• 제목/요약/키워드: Mg-doped

검색결과 344건 처리시간 0.028초

$SrAl_{12}O_{19}:Mn^{4+}$ 적색 형광체의 플럭스와 Mn 농도에 따른 영향 및 발광특성 (Photoluminescence properties of $SrAl_{12}O_{19}:Mn^{4+}$ red phosphor depending on Mn concentration and fluxes)

  • 박우정;정몽권;문지욱;윤대호
    • 한국결정성장학회지
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    • 제17권4호
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    • pp.156-159
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    • 2007
  • 본 연구에서는 장파장 UV 영역하에서 비교적 우수한 발광강도를 가지는 적색 형광체를 얻기 위하여 고상법으로 합성하여 발광특성을 관찰하였다. $SrAl_{12}O_{19}:Mn^{4+}$ 적색 형광체의 발광강도는 $Mn^{4+}$$^2E\to^4A_2$ 천이 때문에 643, 656, 666, 671 nm에서 4개의 sharp한 peak이 $600{\sim}700 nm $의 영역에서 발생하였으며, 여기 스펙트럼은 $250{\sim}550 nm$ 넓은 영역에서 338, 398, 468nm 3개의 peak이 발생하였다. 또한 $SrAl_{12}O_{19}:Mn^{4+}$에 0.67mol% MgO를 함유한 $SrAl_{12}O_{19}:Mn^{4+}$의 상대적인 발광강도는 $SrAl_{12}O_{19}:Mn^{4+}$ 보다 약 30% 정도 증가하였는데, 이러한 원인은 MgO가 첨가되어 $Al_2O_3$ 부분에 대체되어진 것으로 사료된다. 또한, 발광강도를 향상시키기 위하여 0.67mol% MgO를 함유한 $SrAl_{12}O_{19}:Mn^{4+}$ 시료에 $CaF_2$를 첨가하였다. 0.67mol% $CaF_2$와 0.67mol% MgO를 함유한 $SrAl_{12}O_{19}:Mn^{4+}$의 656nm에서의 상대적인 발광강도는 융제를 첨가하지 않은 $SrAl_{12}O_{19}:Mn^{4+}$보다 약 48% 이상 증가하였다.

Zn가 첨가된 GaN 미세 분말의 합성에 관하여 (On the Synthesis of Zn-doped GaN Fine-Powders)

  • 이재범;이종원;박인용;김선태
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
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    • pp.95-95
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    • 2003
  • 최근, 대면적 평판표시소자 제작을 위한 전기발광 (EL; electroluminescence)소자용 소재로서 GaN 분말을 적용하고자 하는 연구가 진행되고 있다. 이와 같이 GaN 분말을 EL 소재로 사용하기 위해서는 원하는 파장의 빛을 발광할 수 있도록 특정의 불순물을 첨가하여야 할 필요가 있다. Mg이 첨가된 GaN 분말의 합성과 특성에 대한 연구가 있었으며, 희토류 원소가 첨가된 GaN 분말의 특성이 보고된바 있다. 본 논문에서는 GaOOH 분말을 출발물질로 채택하여 Zn가 첨가된 GaN 분말을 합성하고 광학적인 특성을 조사하였다. Zn가 첨가된 GaN 분말을 합성하기 위하여, 우선 CaOOH 분말 1g과 일정량의 ZnO 또는 Zn(NO$_3$)$_3$를 함께 섞어 유발에서 습식 혼합한 후 건조시켰다. Ga에 대한 Zn의 몰 비는 0.1부터 30 까지 변화시켰다. 반응온도는 900~110$0^{\circ}C$의 범위에서 변화시켰고, 반응시간은 1~4시간 범위에서 변화시켰으며, NH$_3$의 유량은 400 sccm으로 하였다. X선 회절분석장치를 사용하여 결정구조를 확인하였고, Zn의 첨가에 따른 광학적 특성은 10 K의 온도에서 광루미네센스(PL; photoluminescence)를 측정하여 평가하였다.

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Ohmic contacts to p-type GaN for high brightness LED applications

  • Seong, Tae-Yeon
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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    • pp.23-23
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    • 2003
  • GaN-related semiconductors are of great technological importance for the fabrication of optoelectronic devices, such as blue and ultra violet light emitting diodes (LEDs), laser diodes, and photo-detectors. One of the most important applications of GaN-based LEDs is solid-state lighting, which could replace incandescent bulbs and ultimately fluorescent lamps. For solid-state lighting applications, the achievement of high extraction efficiency in LED structures is essential. For flip-chip LEDs (FCLEDS), the formation of low resistance and high reflective p-GaN contact is crucial. So far, a wide variety of different methods have been employed to improve the ohmic properties of p-type contacts to GaN. For example, surface treatments using different chemical solutions have been successfully used to produce high-quality ohmic contacts, Metallization schemes, such as Ta/Ti contacts to p-GaN, were also investigated. For these contacts, the removal of hydrogen atoms from the Mg atoms doped n the GaN was argued to be responsible for low contact resistances.

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Cyanine 및 Merocyanine색소의 분광특성 및 광전특성에 대한 전자구조의 상관관계(II) (Interrelation on the Electronic Structure and Spectroscopic-Photoeletric Characteristics in the Cyanine and Merocyanine Dye(II))

  • 손세모
    • 한국인쇄학회지
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    • 제13권2호
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    • pp.1-17
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    • 1995
  • Organic thin film electroluminescene devices were fabricated using by molecularly doped method with N,N`-diphenyl-N,N`-bis(3-methylphenyl)-1,1`-biphenyl-4,4`-diamine(TPD) as a hole transport material, tris(8-quinolinolate) aluminium(III)(Alq3) as an emitting and electron transport agent, fluorescent squarylium(SQ) dye as a dopant, and poly(methylmethacrylate) as polymer materials. A cell structure of ITO/TPD-PMMA/Alq3-dopant/Mg was employed. The EL spectrum covers a wide range of the visible region and orange emission os observed. Two peaks at 520 and 660nm correspond to the emissions 620nm Alq3 and SQ dye, respectively.

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PMN-PT-PZ 계 세라믹스를 이용한 압전 발음체 설계 (Design of the Piezoelectric Sounder Using the PMN-PT-PZ)

  • 고영준;김현철;남효덕;장호경;우홍
    • 한국전기전자재료학회논문지
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    • 제14권1호
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    • pp.12-19
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    • 2001
  • In this study, the physical properties of the piezoelectric sounder with metal-piezoelectric ceramics were analyzed. The dielectric and piezoeletric properties of 0.5wt% MnO$_2$ and NiO doped 0.1Pb(Mg$\_$1/3/Nb$\_$2/3/)O$_3$-0.45PbTiO$_3$-0.45PbZrO$_3$ ceramics were investigated aiming at acoustic transducer applications. The acoustic characteristics of a thin circular disc-type with metal-piezoceramics have been investigated. Also, the acoustic characteristics for the geometrical form of case were investigated. The piezoelectric sounder with 200kHz resonant frequency and 20kHz bandwidth was designed by considering the sharp directivity and the sound pressure.

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알콕사이드로부터 알루미나 미분말의 합성과 그 소결특성 (Preparation and Sintering Behavior of Alumina Powders Synthesized from Aluminum Alkoxide)

  • 김창은;이종혁;이해욱
    • 한국세라믹학회지
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    • 제28권7호
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    • pp.568-576
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    • 1991
  • The powder characterization and sintering behavior of alkoxide-derived alumina powders prepared by esterification were investigated. The dried powders were calcined at 700$^{\circ}C$, 900$^{\circ}C$, 1080$^{\circ}C$, 1170$^{\circ}C$ for 1 h. and the resulting crystalline forms were amorphous, {{{{ gamma }} phase, {{{{ theta }}+{{{{ alpha }} phase, and {{{{ alpha }} phase, respectively. The sinterability was best in the case of being calcined at 1170$^{\circ}C$. It was most effective to disperse sintering additive in the initial stage from which acetate was formed. At 1600$^{\circ}C$ for 4 h, 98.5% of relative density was obtained when MgO and Fe2O3 were simultaneously doped, and dense sintered body whose density was near theoretical value was obtained when heating schedule was controlled.

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PMN-PT-PZ계를 이용한 압전소자의 설계 및 음향특성 (Design and Acoustic Properties of Piezoelectric Device with the PMN-PT-PZ System)

  • 고영준;서희돈;남효덕;장호경
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 영호남학술대회 논문집
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    • pp.283-286
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    • 2000
  • In this study, the acoustic transducer of a thin circular disc-type with PZT/Metal was manufactured. The piezoelectric transducer with 200kHz resonance frequency was designed by considering the sharp directivity and the sound pressure. The dielectric and piezoelectric properties of 0.5 weight percent $MnO_2$ and NiO doped $0.1Pb(Mg_{1/3}Nb_{2/3})O_3-0.45PbTiO_3-0.42PbZrO_3$ ceramics were investigated aiming at acoustic transducer applications. Also, the acoustic characteristics of a thin circular disc-type with metal-piezoceramics have been Investigated.

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Structural studies of $Mn^+$ implanted GaN film

  • Shi, Y.;Lin, L.;Jiang, C.Z.;Fan, X.J.
    • 한국진공학회지
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    • 제12권S1호
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    • pp.56-59
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    • 2003
  • Wurtzite GaN films are grown by low-pressure MOCVD on (0001)-plane sapphire substrates. The GaN films have a total thickness of 4 $\mu$m with a surface Mg-doped p-type layer, which has a thickness of 0.5 $\mu$m. 90k eV $Mn^{+}$ ions are implanted into the GaN films at room temperature with doses ranging from $1 \times10^{15}$ to $1 \times 10^{16}\textrm{cm}^{-2}$. After an annealing step at $770^{\circ}C$ in flowing $N_2$, the structural characteristics of the $Mn^{+}$ implanted GaN films are studied by X-ray diffraction (XRD), Rutherford backscattering spectrometry (RBS) and atomic force microscopy (AFM). The structural and morphological changes brought about by $Mn^{+}$ implantation and annealing are characterized.