• Title/Summary/Keyword: Mg-Zn-(Cu) alloys

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Effects of Zr, B and P Additions the Grain Refinement of CuZn36 Alloys. (CuZn36 합금의 입자 미세화에 미치는 Zr, B, P 첨가의 영향)

  • Kim, Chung-Keun;Lee, Dong-Woo
    • Journal of Korea Foundry Society
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    • v.13 no.2
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    • pp.168-174
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    • 1993
  • It has been known that the grain refinement of Cu base alloys greatly improved mechanical properties, castability, workability and hot shortness resistance etc. In this study CuZr50, CuP7, CuFe7, CuMg10 binary alloys were added as grain refiners in CuZn36 alloy. The alloys melted in vacuum and controlled in mixed gas conditions and casted at $1050^{\circ}C$. Zr-P-X compound has significantly grain refined but oxygen has been found detrimental to grain refinement. In the case of Zr /B ratio below 4, B acted as grain growth element in this alloy.

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Effect of Zn additions on the Mechanical Properties of High Strength Al-Si-Mg-Cu alloys (Zn 첨가량에 따른 Al-Si-Mg-Cu계 합금의 미세조직 및 기계적 특성변화)

  • Hwang, Soo-Been;Kim, Byung-Joo;Jung, Sung-Su;Kim, Dong-Gyu;Lee, Young-Cheol
    • Journal of Korea Foundry Society
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    • v.39 no.3
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    • pp.33-43
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    • 2019
  • In this study, the effects of Zn additions on the mechanical properties of Al-Si-Mg-Cu alloys were investigated by increasing the amount of Zn up to 8wt.%. As the Zn content was increased up to 6 wt.%, the yield strength and elongation changed linearly without any significant changes in the size and shape of the main reinforcement phase. However, it was confirmed by SEM observation that the Mg-Zn phase formed between the reinforcement phases when the amount of Zn added exceeded 7wt.%. A Mg-Zn intermetallic compound formed between the $Mg_2Si$ phase, becoming a crack initiation point under stress. Thus, the formation of the Mg-Zn phase may cause a sharp decrease in the elongation when Zn at levels exceeding 7 wt.%. It was also found that the matrix became more brittle with increasing the Zn content. From these results, it can be concluded that the formation of the Mg-Zn intermetallic compound and the brittle characteristics of the matrix are the main causes of the remarkable changes in the mechanical properties of this alloy system

Grain Refining and Age Hardening of Mg-Zn Alloys by Addition of Cu and Si (Cu 및 Si첨가에 의한 Mg-Zn합금계의 입자미세화 및 시효경화)

  • Hwang, Jin-Hwan;Nam, Tae-Hyeon;An, In-Seop;Kim, Yu-Gyeong;Heo, Gyeong-Cheol;Heo, Bo-Yeong
    • Korean Journal of Materials Research
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    • v.5 no.6
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    • pp.682-689
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    • 1995
  • In order to refine the grain size of Mg-Zn alloy 0.5 to 6wt.%Cu or Si elements were added. Alloy ingot was made under vacuum atmosphere of 4 ${\times}$ 10$\^$-4/ Torr in the quartz tube coated by BN. Grain size and hardness were measured after solution treatment for 8 hours at 435$^{\circ}C$. Optimal condition for grain size refining effect was obtained at the minimum composition of 2wt.%Cu or 1.5wt.%Si addition to Mg-6wt%Zn alloy. Age hardening behavior was experimented at the optimal compositions of the Mg-6wt.%Zn, Mg-6wt.% Zn-2wt.%Cu and Mg-6wt.% Zn-1.5wt.%Si. The hardness increment due to fine grain size was higher at the Mg-Zn-Cu alloy system, but that due to age hardening was higher at the Mg-Zn-Si alloy system.

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Influence of Cu and Zn Contents on the Properties of Al-Fe-Cu-Mg Based Casting Alloys (Cu 및 Mg 첨가량에 따른 Al-Fe-Cu-Mg계 주조합금의 특성변화)

  • Kim, Jeong-Min;Kim, Nam-Hoon;Shin, Je-Sik;Kim, Ki-Tae;Ko, Se-Hyun
    • Journal of Korea Foundry Society
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    • v.34 no.4
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    • pp.130-135
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    • 2014
  • Efforts have been made to develop new silicon-free aluminum casting alloys that possess high electrical and thermal conductivity. In this research Al-Fe-Cu-Mg alloys with various Cu and Mg contents were investigated for their various properties. As the Cu or Mg content was increased, the electrical conductivity gradually decreased, while the tensile strength of the Al-Fe-Cu-Mg alloy tended to be improved. It was found that fluidity was generally inversely proportional to the Cu content, but the alloys containing 1%Mg showed considerably low fluidity, regardless of the Cu content.

Effect of Sc Addition on Microstructure, Electrical Conductivity, Thermal Conductivity and Mechanical Properties of Al-2Zn-1Cu-0.3Mg Based Alloy (Al-2Zn-1Cu-0.3Mg합금의 Sc첨가에 따른 미세조직, 전기전도도, 열전도도 및 기계적 특성 변화)

  • Na, Sang-Su;Kim, Yong-Ho;Son, Hyeon-Taek;Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.30 no.10
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    • pp.542-549
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    • 2020
  • Effects of Sc addition on microstructure, electrical conductivity, thermal conductivity and mechanical properties of the as-cast and as-extruded Al-2Zn-1Cu-0.3Mg-xSc (x = 0, 0.25, 0.5 wt%) alloys are investigated. The average grain size of the as-cast Al-2Zn-1Cu-0.3Mg alloy is 2,334 ㎛; however, this value drops to 914 and 529 ㎛ with addition of Sc element at 0.25 wt% and 0.5 wt%, respectively. This grain refinement is due to primary Al3Sc phase forming during solidification. The as-extruded Al-2Zn-1Cu-0.3Mg alloy has a recrystallization structure consisting of almost equiaxed grains. However, the as-extruded Sc-containing alloys consist of grains that are extremely elongated in the extrusion direction. In addition, it is found that the proportion of low-angle grain boundaries below 15 degree is dominant. This is because the addition of Sc results in the formation of coherent and nano-scale Al3Sc phases during hot extrusion, inhibiting the process of recrystallization and improving the strength by pinning of dislocations and the formation of subgrain boundaries. The maximum values of the yield and tensile strength are 126 MPa and 215 MPa for the as-extruded Al-2Zn-1Cu-0.3Mg-0.25Sc alloy, respectively. The increase in strength is probably due to the existence of nano-scale Al3Sc precipitates and dense Al2Cu phases. Thermal conductivity of the as-cast Al-2Zn-1Cu-0.3Mg-xSc alloy is reduced to 204, 187 and 183 W/MK by additions of elemental Sc of 0, 0.25 and 0.5 wt%, respectively. On the other hand, the thermal conductivity of the as-extruded Al-2Zn-1Cu-0.3Mg-xSc alloy is about 200 W/Mk regardless of the content of Sc. This is because of the formation of coherent Al3Sc phase, which decreases Sc content and causes extremely high electrical resistivity.

A Study on the Effects of Ag Addition on the Mechanical Properties and Microstructure in Atomized Al-Zn-Mg Alloys (분무 Al-Zn-Mg 합금의 기계적 성질 및 미세조직에 미치는 Ag 첨가의 영향)

  • Shin, Hee-Sang;Jeong, Tae-Ho;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.19 no.6
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    • pp.456-465
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    • 1999
  • The overall objective of this study is to investigate the effect of Ag addition on the mechanical properties and microstructure of rapid solidified 7000 Al series alloys. Al-Zn-Mg-Cu alloys with small amounts of Ag was fabricated into the powder by gas atomization. The powder was extruded after the cold compaction and degassing and then followed by T6 heat treatment. Microstructure observation, phase analysis, room and high temperature tensile test and hardness test were pursued. The tensile strength and hardness of Ag-added alloy after heat treatment was increased with increasing Ag contents. However, the elongation of extruded alloys was not increased as much as to be expected. The reason of this result seems to be related to $the{\Omega}$ phase, which contribute to the high temperature strength stability of Al-Cu-Zn alloys through the formation of eutectoid with Ag addition.

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RRA Treatment of Semi-Solid Al-Zn-Mg-Cu Al Alloy Fabricated by Cooling Plate (냉각판으로 제조된 Al-Zn-Mg-Cu계 반응고 알루미늄 합금의 RRA 처리)

  • Kim, Dae-Hwan;Shim, Sung-Yong;Kim, Young-Hwa;Lim, Su-Gun
    • Journal of Korea Foundry Society
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    • v.29 no.6
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    • pp.265-269
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    • 2009
  • The optimum RRA heat treating conditions and SCC (stress corrosion cracking) resistance of semi-solid Al-Zn-Mg-Cu alloy fabricated by inclined cooling plate were compared with those of conventional mould cast alloys. The non-stirring method characterized by using a cooling plate can effectively eliminate dendritic structure and form a fine globular semisolid microstructure in as-cast Al-Zn-Mg-Cu alloy and the SCC resistance of semi-solid Al-Zn-Mg-Cu alloy was higher than that of conventional mold cast alloy. Also, after retrogressed treatment at RRA heat treatment of semi-solid Al-Zn-Mg-Cu alloy, retrogressed treatment time has increased more than 10 minutes at $180^{\circ}C$ to recovery the T6 heat treatment strength.

Microstructural changes of Al-Zn-Mg-Cu alloys containing Sc during hot extrusion and post heat treatments (Sc을 첨가한 Al-Zn-Mg-Cu 합금 압출재의 열처리에 따른 미세조직 변화)

  • 이혜경;서동우;이상용;이경환
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.10a
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    • pp.281-284
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    • 2003
  • The microstructural changes of Al-Zn-Mg-Cu alloy containing Sc during hot extrusion and post heat treatment is investigated. Two kinds of Al-Sc alloys with different alloying elements (B1, B2) are hot extruded to make I-shape bars at 380$^{\circ}C$, then the bars are solution treated at 480$^{\circ}C$ for 2hrs followed by artificial aging at 120$^{\circ}C$ for 24hrs. The interior microstructure of as extruded bar consists of elongated grains, however, fine equiaxed grains are mainly observed around surface. The microstructural gradient suggests that different restoration process can proceed during the hot extrusion. For B1 and B2, different grain growth behaviors are found around the surface during the post heat treatment. Rapid grain growth behavior around the surface is discussed related with the crystallographic orientation of the grain.

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The Effects of AI-Alloying Elements on the Melt Oxidation - III. Oxidation Behavior of Pentad Alloy- (AI 합금의 원소가 용융산화에 미치는 영향 -lll. 오원계 합금의 산화거동-)

  • Ha, Yong-Soo;Kim, Chul-Soo;Kang, Chung-Yun;Kim, Il-Soo;Cho, Chang-Hyun
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.672-677
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    • 1998
  • The following work examines the growth rate and microstructure of the $AI_2O_3$-composite formation by melt oxdation of pentad AI-alloys. The I weight % of each metal elements Cu and Ni were added to AI-IMg-3Si-3Zn and AI-IMg- 3Si-5Zn alloys. The diffenent pentad AI-alloys were oxidized 20 hours long at 1373K and 1473K. The oxidation rates were determined by observing the weight gain. The macro- and microstructure of formed oxide layer were examined by optical microscopy. The AI-IMg-3Si-5Zn-lCu alloy revealed the best oxidation behavior, but formedoxide layer was inhomogeneous.The oxidation rate were accelerated, and the uniform growth of the oxide layer with fine microstructure were obtained by putting a thin layer of $SiO_2$ on the surface of the alloy.

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Investigations on electron beam weldability of AlZnMgCu0.5 alloys (AlZnMgCu0.5 합금의 Electron Beam 용접성에 관한 연구)

  • 배석천
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.166-177
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    • 1997
  • The high strength AlZnMgCu0.5 alloy is a light metal with good age hardenability, and has a high tensile and yielding strength. Therefore, it can be used for structures requiring high speciple strength. Even though high strength AlZnMgCu alloy has good mechanical properties, it has a lot of problems in TIG and MIG welding processes. Since lots of high heat absorption is introduced into the weldment during TIG and MIG processes, the microstructural variation and hot cracks take place in heat affected zone. Therefore, the mechanical properties of high strength AlZnMgCu0.5 alloy can be degraded in weldment and heat affected zone. Welding process utilizing high density heat source such as electron beam should be developed to reduce pore and hot cracking, whichare usually accompanied by MIG and TIG welding processes. In this work, electron beam welding process were used with or without AlMg4.5Mn as filler material to avoid the degradation of mechanical properties. Mechanical and metallurgical characteristics were also studied in electron beam weldment and heat affected zone. Moreover hot cracking mechanism was also investigated.

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