• 제목/요약/키워드: Micro-content

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Study on quantitative & trace element analysis of metal objects (고대 청동기의 성분조성 및 산지추정 연구)

  • Chung, Kwang-Yong;Kang, Hyung-tae;Chong, Dong-Chan;Yun, Yong-hyun;Lee, Hoon
    • 한국문화재보존과학회:학술대회논문집
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    • 2004.10a
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    • pp.137-153
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    • 2004
  • We have analyzed the ingredients of 17 pieces of Bronze Age bronze ware, and an additional 22 pieces of Koryo and Chosun dynasty bronze ware. We have also conducted analysis of the extraction sites where these bronze ware items were found. For analyzing the main ingredient the bronze ware items have been divided into 3 groups - Cu-Sn(70?75:20), Cu-Pb-Sn(70:10:10), Cu-Pb-Sn(60:10:20) type respectively. In tile cases of the Cu-Pb-Sn groups the division comes down to differences in the Cu content as the main component, and elements such as Ni, Fe, Co contribute as a micro ingredient. The geographical and periodic characteristics of ancient bronze ware items show that theircompositional element changes from Cu:Sn to Cu:Pb:Sn and the Cu content decreases with the period,while the Pb content increases with the period. Bronze ware items from Suchon Ri, Gongju (that were used in 3 B.C.) form very different categories from 3rd ${\~}$ 2nd B.C.. They additionally formed very different categories from those bronze ware items analyzed in this research. These bronze ware itemsare shown to be geographically close and periodically overlapped, but made of a new elemental composition. This shows an inflow of a production technical culture present in the new bronze wares. The main component content of Cu is lower, and the Co and Fe contents (as microelements) are much higher than that of other bronze ware items. Such facts showthat those bronze ware items used completely different materials from bronze ware items in other cultural areas, or that there were differences in smelting techniques In the places where ancient bronze ware items have been extracted, it is presumed that the materials originated from the southern parts of Korea andnorthern parts and southern parts of China. .As more bronze ware scientific research is compiled one can conclude that that there will be enough scientific evidence to study the Bronze Age culture of Koreasystematically.

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Analysis of Eutectic Reaction as a Function of Cooling Rate in High Manganese Flake Graphite Cast Irons (고 망간 편상흑연주철에서 냉각속도별 공정반응 분석)

  • Lee, Sang-Hwan;Lee, Hyun-Woo;Lee, Sang-Mok
    • Journal of Korea Foundry Society
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    • v.33 no.4
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    • pp.162-170
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    • 2013
  • The effects of Mn content and cooling rate on the eutectic reaction of flake graphite cast irons were studied by a combined analysis of macro/micro-structure and cooling curve data. The correlation between the eutectic reaction parameter and macro/microstructure was systematically investigated. Two sets of chemical compositions with different Mn contents were designed to cast. Three types of molds for cylindrical specimens with different diameters were prepared to analyze the cooling rate effect. The difference between undercooling temperature and cementite eutectic temperature (${\Delta}T_1=T_U-T_{E,C}$), which is decreased by increasing the Mn content or increasing the cooling rate, is considered to be a suitable eutectic reaction parameter for predicting graphite morphology. According to the criterion, A-type graphite is mainly suggested to form for ${\Delta}T_1$ over $20^{\circ}C$, and D-type graphite is mainly suggested to form for ${\Delta}T_1$ below $0^{\circ}C$. Eutectic reaction time (${\Delta}T$), which is increased by increasing the Mn content and decreased by increasing the cooling rate, is regarded as a suitable eutectic reaction parameter for predicting eutectic cell size. Eutectic cell size is found to decrease in proportion to the decrease of ${\Delta}T$.

A Study on the Effects of Hydrogen Addition and Swirl Intensity in CH4-Air Premixed Swriling Flames (메탄-공기 예혼합 선회화염에서 수소첨가와 선회강도 영향에 관한 연구)

  • KIM, HAN SEOK;CHO, JU HYEONG;KIM, MIN KUK;HWANG, JEONGJAE;LEE, WON JUNE
    • Journal of Hydrogen and New Energy
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    • v.30 no.6
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    • pp.593-600
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    • 2019
  • The combustion characteristics of methane/hydrogen pre-mixed flame have been investigated with swirl stabilized flame in a laboratory-scale pre-mixed combustor with constant heat load of 5.81 kW. Hydrogen/methane fuel and air were mixed in a pre-mixer and introduced to the combustor through a burner nozzle with different degrees of swirl angle. The effects of hydrogen addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using particle image velocimetry (PIV), micro-thermocouples, various optical interference filters and gas analyzers to provide information about flow velocity, temperature distributions, and species concentrations of the reaction field. The results show that higher swirl intensity creates more recirculation flow, which reduces the temperature of the reaction zone and, consequently, reduces the thermal NO production. The distributions of flame radicals (OH, CH, C2) are dependent more on the swirl intensity than the percentage of hydrogen added to methane fuel. The NO concentration at the upper part of the reaction zone is increased with an increase in hydrogen content in the fuel mixture because higher combustibility of hydrogen assists to promote faster chemical reaction, enabling more expansion of the gases at the upper part of the reaction zone, which reduces the recirculation flow. The CO concentration in the reaction zone is reduced with an increase in hydrogen content because the amount of C content is relatively decreased.

Discrimination of Ginseng Habitat by Using Instrumental Analysis Techniques

  • Sohn H. J.;Lee S. K.;Cho B. G.;Kim S. J.;Lee N. Y.;Choi D. S.;Jeong M. S.;Bae H. R.;Yang J. W.
    • Proceedings of the Ginseng society Conference
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    • 2002.10a
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    • pp.238-252
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    • 2002
  • In order to screen out indicators for the discrimination of ginseng habitat, some physical and chemical characteristics of Korean red ginsengs (94 kinds) and Chinese red ginsengs (50 kinds) were analyzed by using a rheometer, an electronic nose system, a combined technique of solid phase micro-extraction (SPME) and gas chromatograph equipped with an electron capture detector (GC/ECD), an X-ray fluorescence spectrometer (XRF), an inductively coupled plasma mass spectrometer (ICP/MS), a near infrared spectrometer (NIRs) and high performance liquid chromatography equipped with evaporative light scattering detector (HPLC/ELSD). The results are summarized as follows: (i) The rhizome strengths of Korean red ginsengs were significantly higher than those of Chinese red ginsengs. (ii) The electronic nose patterns of Korean red ginsengs were significantly different from those of Chinese red ginsengs. (iii) Some unidentified peaks were detected not in the headspace of Korean red ginsengs but in the headspace of Chinese red ginsengs when the headspace volatiles prepared by the SPME technique were analyzed by GC/ECD. (iv) Either the content ratios of K to Ca or Mn to Fe were significantly different between Korean red ginsengs and Chinese red ginsengs. (v) The reflectance ratios of NIRs wavenumbers such as $904\;cm^{-1}\;to\;1088\;cm^{-1}$ for Korean red ginsengs were significantly different from those for Chinese red ginsengs. (vi) The content ratios of ginsenoside-Rg to ginsenoside-Re of Korean red ginsengs were significantly higher than those of Chinese red ginsengs. These results indicate that the rhizome strength, the electronic nose pattern, the occurrence of ECD-sensitive headspace volatile components, the content ratios of K to Ca and Mn to Fe, the NIRs pattern and the content ratio of ginsenoside-Rg to -Re may be indicators for the discrimination of ginseng habitat.

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Assessment of flowing ability of self-compacting mortars containing recycled glass powder

  • Alipour, Pedram;Namnevis, Maryam;Tahmouresi, Behzad;Mohseni, Ehsan;Tang, Waiching
    • Advances in concrete construction
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    • v.8 no.1
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    • pp.65-76
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    • 2019
  • This paper investigates the effect of recycled glass powder (RGP) on flowing properties of self-compacting mortars (SCMs) containing different ratios of fillers and superplasticizer dosages. Fly ash (FA), nano-silica (NS), micro-silica (MS), metakaolin (MK) and rice husk ash (RHA) are used as fillers and their synergistic effect with RFP is studied. The effects of fillers and high-range water reducer (HRWR) on flowing ability of mortars are primarily determined by slump flow and V-funnel flow time tests. The results showed that for composites with a higher RGP content, the mortar flowing ability increased but tended to decrease when the composites containing 10% MK or 5% RHA. However, the flowing ability of samples incorporating 5% RGP and 10% SF or 25% FA showed an opposite result that their slump flow spread decreased and then increased with increasing RGP content. For specimens with 3% NS, the influence of RGP content on flowing properties was not significant. Except RHA and MS, the fillers studied in this paper could reduce the dosage of HRWR required for achieving the same followability. Also, the mixture parameters were determined and indicated that the flowability of mixtures was also affected by the content of sand and specific surface area of cement materials. It is believed that excess fine particles provided ball-bearing effect, which could facilitate the movement of coarse particles and alleviate the interlocking action among particles. Also, it can be concluded that using fillers in conjunction with RGP as cementitious materials can reduce the material costs of SCM significantly.

A Study on Improvement Measures Related to District Unit Planning to Induce Landscape-Friendly Planning in Non-Urban Areas (비시가화지역의 경관친화적 계획 유도를 위한 지구단위계획 관련 제도 개선방안 연구)

  • Kim, Jin Hyo;Ra, Jung Hwa;Kwon, Oh Sung
    • Journal of Korean Society of Rural Planning
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    • v.27 no.2
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    • pp.1-11
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    • 2021
  • In this study, in order to induce landscape-friendly various development plans established at the district level, the contents of landscape plans appearing in domestic laws and systems and related previous studies are reviewed and comparative analysis is performed to advance the district-level landscape plan. The main focus was to explore the institutional methodology for this. The summary of the research results is as follows. First of all, as a result of analysis of the landscape plan content prescribed in the National Territory Planning Act and the enforcement decree of the same Act, the landscape plan content for natural elements and the landscape plan content for artifacts appeared mixed. Next, looking at the analysis results of the landscape plan contents in the Landscape Act, the Enforcement Decree of the same Act, and the landscape plan establishment guidelines, it is analyzed that the content mainly intended to improve the artificial landscape in terms of aesthetics, such as color, lighting, and buildings. Became. As a result of analysis of the landscape plan contents in the district unit plan establishment guidelines, it was found that the contents of the landscape plan for the skyline, night view, color, advertisements, and viewpoints were presented. As a result of the analysis of the landscape plan contents in the preceding study, the plan contents for ecological, recreational, and micro-visual aspects were revealed, and all three aspects aim to establish a landscape plan within the range of minimizing damage to nature. there was. Appeared to be. The results of this study are considered to be able to induce more landscape and nature-friendly district unit plans being conducted at the district level.

Determination of Optimum Binder Content in the Catalyst Layer with Different GDL for Anode of HT-PEMFC (고온 고분자 전해질막 연료전지 수소극 전극에서 서로 다른 가스 확산층에 따른 최적 바인더 함량 결정)

  • CHUN, HYUNSOO;KIM, DO-HYUNG;JUNG, HYEON-SEUNG;PAK, CHANHO
    • Journal of Hydrogen and New Energy
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    • v.33 no.1
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    • pp.38-46
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    • 2022
  • Two different gas diffusion layers having noticeable differences in micro-porous layer's (MPL's) crack were studied as a substrate for the gas diffusion electrode (GDE) with different binder/carbon (B/C) ratios in high-temperature polymer electrolyte fuel cell (Ht-PEMFC). As a result, the performance defined as the voltage at 0.2 A/cm2 and maximum power density from the single cells using GDEs from H23 C2 and SGL38 BC with different B/C ratios were compared. GDEs from H23 C2 showed a proportional increase of the voltage with the binder content on the other hand GDEs from SGL38 BC displayed a proportional decline of the voltage to the binder content. It was revealed that MPL crack influences the structure of catalyst layer in GDEs as well as affects the RCathode which is in close connection with the Ht-PEMFC performance.

Impact of Korean Malting Barley Varieties on Malt Quality

  • Young-Mi Yoon;Jin-Cheon Park;JaeBuhm Chun;Yang-Kil Kim;Hyeun-Cheol Cheo;Chang-Hyun Lee;Seul-Gi Park;Tae-Il Park
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.18-18
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    • 2022
  • Barley has been used for the production of malt in the brewing industry. Malting is the process of preparing barley through partial germination. Malt extract is the most important quality parameter for malt quality. The grain and malt quality parameters of ten Korean malting barley varieties were studied. Malts was prepared using Phoeix automated micro malting system(Phoenix Bio, Australia). Quality analysis of Barley and malt was determined according to European brewery convention(EBC, 1998) and American society of brewing chemists(ASBC, 1997) method. And the hordeins of barley and malt were extracted with 50% isopropyl alcohol(IPA, 2-propanol) of 1% dithiothreitol(DTT). The analysis of hordeins was carried out by ultra-performance liquid chromatography(UPLC). The mean values of 1000-grains weight, assortment rate, protein content, starch content, beta-glucan content, husk rate, germination energy, germination capacity and water sensitivity of grain were 45.8g, 86.8%, 11.9%, 58.0%, 3.8%, 14.0%, 96.2%, 97.2%, 10.0%, respectively. The mean values of protein content, friability, diastatic power, extract, soluble protein, Kolbach index, beta-glucan of malt and wort were 11.3%, 87.6%, 201WK(Windish Kolbach), 79.3%, 4.6%, 41%, 85mg/L, respectively. UPLC analysis of grain and malt hordeins revealed that the amount of hordeins significantly degraded during malting. Also, we could successfully be used to compare hordein polypeptide patterns with malt quality.

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Experimental Research on the Effect of the Number of Layers by Overlay Welding of Monel-Clad Pipe on Weldability (모넬(Monel)-Clad 파이프의 오버레이 용접 적층수가 용접성에 미치는 영향에 관한 실험적 연구)

  • Choi, Hyeok;Park, Joon-Hong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.11
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    • pp.42-50
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    • 2016
  • Overlay welding affects the chemical components and weld hardness by dilution of the lamination layer thickness, which determines the surface properties. This study experimentally investigates different numbers of layers for overlay welding monel materials, which are anti-corrosion materials. The Fe content, weldability of the base metal and monel materials, hardness, and surface flatness were examined. Each evaluation was carried out after overlay welding with three layers on the base material and pipe base material of the plate. The Fe content was evaluated by analyzing the constituents of each layer. The Fe content was satisfactory in the three layers. The weldability of the laminate specimens was evaluated by a bending test. The hardness and bead flatness of the laminate specimens were evaluated by micro Vickers and 3D measurements. The hardness was highest in the heat-affected zone with one layer, and it decreased with increasing lamination. In the case of bead flatness, there is a sharp difference in the deviation with increasing numbers of laminations, which should be considered carefully.

Physicochemical Changes of Woody Charcoals Prepared by Different Carbonizing Temperature (탄화온도가 목탄의 물리·화학적 특성에 미치는 영향)

  • Jo, Tae-Su;Choi, Joon-Weon;Lee, Oh-Kyu
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.3
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    • pp.53-60
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    • 2007
  • Carbon content, properties of micro-pore, and chemical properties of the charcoal prepared from wood powder, wood fiber, and bark of Abies sibirica Ledeb at different temperatures were investigated. The yield of charcoal decreased with increasing the carbonization temperature. The yield of bark charcoal was higher than those of wood and wood fiber charcoal. The content ratio of carbon atom in the charcoal increased with increasing the carbonization temperature, whereas those of hydrogen and oxygen atom were decreased. Ash content of bark charcoal was also higher than those of wood and wood fiber charcoal. The specific surface area of wood and wood fiber charcoal was greater than that of bark charcoal. In all charcoal, the specific surface area and the volume of micro-pore were highest when the carbonization temperature was $600^{\circ}C$, however they tended to decrease when the temperature was reached to $800^{\circ}C$. For the functionality test of chemical groups on the charcoal surface, adsorption test have performed against acidic (HCl) and basic chemicals (NaOH, $Na_2CO_3$, and $NaHCO_3$). As carbonization temperature increased, adsorption amount of HCl increased, while adsorption amounts of NaOH, $Na_2CO_3$, and $NaHCO_3$ were decreased. The charcoal prepared at higher temperature showed basic properties, while the charcoals manufactured at lower temperature presented acidic properties. Therefore, it was considered that the carbonization temperature affected the pH of charcoal.