
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• 제3권3호
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• pp.185-192
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• 2000

미세중력 측정기는 최근 그 중요성이 부각되고 있는 분야로 전통적인 중력측정장치를 기초로 개발되었다. 이 논문에서는 지하 광전 탐사 작업을 위한 미세중력 측정기의 원리와 기술, 그리고 활용법을 소개한다. 몇몇 조사 곡선들은 모델들을 통한 이론적 계산치와 비교하여 볼 때 왜 만족스러운 결과들을 보여주고 있다. 이 방법들은 지하의 왕궁이나 묘지들을 탐사하는데 유용하게 사용될 수 있을 것이다.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.3113-3116
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• 2013

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 1999년도 제2회 총회 및 춘계학술발표회
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• pp.13-13
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• 1999

• Bulletin of the Korean Chemical Society
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• 제29권5호
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• pp.939-942
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• 2008

Photoelectrochemical deposition of CdZnSe thin films on the Se-modified Au electrode using electrochemical quartz crystal microgravimetry (EQCM) and voltammetry is described. Corrosion of pre-deposited Se electrodes by illumination at a fixed potential resulted in $Se^{2-}$ species, which was manifest from the EQCM frequency changes. $Se^{2-}$ species generated from the photocorrosion reacted with $Cd^{2+}$ and $Zn^{2+}$ ions in the electrolyte to form CdZnSe films on the Au electrode. The effect of electrolyte composition on the composition and band gap of CdZnSe films was studied in detail. Also, photoelectrochemistry, EDX, Raman spectroscopy were used for the characterization of CdZnSe thin films.

• Bulletin of the Korean Chemical Society
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• 제22권9호
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• pp.994-998
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• 2001

Ni, Fe and NiFe alloy thin films were electrodeposited at a polycrystalline Au surface using a range of electrolytes and potentials. Coulometry and EQCM were used for real-time monitoring of electroplating efficiency of the Ni and Fe. The plating efficiency of NiFe alloy thin films was computed with the aid of ICP spectrometry. In general, plating efficiency increased to a steady value with deposition time. Plating efficiency of Fe was lower than that of Ni at -0.85 and -1.0 V but the efficiency approached to the similar plateau value to that of Ni at more negative potentials. The films with higher content of Fe showed different stripping behavior from the ones with higher content of Ni. Finally, compositional data and real-time plating efficiency are presented for films electrodeposited using a range of electrolytes and potentials.

• Journal of Electrochemical Science and Technology
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• 제4권4호
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• pp.140-145
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• 2013

This study describes the electrodeposition of $Cu_2Se$ thin films with a two-step approach that is based on the initial modification of polycrystalline Au electrode with a selenium overlayer followed by a cathodic stripping of the layer as $Se^{2-}$ in a 1 M lactic acid electrolyte containing $Cu^{2+}$ ions. For this two-step approach to be effective, the $Cu^{2+}$ reduction potential should be shifted to more negative potentials passed potentials for the reduction of Se to $Se^{2-}$. This was accomplished by the complexation of $Cu^{2+}$ ions with lactic acid. The resultant $Cu_2Se$ films were characterized by linear sweep voltammetry combined with electrochemical quartz crystal microgravimetry, UV-vis absorption spectrometry and Raman spectroscopy. Photoelectrochemical experiments revealed that $Cu_2Se$ synthesized thus, behaved as a p-type semiconductor.

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2007년도 특별 심포지엄 논문집
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• pp.15-25
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• 2007

Gravity method could be one of the most effective tool for evaluating the soundness of basement which is directly correlated with density and its variations. Moreover, Gravimeter is easy to handle and strong to electromagnetic noises. But, gravity anomaly due to the target structures in engineering and environmemtal applications are too small to detect, comparing to the external changes, such as, elevation, topography, and regional geological variations. Gravity method targeting these kinds of small anomaly sources with high precision usually called microgravity. Microgravimetry with precision and accuracy of few ${\mu}Gal$, can be achieved by the recent high-resolution gravimeter, careful field acquisition, and sophisticated processing, analysis, and interpretation routines. This paper describes the application of the microgravity, such as, density structure of a rock fill dam, detection of abandoned mine-shaft, detection and mapping of karstic cavities in limestone terrains, and time-lapse gravity for grout monitoring. The case studies show how the gravity anomalies detect the location of the targets and reveal the geologic structure by mapping density distributions and their variations.

• 전기화학회지
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• 제10권4호
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• pp.262-264
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• 2007

This paper describes a two-step approach for the electrochemical deposition of CdZnS thin films on the polycrystalline Au electrode. Initially, an Au substrate is electrochemically modified with a sulfur layer. In the second step, the layer is electroreduced to $S^{2-}$ in the electrolyte dosed with the requisite amount of $Cd^{2+}$ and $Zn^{2+}$ ions to generate CdZnS films in situ. This approach was validated using a combination of linear sweep voltammetry and electrochemical quartz crystal microgravimetry. Thus synthesized CdZnS thin films have different composition depending on the composition of electrolytes. CdZnS thin films are characterized by energy-dispersive X-ray analysis and Raman spectroscopy.

• Bulletin of the Korean Chemical Society
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• 제24권11호
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• pp.1613-1617
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• 2003

In the phosphoric acid based etchant, the dissolution rates of Mo films were measured by microgravimetry and the corrosion potentials of Mo and Al were estimated by Tafel plot method with various concentrations of nitric acid. Dissolution rate of Mo increased with the nitric acid concentration and reached a limiting value at high concentration of nitric acid in ambient condition. Corrosion potentials of Mo and Al shifted to positive direction and the difference between potentials of both metals was about 1,100 mV and 1,200 mV with 1% and above 4% of $HNO_3$, respectively. For a Mo/Al bilayers, the dissolution rate inversion is the main reason for good taper angle in shower etching process. Taper angles are observed by scanning electron microscope (SEM) after wet etching process for Mo/Al layered films with different concentrations of $HNO_3$. In the etch side profile, it was found that Al corroded faster than Mo below 4% of $HNO_3$ in dip etching process, however, Mo corroded faster above 4%. Trend for variation of taper angle of etched side of Mo/Al layered film can be explained by considering the effect corrosion rates of both metals with various concentrations of $HNO_3$.