• 열처리공학회지
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• 제36권6호
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• pp.389-395
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• 2023

Damping capacities of Mg-2.5%Al and Mg-2.5%Zn (in atomic) solid solutions were comparatively investigated in order to clarify the influence of solutionized Al and Zn elements on the damping characteristics of Mg. In this study, solid solutions with similar grain size were obtained by solution treatment at 678 K for different times (24 h for Mg-2.5%Al and 36 h for Mg-2.5%Zn), followed by water quenching at RT. The Mg-2.5%Al and Mg-2.5%Zn solid solutions showed similar damping capacities in the strain-amplitude independent region of 1 × 10^-6 ~ 1 × 10^-5 and in the strain-amplitude dependent region below 6 × 10^-4, over which the Mg-2.5%Zn solid solution possessed better damping capacity than the Mg-2.5%Al solid solution. The damping tendencies depending on strain-amplitude for the two solid solutions were analyzed and discussed in terms of similar length between weak pinning points (solutes) and different solute/dislocation interaction forces in Granato-Lücke model.

• 열처리공학회지
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• 제37권5호
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• pp.221-227
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• 2024

The damping capacities in the strain-amplitude dependent and strain-amplitude independent regions were comparatively investigated for pure Mg and Mg-X%Al solid solutions (X : 1, 2 at%) to clarify the role of Al solute in the damping properties of Mg-Al binary solid solution. In order to rule out the effect of grain size on damping capacity, grain sizes of the samples were adjusted to an almost similar level by changing the heat-treatment or solution treatment times at 683 K (12 h, 24 h and 32 h for pure Mg, Mg-1%Al and Mg-2%Al alloys, respectively). The damping capacities of the heat-treated pure Mg and Mg-X%Al solid solutions exhibited a decreasing tendency with an increase in Al concentration both in the strain-amplitude dependent and strain-amplitude independent regions. The observed damping trends depending on strain-amplitude were analyzed and discussed in association with decreasing length between weak pinning points (Al solutes) in Granato-Lücke model.

• 열처리공학회지
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• 제9권4호
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• pp.281-288
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• 1996

This study has been investigated the influence of solid solution treatment on the microstructure of Mg-6Al-xZn(x=0,1,2) alloys fabricated by squeeze casting process. The products having clean surface and fine microstructure are fabricated by adopting the liquid metal forging method. The microstructures of as-fabricated state show ${\beta}(Mg_{17}Al_{12})$ precipitates between the dendrite boundaries. It is found that the hardness of the alloys is increased with increasing amount of zinc due to the solid solution hardening effect of zinc. In the changes of microstructure upon solid solution treatment time at $405^{\circ}C$, ${\beta}$ phases are dissolved in ${\alpha}$ matrix up to 1hr and the microstructure are coarsened rapidly after 2hrs. The microhardness are decreased rapidly until 1hr of solution treatment time and then stabilized. From the above results, it is concluded that the optimum solid solution treatment condition for Mg-6Al-xZn alloys is at $405^{\circ}C$ for 1hr. The solution treatment time is greatly reduced comparing to conventional casting(at $385{\sim}418^{\circ}C$ for 10~14hrs) due to the formation of the super-saturated solid solution by liquid metal forging.

• 한국세라믹학회지
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• 제25권1호
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• pp.35-41
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• 1988

In the system of Li2O-MgO-Al2O3-Cr2O3, the crystalline solid solution of LiCrO2 along the pseudo-binary join between rocksalt structure(LiCrO2) and spinel structure(MgCr2O4 or MgAl2O4) have been investigated by x-ray diffraction techniques. In this study, order-disorder phase transition of LiCrO2 was observed and the unit cell of the disordered LiCrO2 structure has been established. It has been found that LiCrO2 makes a solid solution over a wide range with MgAl2O4, while not with MgCr2O4. This difference was explained as being due to the ability of oxygen lattice distortion which depended on the relative sizes and chemical bonding characteristics of the substituted ions.

• 한국세라믹학회지
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• 제20권1호
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• pp.25-30
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• 1983

This experiment was studied in the system of (1-x) CaO MgO $2SiO-Al_2O_3$ to investigate forming of solid solution. The technique empolyed was the well known water-quenching method. Differential thermal analysis of the each glass water quenched indicated that under 30 mole% $Al_2O_3$ was lowered with increasing of the amount of $Al_2O_3$ It was supposed by X-ray diffraction patterns of each specimen sintered at various temperature that only solid solution was formed under the 30mole % $Al_2O_3$ compositions solid solution and anorthite were formed at the 20mole% $Al_2O_3$ composition anorthite solid solution and spinel$(MgAl_2O_4)$ were formed over the 40mole% $Al_2O_3$ compositions. The maximum density and thermal expanison coefficient was 2.89g/cm 7.74x106./C$^{\circ}$ respectively in the composi-tion of 10 mole% $Al_2O_3$ . All the specimens showed linear thermal expansion behavior. Microhardness was as high as 850kg/nm2 in the composition of 5, 10, 20 mole % $Al_2O_3$ and dielectric constant was 7.3-6.9.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2005년도 후기학술대회논문집
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• pp.194-195
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• 2005

(100-x)Zn xMg alloy films are prepared onto cold-rolled steel substrates; where x ranged from 0 to about 38 atomic %. The alloy films show microcrystalline and grain structures respectively, according to preparation conditions such as composition ratio of zinc and magnesium or gas pressures etc.. And X-ray diffraction analysis indicates not only the presence of Zn-Mg thin films with forced solid solution but also the one of $MgZn_2$ alloy films partly. In addition the influence of Mg/Zn composition ratio and morphology of the Zn-Mg alloy films on corrosion behavior is evaluated by electro-chemical anodic polarization tests in deaerated 3% NaCl solution. From this experimental results, all the prepared Zn-Mg alloy films showed obviously good corrosion resistance to compare with 99.99% Zn and 99.99% Mg Ingots for evaporation metal. It is thought that the Zn-Mg films with effective forced solid solution prepared by plasma enhanced PVD method, produces smaller and denser grain structure so that may improve the formation of homogeneous passive layer in corrosion environment.

• 한국세라믹학회지
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• 제32권2호
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• pp.234-238
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• 1995

MgFe2O4 formation, grain growth in Fe2O3, Fe solid-solution limit in MgO for MgO-Fe2O3 mixture were studied by means of investigating the distribution of phases and compositions in reaction area between MgO and Fe2O3. The reaction area at equlibrium was composed with MgO-FexO matrix and MgFe2O4 precipitation, MgFe2O4 was formed by precipitating from MgO-FexO matrix dependent on oxygen partial pressure. Fe contents was exponentially decreased with diffusion distance in MgO single crystal, and thus Fe solid-solution limitation in MgO was about 4mol%. The grain growth rate in Fe2O3 base was increased with Mg contents diffused from MgO single crystal.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.75-76
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• 2006

New PM route via bulk mechanical alloying is developed to fabricate the solid solution semi-conductive materials with $Mg_2Si_{1-x}Ge_x$ and $Mg_2Si_{1-y}Sn_y$ for 0 < x, y < 1 and to investigate their thermoelectric materials. Since $Mg_2Si$ is n-type and both $Mg_2Ge$ and $Mg_2Sn$ are p-type, pn-transition takes place at the specified range of germanium content, x, and tin content, y. Through optimization of chemical composition, solid-solution type thermoelectric semi-conductive materials are designed both for n-and p-type materials.

• 한국환경과학회지
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• 제24권1호
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• pp.47-53
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• 2015

Removal characteristics of Cu(II) ions by solid-phase extractant immobilized D2EHPA and TBP in PVC were investigated. Cu(II) ion concentrations in the solution and removal capacity of Cu(II) ion according to operation time were compared. The lower the initial concentration of Cu(II) ion in aqueous solution was, the removal capacity of Cu(II) ion by solid-phase extractant was increased relatively. The bigger the initial concentration of Cu(II) ion was, the removal capacity of Cu(II) ion was increased relatively. The pseudo-second-order kinetics according to operation time was showed more satisfying results than the pseudo-first-order kinetics for the removal velocity of Cu(II) ion. The removal capacity of Cu(II) ion was 0.025 mg/g in aqueous solution of pH 2, but the removal capacity of Cu(II) ion was increased to 0.33 mg/g mg/g in aqueous solution of pH 4 according to increasing pH.

• 열처리공학회지
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• 제26권4호
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• pp.165-172
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• 2013

In the present study, the microstructure and solution treatment response of Al-Zn-Mg alloys bars by thixo-extrusion was investigated. The alloy bars were solution treated at 400, 430, 460 and $490^{\circ}C$ for various times. In order to examine the microstructures and phase analysis of the samples after solution treatment, it was performed by optical and scanning electron microscopy. And, Vickers hardness and electrical conductivity was measured on the solution treated samples for each condition to investigate the solution treatment response of extruded bars during solution treatment. The results show that the optimum solution heat treatment conditions of thixo-extruded Al-Zn-Mg alloy for minimization of the grain growth and degradation promotion of the second phase is a temperature of $460^{\circ}C$ and holding time of 0.5 to 2 h.