• Title/Summary/Keyword: Micro-batteries

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Porous Nickel-Tin Nano-Dendritic Electrode for Rechargeable Lithium Battery (리튬 이차 전지를 위한 다공성 니켈-주석 나노 수지상 전극)

  • Jung, Hye-Ran;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.20 no.11
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    • pp.592-599
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    • 2010
  • A porous nickel-tin nano-dendritic electrode, for use as the anode in a rechargeable lithium battery, has been prepared by using an electrochemical deposition process. The adjustment of the complexing agent content in the deposition bath enabled the nickel-tin alloys to have specific stoichiometries while the amount of acid, as a dynamic template for micro-porous structure, was limited to a certain amount to prevent its undesirable side reaction with the complexing agent. The ratios of nickel to tin in the electro-deposits were nearly identical to the ratios of nickel ion to tin ion in the deposition bath; the particle changed from spherical to dendritic shape according to the tin content in the deposits. The nickel to tin ratio and the dendritic structure were quite uniform throughout the thickness of the deposits. The resulting nickel-tin alloy was reversibly lithiated and delithiated as an anode in rechargeable lithium battery. Furthermore, the resulting anode showed much more stable cycling performance up to 50 cycles, as compared to that resulting from dense electro-deposit with the same atomic composition and from tin electrodeposit with a similar porous structure. From the results, it is expected that highly-porous nickel-tin alloys presented in this work could provide a promising option for the high performance anode materials for rechargeable lithium batteries.

Compact battery-less guest guidance system at the EXPO 2005, Aichi Japan

  • Itoh, Hideo;Lin, Xin;Kaji, Ryosaku;Niwa, Tatsuya;Nakamura, Yoshiyuki;Nishimura, Takuichi
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.2207-2210
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    • 2005
  • Guest guidance system based on the compact battery-less information terminal, Aimulet, which has been developed by the authors of the National Institute of Advanced Industrial Science and Technology (AIST), Japan. Conventional Aimulet, which is Aimulet ver.1 or CoBIT, has features of location and direction sensitive information service device without batteries. On the other hand, the Aimulet has two subjects, one is multiplex and demultiplex of some contents, and the other is operation under sunshine. Former subject is of solved by the wavelength multiplex technique using LED emitter with different wavelength and dielectric optical filters. Latter subject is solved by new micro spherical solar cells with a visible-light-eliminating optical filter and a new design of light irradiation. These techniques are applied to the EXPO 2005, Aichi Japan and introduced in public. Aimulet GH is Former technique is applied on Aimulet GH, which is used in Orange Hall of the Global House, scientific museum with a fossil of a frozen mammoth.

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Energy efficiency strategy for a general real-time wireless sensor platform

  • Chen, ZhiCong
    • Smart Structures and Systems
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    • v.14 no.4
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    • pp.617-641
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    • 2014
  • The energy constraint is still a common issue for the practical application of wireless sensors, since they are usually powered by batteries which limit their lifetime. In this paper, a practical compound energy efficiency strategy is proposed and realized in the implementation of a real time wireless sensor platform. The platform is intended for wireless structural monitoring applications and consists of three parts, wireless sensing unit, base station and data acquisition and configuration software running in a computer within the Matlab environment. The high energy efficiency of the wireless sensor platform is achieved by a proposed adaptive radio transmission power control algorithm, and some straightforward methods, including adopting low power ICs and high efficient power management circuits, low duty cycle radio polling and switching off radio between two adjacent data packets' transmission. The adaptive transmission power control algorithm is based on the statistical average of the path loss estimations using a moving average filter. The algorithm is implemented in the wireless node and relies on the received signal strength feedback piggybacked in the ACK packet from the base station node to estimate the path loss. Therefore, it does not need any control packet overheads. Several experiments are carried out to investigate the link quality of radio channels, validate and evaluate the proposed adaptive transmission power control algorithm, including static and dynamic experiments.

Structuring of Bulk Silicon Particles for Lithium-Ion Battery Applications

  • Bang, Byoung-Man;Kim, Hyun-Jung;Park, Soo-Jin
    • Journal of Electrochemical Science and Technology
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    • v.2 no.3
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    • pp.157-162
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    • 2011
  • We report a simple route for synthesizing multi-dimensional structured silicon anode materials from commercially available bulk silicon powders via metal-assisted chemical etching process. In the first step, silver catalyst was deposited onto the surface of bulk silicon via a galvanic displacement reaction. Next, the silver-decorated silicon particles were chemically etched in a mixture of hydrofluoric acid and hydrogen peroxide to make multi-dimensional silicon consisting of one-dimensional silicon nanowires and micro-scale silicon cores. As-synthesized silicon particles were coated with a carbon via thermal decomposition of acetylene gas. The carbon-coated multi-dimensional silicon anodes exhibited excellent electrochemical properties, including a high specific capacity (1800 mAh/g), a stable cycling retention (cycling retention of 89% after 20 cycles), and a high rate capability (71% at 3 C rate, compared to 0.1 C rate). This process is a simple and mass-productive (yield of 40-50%), thus opens up an effective route to make a high-performance silicon anode materials for lithiumion batteries.

Enhanced High-Temperature Performance of LiNi0.6Co0.2Mn0.2O2 Positive Electrode Materials by the Addition of nano-Al2O3 during the Synthetic Process (LiNi0.6Co0.2Mn0.2O2 양극 활물질의 합성공정 중 나노크기 알루미나 추가에 의한 고온수명 개선)

  • Park, Ji Min;Kim, Daeun;Kim, Hae Bin;Bae, Joong Ho;Lee, Ye-Ji;Myoung, Jae In;Hwang, Eunkyoung;Yim, Taeeun;Song, Jun Ho;Yu, Ji-Sang;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.80-86
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    • 2016
  • High Ni content layered oxide materials for the positive electrode in lithium-ion batteries have high specific capacity. However, their poor electrochemical and thermal stability at elevated temperature restrict the practical use. A small amount of $Al_2O_3$ was added to the mixture of transition metal hydroxide and lithium hydroxide. The $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ was simultaneously doped and coated with $Al_2O_3$ during heat-treatment. Electrochemical characteristics of modified $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ were evaluated by the galvanostatic cycling and the LSTA(linear sweep thermmametry) at the constant voltage conditions. The nano-sized $Al_2O_3$ added materials show better cycle performance at elevated temperature than that of micro-sized $Al_2O_3$. As the added amount of nano-$Al_2O_3$ increased, the thermal stability of electrode also enhanced, but the use of 2.5 mol% Al showed the best high temperature performance.

Synthesis and characterization of LiCoO2 thin film by sol-gel process (Sol-gel법에 의한 LiCoO2 박막의 합성과 특성평가)

  • Roh, Tae-Ho;Yon, Seog-Joo;Ko, Tae-Seog
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.3
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    • pp.94-98
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    • 2014
  • $LiCoO_2$ thin film has received diverse attention as cathodes material of thin-film micro-batteries. In this study, $LiCoO_2$ thin films were synthesized on Au substrates by sol-gel spin coating method and an annealing process. Their structures were studied using X-ray diffraction and Raman Spectroscopy. The particle morphologies of these thin films were observed by Scaning electron microscope. From the results of X-ray diffractometry and Raman Spectroscopy analyses, it was found that as-grown films had the structure of spinel (LT-$LiCoO_2$) and layered-Rock-salt (HT-$LiCoO_2$) at $550^{\circ}C$ and $750^{\circ}C$ respectively. The annealed films at $650^{\circ}C$ were presumed to be the mixed state of these two types. Throlugh the scanning electron microscope, It was estimated that the particle size in as-grown films at $750^{\circ}C$, were larger crystilline particle than in those at the other lower temperature and well distributed in the film.

Fabrication of Nickel-based Piezoelectric Energy Harvester from Ambient Vibration with Micromachining Technology (마이크로 머시닝 기술을 이용한 니켈기반의 압전 진동형 에너지 하베스터 제작)

  • Cha, Doo-Yeol;Lee, Jai-Hyuk;Chang, Sung-Pil
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.1
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    • pp.62-67
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    • 2012
  • Owing to the rapid growth of mobile and electronic equipment miniaturization technology, the supply of micro mobile computing machine has been fast raised. Accordingly they have performed many researches on energy harvesting technology to provide promising power supply equipment to substitute existing batteries. In this paper, in order to have low resonance frequency for piezoelectric energy harvester, we have tried to make it larger than before by adopting nickel that has much higher density than silicon. We have applied it for our energy harvesting actuator instead of the existing silicon based actuator. Through such new concept and approach, we have designed energy harvesting device and made it personally by making with micromachining process. The energy harvester structure has a cantilever type and has a dimension of $10{\times}2.5{\times}0.1\;mm^3$ for length, width and thickness respectively. Its electrode type is formed by using Au/Ti of interdigitate d33 mode. The pattern size and gap size is 50 ${\mu}m$. Based on the measurement of the nickel-based piezoelectric energy harvester, it is found to have 778 Hz for a resonant frequency with no proof mass. In that resonance frequency we could get a maximum output power of 76 ${\mu}W$ at 4.8 $M{\Omega}$ being applied with 1 g acceleration.

A Study on Energy Efficiency of Battery Charge/Discharge System based on DC μ-Grid (DC μ-Grid 기반 배터리 충/방전 시스템의 에너지 효율에 관한 연구)

  • Yeo, Sung-Dae;Kim, Jong-Un;Lee, Kyung-Ryang;Han, Cheol-Kyu;Ryu, Tae-Hyoung;Kim, Kyeong-Hwa;Kim, Seong-Kweon
    • The Journal of the Korea institute of electronic communication sciences
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    • v.10 no.12
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    • pp.1337-1344
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    • 2015
  • Formation process through charge/discharge operation is needed in manufacturing Li-ion battery. In the process battery is discharged by a load resistor of discharger. Here, energy losses happen. Therefore, in this paper, the efficient energy operation of battery is studied in the charge/discharge system based on DC ${\mu}-Grid$. A result of computer simulation shows that if in the charge/discharge system based on DC ${\mu}-Grid$, the number of discharge batteries in comparison with three charge battery sets exceeds 133%, voltage fluctuation that occurs while the grid voltage stabilizes, which makes the system fatal. Therefore, it was demonstrated that a remarkable energy saving effect could be achieved when the number of discharge battery set is maintained to be 133% in comparison with three charge battery sets.

Development of Economic based Optimal Operation Program for Microgrid (경제성 기반의 마이크로그리드 최적운영 프로그램 개발)

  • Lee, Hak-Ju;Cha, Woo-Ku;Song, Il-Kun;Yoon, Yong-Tae
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.12
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    • pp.106-114
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    • 2009
  • This paper addresses unit commitment for microgrid optimization including renewable energy sources, working under deregulated power market. As microgrid supplies both heat and electricity for consumer, operational optimization must be done to meet their demand economically. So renewable energy sources are considered to be negative load, and batteries are used as the load flattening device to raise possibly operational function. In the state of solution, the program is developed to solve out the maximum profit of microgrid using dynamic programming method. Finally, its validity is verified through case study in isolation mode and interconnected mode. The S/W will be used to operate microgrid economically after the market of microgrid is formed.

A Model to Forecast Rice Blast Disease Based on Weather Indexing (기상지수에 의한 벼도열병 예찰의 한 모델)

  • Kim Choong-Hoe;MacKenzie D. R.;Rush M. C.
    • Korean Journal Plant Pathology
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    • v.3 no.3
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    • pp.210-216
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    • 1987
  • A computer program written to predict blast occurrence based on micro climatic events was developed and tested as an on-site microcomputer in field plots in 1984 and 1985. A microcomputer unit operating on alkaline batteries; continuously monitored air temperature, leaf wetness, and relative humidity; interpreted the microclimate information in relation to rice blast development and displayed daily values (0-8) of blast units of severity (BUS). Cumulative daily BUS values (CBUS) were highly correlated with blast development on the two susceptible cultivars, M-201 and Brazos grown in field plots. When CBUS values were used to predict the logit of disease proportions, the average coefficients of determination $(R^2)$ between these two factors were 71 to $91\%$, depending on cultivar and year. This was a significant improvement when compared to 61 to $79\%$ when days were used as a predictor of logit disease severity. The ability of CBUS to predict logit disease severity was slightly less with Brazos than M-201. This is significant inasmuch as Brazos showed field resistance at mid-sea­son. The results in this study indicate that the model has the potential for future use and that the model could be improved by incorporating other variables associated with host plants and pathogen races in addition to the key environmental variables.

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