• Title/Summary/Keyword: Micro Shell

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Optical Characteristics of CdSe/ZnS Quantum Dot with Precursor Flow Rate Synthesized by using Microreactor (마이크로리액터를 이용한 전구체 유속에 따른 CdSe/ZnS 양자점의 광학특성)

  • Park, Ji Young;Jeong, Da-Woon;Ju, Won;Seo, Han Wook;Cho, Yong-Ho;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.23 no.2
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    • pp.91-94
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    • 2016
  • High-quality colloidal CdSe/ZnS (core/shell) is synthesized using a continuous microreactor. The particle size of the synthesized quantum dots (QDs) is a function of the precursor flow rate; as the precursor flow rate increases, the size of the QDs decreases and the band gap energy increases. The photoluminescence properties are found to depend strongly on the flow rate of the CdSe precursor owing to the change in the core size. In addition, a gradual shift in the maximum luminescent wave (${\lambda}_{max}$) to shorter wavelengths (blue shift) is found owing to the decrease in the QD size in accordance with the quantum confinement effect. The ZnS shell decreases the surface defect concentration of CdSe. It also lowers the thermal energy dissipation by increasing the concentration of recombination. Thus, a relatively high emission and quantum yield occur because of an increase in the optical energy emitted at equal concentration. In addition, the maximum quantum yield is derived for process conditions of 0.35 ml/min and is related to the optimum thickness of the shell material.

Fabrication and Characterization of Silica Coated Fe3O4 Nanoparticles in Reverse Micro Emulsion (마이크로에멀젼법을 이용하여 실리카 코팅된 나노 Fe3O4 분말의 합성과 분석연구)

  • Yu, Ri;Kim, Yoo-Jin;Pee, Jae-Hwan;Hwang, Kwang-Taek;Yang, Hee-Seung;Kim, Kyung-Ja
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.113-116
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    • 2010
  • The silica coated $Fe_3O_4$ nanoparticles have been synthesized using a micro-emulsion method. The $Fe_3O_4$ nanoparticles with the sizes 6 nm in diameter were synthesized by thermal decomposition method. Hydrophobic $Fe_3O_4$ nanoparticles were coated silica using surfactant and tetraethyl orthosilicated (TEOS) as a $SiO_2$ precursor. Shell thickness of silica coated $Fe_3O_4$ can be controlled (11~20 nm) through our synthetic conditions. The $Fe_3O_4$ and silica coated $Fe_3O_4$ nano powders were characterized by transmission electron microscopy (TEM), x-ray diffraction (XRD) and vortex magnetic separation (VMS).

Development of Nano-Stereolithography Process for Precise Fabrication of Three-Dimensional Micro-Devices (3차원 마이크로 디바이스 개발을 위한 나노 스테레오리소그래피 공정 개발에 관한 연구)

  • Park Sang-Hu;Lim Tae Woo;Yang Dong-Yol;Yi Shin Wook;Kong Hong-Jin;Lee Kwang-Sup
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.1
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    • pp.45-49
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    • 2006
  • A nano-stereolithography (NSL) process has been developed for the fabrication of three-dimensional (3D) micro-devices with high spatital resolution of approximately 100 nm. In the NSL process, a complicated 3D structure can be created by stacking layer-by-layer, so it does not require any sacrificial layer or any supporting structure. A laminated layer was fabricated by means of solidifying liquid-state monomers using two-photon absorption (TPA) which was induced by a femtosecond laser. When the fabrication of a 3D stacked structure was finished, unsolidified liquid resins were rinsed by ethanol to develop the fabricated structures; then, the polymerized structure was only left on the glass substrate. Through this work, several 3D microstructures such as a micro-channel, shell structures, and photonic crystals were fabricated to evaluate the possibility of the developed system.

Dynamic stability of FG-CNT-reinforced viscoelastic micro cylindrical shells resting on nonhomogeneous orthotropic viscoelastic medium subjected to harmonic temperature distribution and 2D magnetic field

  • Tohidi, H.;Hosseini-Hashemi, S.H.;Maghsoudpour, A.;Etemadi, S.
    • Wind and Structures
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    • v.25 no.2
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    • pp.131-156
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    • 2017
  • This paper deals with the dynamic stability of embedded functionally graded (FG)-carbon nanotubes (CNTs)-reinforced micro cylindrical shells. The structure is subjected to harmonic non-uniform temperature distribution and 2D magnetic field. The CNT reinforcement is either uniformly distributed or FG along the thickness direction where the effective properties of nano-composite structure are estimated through Mixture low. The viscoelastic properties of structure are captured based on the Kelvin-Voigt theory. The surrounding viscoelastic medium is considered nonhomogeneous with the spring, orthotropic shear and damper constants. The material properties of cylindrical shell and the viscoelastic medium constants are assumed temperature-dependent. The first order shear deformation theory (FSDT) or Mindlin theory in conjunction with Hamilton's principle is utilized for deriving the motion equations where the size effects are considered based on Eringen's nonlocal theory. Based on differential quadrature (DQ) and Bolotin methods, the dynamic instability region (DIR) of structure is obtained for different boundary conditions. The effects of different parameters such as volume percent and distribution type of CNTs, mode number, viscoelastic medium type, temperature, boundary conditions, magnetic field, nonlocal parameter and structural damping constant are shown on the DIR of system. Numerical results indicate that the FGX distribution of CNTs is better than other considered cases. In addition, considering structural damping of system reduces the resonance frequency.

Effects of the Tagging methods on the Growth and Survival of Abalone Juvenile, Haliotis discus hannai (전복, Haliotis discus hannai 치패의 성장과 생존에 미치는 표지의 영향)

  • Kim Bong Seok;Lee Yun Ho;Park Doo Won
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.3
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    • pp.282-288
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    • 2002
  • This study was carried out to investigate the optimum tagging method of the abalone juvenile, Haliotis discus hannai in indoor culture system from May 2000 to January2001. Tagging methods were shell drilling, copper-wire tagging at the respiratory pore and nut gluing on the shell. The attachment rates of the shell showed high in the 2- and 3 cm bolt-nut tagged groups, about over $89.5\%$, whereas shell drilling groups on the shell were about $18.5\%$. The internal coating rates tagged with bolt-nut were over $96.6\%$, while those tagged with copper wire were less than $17.1\%$. Growths in the all marked and tagged experimental groups comparing with control groups were not significantly different (p>0,05). Survivals in all tagging groups except shell drilling and nut gluing groups in the 5 cm abalone were over $95\%, Accordingly, all juvenile groups were not affected by the tagging methods in terms of the growth and survival on the abalones. Based on these results, the micro bolt-nut tagging was the most effective method in abalone.

Effects of Oyster-Shell Meal on Improving Spring Chinese Cabbage Productivity and Soil Properties (굴 패화석 비료가 배추 수량 및 토양 특성에 미치는 효과)

  • Lee, Ju-Young;Lee, Chang-Hoon;Yoon, Young-Sang;Ha, Byung-Hyun;Jang, Byoung-Choon;Lee, Ki-Sang;Lee, Do-Kyoung;Kim, Pil-Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.5
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    • pp.274-280
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    • 2005
  • Enormous amount of oyster-shell waste has been illegally disposed at oyster farm sites along the southern coast of Korea and then made a serious problem in environmental side. To increase the consumption of oyster shell meal as a soil amendment, the effects of oyster shell meal on soil properties and spring Chinese cabbage productivity were evaluated in silt loam soil to which 0, 4, 8, 12 and $16Mg\;ha^{-1}$ of oyster-shell meal fertilizer were added. Hydrated lime treatment ($2Mg\;ha^{-1}$) was selected as a control. Oyster-shell meal fertilizer, which made by a simple crushing and has high alkalinity as a calcium materials, had significant effects on neutralizing acid soil and on supplying calcium element. Spring Chinese cabbage yields increased with shell meal application. Plant uptakes of macro-nutrients such as P and C, and micro-nutrient such as B were significantly increased by oyster-shell meal application and then contributed to promote Chinese cabbage growth. The highest yield was achieved following the addition of $8Mg\;ha^{-1}$ shell meal application, and the same yield with that in lime treatment was at the $4Mg\;ha^{-1}$. Oyster-shell meal had more substantial effect on suppling calcium and on improving soil pH than that of lime. In conclusion, oyster shell meal fertilizer could be a good supplement to other inorganic soil amendments to improve nutrient balances in upland soils.

Synthesis and Biodistribution of Cat's Eye-shaped [57Co]CoO@SiO2 Nanoshell Aqueous Colloids for Single Photon Emission Computed Tomography (SPECT) Imaging Agent

  • Kwon, Minjae;Park, Jeong Hoon;Jang, Beom-Su;Jung, Hyun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2367-2370
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    • 2014
  • "Cat's eye"-shaped $[^{57}Co]CoO@SiO_2$ core-shell nanostructure was prepared by the reverse microemulsion method combined with radioisotope technique to investigate a potential imaging agent for a single photon emission computed tomography (SPECT) in nuclear medicine. The core cobalt oxide nanorods were obtained by thermal decomposition of $Co-(oleate)_2$ precursor from radio isotope Co-57 containing cobalt chloride and sodium oleate. The $SiO_2$ coating on the surface of the core cobalt oxide nanorods was produced by hydrolysis and a condensation reaction of tetraethylorthosilicate (TEOS) in the water phase of the reverse microemulsion system. In vivo test, micro SPECT image was acquired with nude mice after 30 min of intravenous injection of $[^{57}Co]CoO@SiO_2$ core-shell nanostructure.

Effects of Muscle Extracts of Fish and Shell-fish on the Oxidation of Methyl Linoleate (어패육추출물(魚貝肉抽出物)이 지질산화(脂質酸化)에 미치는 영향(影響))

  • Lee, Kang-Ho;Jeong, In-Hak;Lee, Jong-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.13 no.4
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    • pp.444-450
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    • 1984
  • Effects of muscle extracts of five species of fish and shell-fish, mackerel, jack mackerel, yellow corvenia, shrimp and baby-neck clam, on lipid oxidation were investigated using a model system consisting of methyl linoleate absorbed in micro crystalline cellulose and extracts of fishes. Ethanol extracts of both mackerel and jack mackerel apparently showed inhibitory effect on the oxidation of methyl linoleate, while the extract of yellow corvenia, and baby-neck clam showed a slight catalyzed effect on contrary. The ethanol extract of shrimp, however, revealed no effect on the oxidation of methyl linoleate. When the ethanol extracts were dialyzed, the outer fractions of dark fleshed fish had a strong inhibitory effect on the oxidation of methyl linoleate, while the inner fractions did not. The outer fraction of yellow corvenia showed catalyzed effect, but the inner fraction inhibited the oxidation slightly. The outer fraction of shrimp had a strong inhibitory action, but the inner fraction showed no effect. The methanol-water fraction of chloroform-methanol extract of shrimp showed a quite strong inhibitory effect on the oxidation, whereas that of four other samples did the same levels of effect as ethanol extracts.

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Deformation Analysis of Miniature Metal Bellows Charged Nitrogen for Temperature Change to Cryogenic Condition (극저온까지 온도변화에 따른 질소 충전 소형 금속 벨로우즈의 변형 해석)

  • Lee, Seung-Ha;Lee, Tae-Won
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.10
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    • pp.81-88
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    • 2009
  • Bellows is used to control temperature of a Joule-Thomson micro cryocooler. It is made of Nickelcobalt alloy that retains mechanical properties from cryogenic temperature to temperature of 570K. The geometry of bellows is an axisymmetric shell and Nitrogen with high pressure was charged at temperature of 293K. During cool-down process, the pressure and volume of Nitrogen are changed and must be satisfied with state equation. At cryogenic temperature, Nitrogen can exist as a part liquid and part vapor. Pressure-density-temperature behavior under this vaporliquid phase equilibrium is closely given by the Modified-Benedict-Webb-Rubin(MBWR) state equation. To evaluate deformation of bellows for temperature change, the numerical calculation of the volume within bellows and finite element analysis of bellows under internal pressure were iteratively performed until MBWR state equation is satisfied. The numerical results show that deformation of the bellows can be analyzed by the present method in a wide range of temperature including cryogenic temperature.

In vitro Estimation of The Hounsfield Units and The Volume and Void of Canine Struvite Stones as Predictors of Fragility in Extracorporeal Shock Wave Lithotripsy

  • Wang, Ji-hwan;Hwang, Tae-sung;Jung, Dong-in;Yeon, Seong-chan;Lee, Hee-chun
    • Journal of Veterinary Clinics
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    • v.34 no.3
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    • pp.178-184
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    • 2017
  • The aim of this study was to determine whether Hounsfield units (HUs), volume, and various void parameters can predict stone fragility in extracorporeal shock wave lithotripsy (ESWL). HU, volume, porosity, number of voids/stone volume, and void distribution of 30 struvite stones were estimated using helical computed tomography (CT) and micro-CT. The number of shock waves necessary for full fragmentation was accepted as a measure of the stone fragility in ESWL. The correlations between the number of shock waves and the HU, volume, porosity, and number of voids/stone volume were examined. The number of shock waves of the two groups according to the void distribution was also compared. Stone volume correlated with the number of shock waves. Shell-patterned struvite stones were significantly less susceptible to fragmentation in ESWL than non-shell-patterned struvite stones. Stone volume and void distribution may be predictors of the outcome of ESWL treatment.