• Title/Summary/Keyword: Mg and Mg-Al alloy

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Microfracture Mechanism of Squeeze Cast AZ51-xSn Magnesium Alloys (용탕단조법으로 제조된 AZ51-xSn 마그네슘 합금의 미세파괴기구)

  • Kim, Byeong Ho;Do, Jeonghyeon;Lee, Sunghak;Park, Ikmin
    • Korean Journal of Metals and Materials
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    • v.47 no.12
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    • pp.797-810
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    • 2009
  • A study was made of the effects of a Sn addition on the microstructure and microfracture mechanism of squeeze cast AZ51-xSn magnesium alloys. Microstructural observation, in situ fracture testing, and fractographic observations were conducted on these alloys to clarify the microfracture process. The microstructural analyses indicated that $Mg_2Sn$ particles as well as $Mg_{17}Al_{12}$ particles precipitated mainly along the solidification cell boundaries; the volume fraction of these hard particles increased as the amount of added Sn increased, with increased the strength. From in situ fracture observations of the AZ51-7Sn alloy, coarse precipitates located on the cell boundaries worked as easy crack propagation sites and caused abrupt intercellular fracturing. On the other hand, the overall fracture properties of the AZ51-3Sn alloy improved because crack propagation proceeded into the Mg matrix rather than into the cell boundaries as twins developed actively, as confirmed by an R-curve analysis. These findings suggest that the addition of 3~5 wt.% Sn is effective in improving both the tensile and fracture properties on the basis of well-developed twins, the blocking of crack propagation, and crack blunting.

Evaluation on Potentiostatic Characteristics of Al-4.06Mg-0.74Mn Alloy with Cavitation Environment in Seawater (Al-4.06Mg-0.74Mn 합금의 해수 내 캐비테이션 환경에 따른 정전위 특성 평가)

  • Lee, Seung-Jun;Han, Min-Su;Jang, Seok-Ki;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.45 no.6
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    • pp.272-277
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    • 2012
  • The hull of a fast sailing aluminium ship are generally prone to erosion owing to the impact of seawater. At this time, synergistic effects of the erosion and the corrosion by aggressive ions such as chlorides tend to aggravate the damage. There have been various attempts, including selection of erosion-resistant materials, cathodic protection and addition of corrosion inhibitors, to overcome damage by erosion or corrosion under marine environments. These approaches, however, have limits on identifying the damage mechanism clearly, because they depend on analogical interpretation by correlating two damage behaviors after the individual studies are assessed. In this research, it was devised a hybrid testing apparatus that integrates electrochemical corrosion test and cavitation test, and thus the erosion-corrosion behavior by cavitation was investigated more reliably. As a result, the slightest damage was observed at the potentials between -1.6 V and -1.5 V. This is considered to be due to a reflection or counterbalancing effect caused by collision of the cavitation cavities and the hydrogen gas formed by activation polarization.

Microstructural Feature of Discontinuous Precipitates Formed by Furnace Cooling in AZ91 Magnesium Alloy (AZ91 마그네슘 합금에서 노냉으로 생성된 불연속 석출물의 미세조직 특징)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.5
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    • pp.231-236
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    • 2018
  • The purpose of this study was to investigate the microstructural characteristics and hardness distribution of AZ91 magnesium alloy furnace-cooled to room temperature after solution treatment, and to compare the results with those of as-cast condition. The as-cast alloy showed a partially divorced eutectic ${\beta}(Mg_{17}Al_{12})$ phase and discontinuous precipitates (DPs) with a lamellar morphology, while only DPs were observed in the furnace-cooled alloy. The DPs in the furnace-cooled AZ91 alloy had various apparent interlamellar spacings, which would be ascribed to the different transformation temperatures during the furnace cooling. The average hardness for the furnace-cooled alloy is similar to that for the as-cast alloy. It is interesting to note that the hardness values of the furnace-cooled alloy were distributed over a narrower range than those of the as-cast alloy. This is likely to be caused by the relatively more homogeneous microstructure of the furnace-cooled alloy in comparison with the ascast one.

Investigation on optimum protection potential of high-strength Al alloy(5456-H116) for application in ships (선박용 고강도 Al합금(5456-H116)의 최적 방식 전위결정에 관한 연구)

  • Kim Sung-Jong;Ko Jae-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.157-168
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    • 2006
  • Recently, interest in using Al alloys in ship construction instead of fiber-reinforced plastic (FRP) has increased because of the advantages of A) alloy ships over FRP ships, including high speed, increased load capacity. and ease of recycling. This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. These results will provide reference data for ship design by determining the optimum protection potential regarding hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a Passive film. In a potentiostatic experiment. the current density after 1200 sec in the Potential range of $-0.68\~-1.5\;V$ was low. This low current density indicates the protection potential range. Elongation at an applied potential of 0 V was high in this SSRT. However, corrosion protection under these conditions is impossible because the mechanical properties are worse owing to decreased strength resulting from the active dissolution reaction in parallel parts of the specimen. A film composed of $CaCO_3\;and\;Mg(OH)_2$ confers corrosion resistance. However, at potentials below -1.6 V forms non-uniform electrodeposition coating, since there is too little time to form a coating. Therefore, we concluded that the mechanical properties are poor because the effect of hydrogen gas generation exceeds that of electrodeposition. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.45 to -0.9 V (SSCE).

Fatigue Life Prediction for Resistance Spot Weldment of Aluminum Alloy Sheet (알루미늄 합금판 저항 점용접부의 피로수명 예측)

  • 장건익;안병국;김동건
    • Journal of Welding and Joining
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    • v.20 no.2
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    • pp.116-124
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    • 2002
  • The fatigue life is predicted on tensile-shear spot weldment made from Al-Mg alloy sheet with thickness of 0.8mm using Mitchell's method and uniform material law by $B{\ddot{a}}umel$ and Seeger based on local strain approach. The fatigue properties of critical HAZ region are estimated from the tensile property using simple hardness method. To predict the fatigue life of spot weldment, the local stresses and strains at the potential critical region are estimated by Neuber's rule. The predicted fatigue life based on uniform material law using HAZ's material properties provides good results within a factor of 3, conservatively.

A Study on the Manufacturing of an Aluminum Shift-Fork by Casting/Forging Process (주조/단조 기술을 이용한 알루미늄 쉬프트 포크 제조에 관한 연구)

  • 배원병;이승재;유민수
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.193-197
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    • 2002
  • In this study, the casting/forging process was applied to the Shift-Fork, a manual transmission part of automobiles. In the casting experiments, the effects of additives, Sr, Ti+B and Mg, on the mechanical properties and the microstructure of a cast preform were investigated. When 0.03% Sr were added into the molten aluminum alloy, the finest silicon-structure was observed in the cast preform and the highest tensile strength and elongation accomplished. And when 0.2% Ti+B were added into the molten Al-Si alloy, the highest values of tensile strength were obtained. The maximum hardness was in case of 0.2% Mg. In the forging experiment, it was confirmed that the optimal configuration of the cast preform could be predicted by FE analysis. To minimize the cost as the press size, the compact shape of preform was proposed to reduce the volume of flash. The modification of shape in designing preform was performed to attain a satisfactory performance in the areas where the mechanical strength were more required. By using FVM(Finite Volume Method) software, it was verified that a proposed casting design was available. To identify the relationship between effective strain and mechanical properties of the final forged product, the compression test was performed. As the result, the tensile strength and elongation of a cast preform were much higher than before forging. The minimum forging temperature was found 40$0^{\circ}C$ to save heating time.

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A Study on the Prediction of the Material Properties of Magnesium Alloys Using Density Functional Theory Method (밀도함수 이론법을 이용한 마그네슘 합금의 재료특성 예측에 관한 연구)

  • Baek, Min-Sook;Won, Dae-Hee;Kim, Byung-Il
    • Korean Journal of Materials Research
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    • v.17 no.12
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    • pp.637-641
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    • 2007
  • The total energy and strength of Mg alloy doped with Al, Ca and Zn, were calculated using the density functional theory. The calculations was performed by two programs; the discrete variational $X{\alpha}\;(DV-X{\alpha})$ method, which is a sort of molecular orbital full potential method; Vienna Ab-initio Simulation Package (VASP), which is a sort of pseudo potential method. The fundamental mixed orbital structure in each energy level near the Fermi level was investigated with simple model using $DV-X{\alpha}$. The optimized crystal structures calculated by VASP were compared to the measured structure. The density of state and the energy levels of dopant elements was discussed in association with properties. When the lattice parameter obtained from this study was compared, it was slightly different from the theoretical value but it was similar to Mk, and we obtained the reliability of data. A parameter Mk obtained by the $DV-X{\alpha}$ method was proportional to electronegativity and inversely proportional to ionic radii. We can predict the mechanical properties because $\Delta{\overline{Mk}}$is proportional to hardness.

Fabrication and Properties of High Strength Hypereutectic AI-Si Powders by a Gas Atomization Process II. Extrusion and Mechanical Properties (가스분무 공정에 의한 고강도 과공정 AI-Si 합금 분말의 제조 및 특성연구 II. 압출재 제조 및 기계적 특성)

  • Kim, Yong-Jin;Kim, Jin-Chun
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.142-147
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    • 2008
  • The hypereutectic Al-20 wt%Si powders including some amount of Cu, Fe, Mg, Mn were prepared by a gas atomization process. In order to get highly densified Al-Si bulk specimens, the as-atomized and sieved powders were extruded at $500^{\circ}C$, Microstructure and tensile properties of the extruded Al-Si alloys were investigated in this study. Relative density of the extruded samples was over 98%. Ultimate tensile strength (UTS) in stress-strain curves of the extruded powders increased after T6 heat treatments. Elongation of the samples was also increased from 1.4% to 3.2%. The fracture surfaces of the tested pieces showed a fine microstructure and the average grain size was about $1{\mu}m$.

A evaluation on laser lap welding characteristics of Al5J32 alloy for automotive application using Yb:YAG Laser welding (Yb:YAG 레이저를 이용한 자동차용 알루미늄 Al5J32 겹치기 용접부의 Spiking방지 및 용접성 평가)

  • Ahn, Do-Chang;Kim, Cheol-Hee;Kim, Jae-Do
    • Proceedings of the KWS Conference
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    • 2010.05a
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    • pp.93-93
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    • 2010
  • 환경 규제 및 배출가스 규제에 의하여 차량 경량화를 위해 점차적으로 Al합금의 차체 및 부품적용 비율이 점차 확대되고 있다. 이에 따라 알루미늄의 레이저 용접 시 출력, 초점거리, 용접 속도 등 공정 변수의 상관관계와 용접 결함 현상에 의한 관심이 집중된 연구가 많이 발표되었으며, 알루미늄 5000계열의 경우 박판 용접 시 기공, 균열 등 과 같은 결함 현상을 방지하기 위하여, Twin spot laser, Laser-TIG hybrid 등과 같은 공법 적용을 제안되었다. 본 연구에서는 Yb:YAG laser welding 시 Mg 함량이 높은 AA5J32을 소재를 이용하여 박판 겹치기 용접 시 Back side spiking 결함 방지를 위한 레이저 빔 출력 파형을 설계하여 실험을 수행하였다. 또한 파형의 특성에 따라 나타나는 겹치기 용접부의 기계적 특성과 기공에 대해 알아 보고자 하였다.

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Mechanism of Hot Cracking in High Strength Al Welds (고강도 알루미늄합금 용접부의 고온균열 Mechanism)

  • 이창희;조성석
    • Journal of Welding and Joining
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    • v.14 no.3
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    • pp.93-104
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    • 1996
  • This study evaluated relative hot cracking susceptibility of commercial aluminum alloy welds, and then suggested possible mechanisms operated in the weld fusion zone and in the heat affected zone based on the observed cracking morphologies, fractography and microstructural features. The fusion zone solidification cracking was found to be mainly due to a microsegregation of Cu, Si, and Mg in grain boundaries, while liquation cracking in the HAZ was by the incipient melting of the segregated grain boundaries and the consitutional liquation of large aging precipitates and intermetallic compounds in the partially melted zone adjacent to the fusion line which experienced a rapid thermal excursion during welding.

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