• Journal of Powder Materials
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• v.23 no.1
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• pp.15-20
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• 2016

Niobium is one of the most important and rarest metals, and is used in the electronic and energy industries. However, it's extremely high melting point and oxygen affinity limits the manufacture of Nb coating materials. Here, a Nb coating material is manufactured using a kinetic spray process followed by hot isotactic pressing to improve its properties. OM (optical microscope), XRD (X-ray diffraction), SEM (scanning electron microscopy), and Vickers hardness and EPMA (electron probe micro analyzer) tests are employed to investigate the macroscopic properties of the manufactured Nb materials. The powder used to manufacture the material has angular-shaped particles with an average particle size of $23.8{\mu}m$. The porosity and hardness of the manufactured Nb material are 0.18% and 221 Hv, respectively. Additional HIP is applied to the manufactured Nb material for 4 h under an Ar atmosphere after which the porosity decreases to 0.08% and the hardness increases to 253 Hv. Phase analysis after the HIP shows the presence of only pure Nb. The study also discusses the possibility of using the manufactured Nb material as a sputtering target.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.3
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• pp.46-56
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• 1998

The objective of this study was to investigate the relationship between water vapor diffusion properties and the pore structure of paper. Gas-phase molecular diffusivity of water vapor through pores was determined based on the kinetic theory of gas. A mathematical model was derived to characterize the dimensional changes of the pore caused by the fiber-swelling mechanism. A modified-Fickean diffusion model was designed to simulate the water-vapor diffusion phenomena in porous paper web. Structural characterisocs of paper pores including the tortuosity and the shape factor was studied on a theoretical basis of Knudsen flow diffusion. Results are summarized as follows: 1. The theoretical water vapor diffusivity in gas-phase was 0.092$cm^2$ /min, 2. Porosity was inversely proportional to the degree of wet-swelling of paper, 3. Solid-phase water-diffusivity of fiber was 1.2 $ \times 10^{-5}cm^2/min$, 4. Modified diffusion model was fairly consistent to the experimental data (from part I), and 5. The Fickean pore tortuosity, ranging from 1,000 to 2,500, was in inverse proportion to the porosity of paper, and the Knudsen shape factor and length-angle factor for micro-pores in paper were 0.5~3.5 and about 340, respectively.

• Journal of Veterinary Clinics
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• v.34 no.3
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• pp.178-184
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• 2017

The aim of this study was to determine whether Hounsfield units (HUs), volume, and various void parameters can predict stone fragility in extracorporeal shock wave lithotripsy (ESWL). HU, volume, porosity, number of voids/stone volume, and void distribution of 30 struvite stones were estimated using helical computed tomography (CT) and micro-CT. The number of shock waves necessary for full fragmentation was accepted as a measure of the stone fragility in ESWL. The correlations between the number of shock waves and the HU, volume, porosity, and number of voids/stone volume were examined. The number of shock waves of the two groups according to the void distribution was also compared. Stone volume correlated with the number of shock waves. Shell-patterned struvite stones were significantly less susceptible to fragmentation in ESWL than non-shell-patterned struvite stones. Stone volume and void distribution may be predictors of the outcome of ESWL treatment.

• International Journal of Concrete Structures and Materials
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• v.11 no.1
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• pp.99-113
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• 2017

The effects of different lightweight functional fillers on the properties of cement-based composites are investigated in this study. The fillers include fly ash cenospheres (FACs) and glass micro-spheres (GMS15 and GMS38) in various proportions. The developed composites were tested for compressive, flexural and tensile strengths at 10 and 28-day ages. The results indicated that both FACs and GMS38 are excellent candidates for producing strong lightweight composites. However, incorporation of GMS15 resulted in much lower specific strength values (only up to $13.64kPa/kg\;m^3$) due to its thinner shell thickness and lower isostatic crushing strength value (2.07 MPa). Microstructural analyses further revealed that GMS38 and GMS15 were better suited for thermal insulating applications. However, higher weight fraction of the fillers in composites leads to increased porosity which might be detrimental to their strength development.

• Computers and Concrete
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• v.6 no.1
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• pp.1-18
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• 2009

Chloride diffusivity of concrete is a crucial material parameter for service life determination and durability designing of marine concrete. Many research works on this issue have been conducted, varying from empirical solutions obtained experimentally to image analysis, based on multi-scale modeling. One of the simple approaches is to express the chloride diffusivity of concrete by a multi-factor function, however, the influences of various factors on the chloride diffusivity are ambiguous. Furthermore, the majority of these research works have not dealt with the carbonation process of concrete, although this process affects the chloride diffusivity of concrete significantly. The purpose of this study is to establish a simple approach to calculate the chloride diffusivity of (non)carbonated concrete. The chloride diffusivity of concrete should be defined, based on engineering and scientific knowledge of cement and concrete materials. In this paper, a lot of parameters affecting the chloride diffusivity, such as the diffusivity in pore solution, tortuosity, micro-structural properties of hardened cement paste, volumetric portion of aggregate, are taken into consideration in the calculation of the chloride diffusivity of noncarbonated concrete. For carbonated concrete, reduced porosity due to carbonation is calculated and used for calculating the chloride diffusivity. The results are compared with experimental data and previous research works.

• Steel and Composite Structures
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• v.44 no.3
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• pp.371-388
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• 2022

The present study tackles the problem of forced vibration of imperfect axially functionally graded shell structure with truncated conical geometry. The linear and nonlinear large-deflection of the structure are considered in the mathematical formulation using von-Kármán models. Modified coupled stress method and principle of minimum virtual work are employed in the modeling to obtain the final governing equations. In addition, formulations of classical elasticity theory are also presented. Different functions, including the linear, convex, and exponential cross-section shapes, are considered in the grading material modeling along the thickness direction. The grading properties of the material are a direct result of the porosity change in the thickness direction. Vibration responses of the structure are calculated using the semi-analytical method of a couple of homotopy perturbation methods (HPM) and the generalized differential quadrature method (GDQM). Contradicting effects of small-scale, porosity, and volume fraction parameters on the nonlinear amplitude, frequency ratio, dynamic deflection, resonance frequency, and natural frequency are observed for shell structure under various boundary conditions.

• Steel and Composite Structures
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• v.45 no.5
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• pp.621-640
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• 2022

In the present article, the vibration response of a geometrically imperfect bi-directional functionally graded plate (2D-FGP) with geometric discontinuities and micro-structural defects (porosities) has been investigated. A porosity model has been developed to incorporate the effective material properties of the bi-directional FGP which varies in two directions i.e. along the axial and transverse direction. The geometric discontinuity is also introduced in the plate in the form of a circular cut-out at the center of the plate. The structural kinematic formulation is based on the non-polynomial trigonometric higher-order shear deformation theory (HSDT). Finite element formulation is done using C° continuous Lagrangian quadrilateral four-noded element with seven degrees of freedom per node. The equations of motion have been derived using a variational approach. Convergence and validation studies have been documented to confirm the accuracy and efficiency of the present formulation. A detailed investigation study has been done to evaluate the influence of the circular cut-out, geometric imperfection, porosity inclusions, partial supports, volume fraction indexes (along with the thickness and length), and geometrical configurations on the vibration response of 2D-FGP. It is concluded that after a particular cut-out dimension, the vibration response of the 2D FGP exhibits non-monotonic behavior.

• Membrane Journal
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• v.17 no.3
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• pp.233-243
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• 2007

In this study, a separate. which is a microporous membrane based on poly(vinylidene fluoride)(PVdF) was prepared by phase inversion method. Being prepared by dissolving the PVdF in the N,N'-dimethylformamide(DMF) with mechanical stirring, the homogenous casting solution was cast onto a clean glass plate. Pore size and porosity of the membranes were controlled by changing preparation condition. The highest porosity of the membrane was 78.6%. The mechanical property of the membrane was determined by using an universal testing machine(UTM). The morphology of the membrane was investigated by scanning electron microscopy(SEM). The cross-section of the membrane shows sponge-like small micro-pores.

• Structural Engineering and Mechanics
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• v.72 no.1
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• pp.113-129
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• 2019

A four-variable shear deformation refined plate theory has been proposed for dynamic characteristics of smart plates made of porous magneto-electro-elastic functionally graded (MEE-FG) materials with various boundary conditions by using an analytical method. Magneto-electro-elastic properties of FGM plate are supposed to vary through the thickness direction and are estimated through the modified power-law rule in which the porosities with even and uneven type are approximated. Pores possibly occur inside functionally graded materials (FGMs) due the result of technical problems that lead to creation of micro-voids in these materials. The variation of pores along the thickness direction influences the mechanical properties. The governing differential equations and boundary conditions of embedded porous FGM plate under magneto-electrical field are derived through Hamilton's principle based on a four-variable tangential-exponential refined theory which avoids the use of shear correction factors. An analytical solution procedure is used to achieve the natural frequencies of embedded porous FG plate supposed to magneto-electrical field with various boundary condition. A parametric study is led to carry out the effects of material graduation exponent, coefficient of porosity, magnetic potential, electric voltage, elastic foundation parameters, various boundary conditions and plate side-to-thickness ratio on natural frequencies of the porous MEE-FG plate. It is concluded that these parameters play significant roles on the dynamic behavior of porous MEE-FG plates. Presented numerical results can serve as benchmarks for future analyses of MEE-FG plates with porosity phases.

• Korean Journal of Metals and Materials
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• v.46 no.5
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• pp.321-327
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• 2008

Cu based amorphous ($Cu_{54}Zr_{22}Ti_{18}Ni_6$) coating was produced by cold spraying as a new fabrication process. The microstructure and macroscopic properties of amorphous coating layer was investigated and compared with those of cold sprayed pure Cu coating. Amorphous powders were prepared by gas atomization and Al 6061 was used as the substrate plate. X-ray diffraction results showed that Cu based amorphous powder could be successfully deposited by cold spraying without any crystallization. The Cu based amorphous coating layer ($300{\sim}400{\mu}m$ thickness) contained 4.87% porosity. The hardness of Cu based amorphous coating represented $412.8H_v$, which was correspond to 68% of the hardness of injection casted bulk amorphous material. The wear resistance of Cu based amorphous coating was found to be three times higher than that of pure Cu coating. The 3-point bending test results showed that the adhesion strength of Cu based amorphous coating layer was higher than that pure Cu coating. It was also observed that hard Cu base amorphous particle could easily deform soft substrate by particle collisions and thus generated strong adhesion between coating and substrate. However, the amorphous coating layer unexpectedly represented lower corrosion resistance than pure Cu coating, which might be resulted from the higher content of porosity in the cold sprayed amorphous coating.