• 제목/요약/키워드: Micro reforming system

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마이크로 개질기 개발을 위한 박막형 Cu/ZnO 나노구조 촉매 합성 (Synthesis of Thin Film Type Cu/ZnO Nanostructure Catalysts for Development of Methanol Micro Reforming System)

  • 여찬혁;김연수;임연호
    • 한국수소및신에너지학회논문집
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    • 제24권3호
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    • pp.193-199
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    • 2013
  • In this work, thin film type Cu/ZnO nanostructure catalysts were fabricated by several synthetic routes in order to maximize the performance of the micro reforming system. For this work, various Cu/ZnO nanostructure catalysts could be synthesized by means of four approaches which are chemical vapor method, wet solution method and their hybrid method. The reforming performance of these as-synthetic catalysts was evaluated as compared to the conventional catalysts. Among the as-synthetic nanostructures, sphere type catalysts with specific surface of $18.6m^2/g$ showed the best performance of hydrogen production rate of 30ml/min at the feed rate of 0.2ml/min. This work will give the first insight on thin film type Cu/ZnO nanostructure catalyst for micro reforming system for hydrogen production of portable electronic systems.

PROX 반응기가 있는 50W급 세라믹재질의 소형 reformer 개발 (Development of a 50W Powered Ceramic Micro Reformer Equiped with PROX Reactor)

  • 정찬화;김우재;오정훈
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 춘계학술대회 논문집
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    • pp.225-229
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    • 2005
  • We have designed micro-fuel processor system, which consists of a steam reforming area and a PROX(preferential oxidation) area. Micro-fuel processor system generates $H_2$ rich gas from a methanol. In our experiment, we have integrated micro-fuel processor system using low temperature cofired ceramics (LTCC) process because LTCC is superior to other materials principally due to their high thermal and chemical stability, simpler fabrication processes, and lower materials cost. Therefore, we have studied and integrated micro-fuel processor system containing embedded heaters, cavities, and 3D structures of micro-channel with LTCC. Also we have optimized the LTCC process.

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LTCC를 소재로 하는 마이크로 리포머의 최적 설계에 관한 연구 ; 일체형 Reformer/PROX 반응기의 설계 및 성능평가 (A Study on the Optimum Design for LTCC Micro-Reformer: Design and performance evalution of monolith fuel reformer/PROX)

  • 정찬화;오정훈;장주희;정명기
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 추계학술대회 논문집
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    • pp.615-616
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    • 2006
  • A micro-fuel processor system integrating steam reformer and partial oxidation reactor was manufactured using low temperature cofired ceramic (LTCC). A CuO/ZnO/$Al_2O_3$ catalyst and Pt-based catalyst prepared by wet impregnation were used for steam reforming and partial oxidation, respectively. The performance of the LTCC micro-fuel processor was measured at various operating conditions such as the effect of the feed flow rate, the ratio of $H_2O/CH_3OH$, and the operating temperature on the LTCC reformer and CO clean-up system. The catalyst layer was loaded with "Fill and Dry" coating for small volume. The product gas was composed of $70\sim75%$ hydrogen, $20\sim25%$ carbon dioxide, and $1\sim2%$ carbon monoxide at $250\sim300^{\circ}C$, respectively.

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초소형 2단 연소기를 이용한 리포머 시스템에 관한 연구 (Studies on a Micro Reformer System with a Two-staged Microcombustor)

  • 김기백;이정학;권오채
    • 한국수소및신에너지학회논문집
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    • 제19권3호
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    • pp.217-225
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    • 2008
  • A new micro reformer system consisted of a micro reformer, a microcombustor and a micro evaporator was studied experimentally and computationally. In order to satisfy the primary requirements for designing the microcombustor integrated with a micro evaporator, i.e. stable burning in a small confinement and maximum heat transfer through a wall, the present microcombustor is simply cylindrical to be easily fabricated but two-staged (expanding downstream) to feasibly control ignition and stable burning. Results show that the aspect ratio and wall thickness of the microcombustor substantially affect ignition and thermal characteristics. For the optimized design conditions, a premixed microflame was easily ignited in the expanded second stage combustor, moved into the smaller first stage combustor, and finally stabilized therein. A micro reformer system integrated with a modified microcombustor based on the optimized design condition was fabricated. For a typical operating condition, the designed micro reformer system produced 22.3 sccm hydrogen (3.61 W in LHV) in an overall efficiency of 12%.

화학적 침식을 받은 콘크리트구조물의 보수기술 개발과 실용화연구 (A Study on the Development and the Practical Approach for Repair Method of RC Structures Subjected to the Chemical Attack)

  • 문한영;신동구;권영진
    • 한국구조물진단유지관리공학회 논문집
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    • 제9권2호
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    • pp.155-162
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    • 2005
  • 본 연구는 하수시설과 같은 열악한 환경에서의 구조물의 열화원인에 대하여 분석한 후 내구성회복을 위하여 항균성개질재와 무기질단면피복재의 개발을 통한 보수공법을 구축하였다. 또한 항균성개질재와 무기질단면 피복재의 복합 사용할 경우에 있어서 이들의 특성평가를 위하여 항균시험, 침투성시험, 침투후의 강도특성 및 전자현미경(SEM)을 이용하여 항균성개질재의 작용에 의한 마이크로조직의 변화특성을 평가하였다. 또한 습윤면에 부착성이 우수한 방식피복재와 항균성개질재의 복합에 의한 내구특성시험을 실시한 후 공정별 상호 부착특성을 파악하기 위하여 현장시험시공과 더불어 실구조물(하수구조물, 지하철구조물)에 적용 후 부착특성을 평가하여 개발된 보수기술에 대한 현장 적용성을 분석하였다.

원통형 고체산화물 연료전지와 마이크로 가스터빈 하이브리드 시스템의 성능해석을 위한 모델링 (Modeling for the Performance Analysis of a Tubular SOFC/MGT Hybrid Power System)

  • 송태원;손정락;김재환;김동섭;노승탁
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.2070-2075
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    • 2004
  • Performance of a solid oxide fuel cell (SOFC) can be enhanced by converting thermal energy of its high temperature exhaust gas to mechanical power using a micro gas turbine (MGT). A MGT plays also an important role to pressurize and warm up inlet gas streams of the SOFC. In this study, the influence of performance characteristics of the tubular SOFC on the hybrid power system is discussed. For this purpose, detailed heat and mass transfer with reforming and electrochemical reactions in the SOFC are mathematically modeled, and their results are reflected to the performance analysis. The analysis target is 220kWe SOFC/MGT hybrid system based on the tubular SOFC developed by Siemens-Westinghouse. Special attention is paid to the ohmic losses in the tubular SOFC counting not only current flow in radial direction, but also current flow in circumferential direction through the anode and cathode.

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