• 제목/요약/키워드: Mg and Mg-Al alloy

검색결과 584건 처리시간 0.033초

Corrosion Charateristics of PEO-treated Ti-6Al-4V Alloy in Solution Containing Si and Mg Ions

  • Park, Seon-Yeong;Choe, Han-Cheol
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.153-153
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    • 2017
  • The application of the coating supports the mechanical characteristics of the implant, and various materials and coatings are currently being used in the implant in a way to accelerate adhesion. Especially, plasma electrolytic oxidation (PEO) coating has been proposed continually with good surface treatment of titanium alloys. Also, the PEO process can incorporate Ca and P ions on the titanium surface through variables varied factor. PEO process for bioactive surface has carried out in electrolytes containing Ca and P ions. Natural bone is composed of mineral elements such as Mg, Si, Zn, Sr, and Mn, etc. Especially, Mg and Si of these elements play role in bone formation and growth after clinical implantation of bio-implants. In this study, corrosion charateristics of PEO-treated Ti-6Al-4V alloy in solution containing Si and Mg ions has been investigated using several experimental techniques. The PEO-treated surfaces were identified by X-ray diffraction, using a diffractometer (XRD, Philips X' pert PRO, Netherlands) with Cu $K{\alpha}$ radiation. The morphology was observed by field-emission scanning electron microscopy (FE-SEM, Hitachi 4800, Japan) and energy-dispersive X-ray spectroscopy (EDX, Oxford ISIS 310, England). The potentiodynamic polarization and AC impedance tests for electrochemical degradations were carried out in 0.9% NaCl solution at similar body temperature using a potentiostat with a scan rate of 1.67mV/s and potential range from -1500mV to + 2000mV.

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입자미세화가 Al-4.8%Cu-0.6%Mn 합금의 유동도에 미치는 영향 (The Effect of Grain Refinement on Fluidity of Al-4.8%CU-0.6%Mn Alloy)

  • 권영동;이진형;김경현
    • 한국주조공학회지
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    • 제22권3호
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    • pp.109-113
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    • 2002
  • A good fluidity of high strength Al-alloys is required to cast thin wall castings needed to reduce the weight of cast parts. The fluidity, measured as the length to which the metal flows in a standard channel, is affected by many factors, such as the pouring temperature, solidification type of the alloy, the channel thickness, melt head, mold materials and temperature, coating etc. Therefore the experimentally measured fluidity scatters very much and makes it difficult to estimate the fluidity of a melt with a few measurements. The effect of Ti content and grain refinement on the fluidity of high strength aluminum alloy was investigated with a test casting with 8 thin flow channels to reduce the scattering of the fluidity results. The fluidity of Al-4.8%Cu-0.6%Mn Al-6.2%Zn-1.6%Mg-1.0%Cu and well-known commercial aluminum alloy, A356 was tested. Initial content of Ti was varied from 0 to 0.2wt% and Al-5Ti-B master alloy was added for grain refinement. The flow length varied linearly with superheat. By adding Ti and Al-5Ti-B, the fluidity increased. The grain size decreased by adding grain refiner at the same time. The fluidity depended on the degree of grain refinement. The fluidity of the alloy solidifying in mushy type is improved by grain refinement, because grain refinement increases the solid fraction at the time of flow stoppage.

반응고 7075 알루미늄 합금의 반용융 압출 및 압출재의 기계적 특성 (Thixo-extrusion of Semi Solid 7075 Aluminum Alloys and Mechanical Properties of The Extrudates)

  • 최태영;김대환;김수배;심성용;임수근
    • 한국주조공학회지
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    • 제34권3호
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    • pp.87-93
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    • 2014
  • Thixo-extrusion of semi-solid 7075 aluminum alloy and the mechanical properties of its extrudates were investigated. The semisolid alloy was prepared by a cooling slope cast. In other to perform thixo-extrusion, semi-solid 7075 aluminum alloy billets were reheated at the reheating conditions reported in a previous study. The maximum extrusion pressure in thixo-extrusion was 615MPa. This was lower than that of conventional hot extrusion ($P_{max}=940MPa$) at the same extrusion conditions due to the increased fluidity of the alloy billet in the semi-solid state. The values of Rockwell hardness (scale B) at the extrusion direction of the as thixoextruded bar were 48~53HRB and the difference in Rockwell hardness between the transverse direction and the extrusion direction was 5HRB or less. The results show that thxio-extrusion of semi-solid 7075 Al alloy improves the workability and anisotropic with the extrusion direction compared with hot extrusion of the conventional alloy.

리브보강 Al-Mg-Si계 가로등 등주의 구조적 거동 (Structural Behavior of Rib Reinforced Mg-Si Aluminum Alloy lighting Pole)

  • 남정훈;주형중;김영호;윤순종
    • Composites Research
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    • 제21권6호
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    • pp.8-14
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    • 2008
  • 가로등은 운전자의 안전을 위한 필수적인 도로 부속구조물이며, 대부분 강재 등주를 사용하고 있다. 강재등주는 부식이 발생하여 내구성을 감소시키고, 도시미관을 저해하므로 스테인레스 제품이나 주철재 등을 사용하기도 한다. 그러나 주철재 및 스테인레스 등주를 사용하더라도 부식에 대한 위험성을 완전히 배제할 수 없고, 높은 강도와 강성은 충돌시 운전자의 안전을 위협하는 요인이 되고 있다. 따라서 새로운 형태의 등주 시스템의 개발이 요구되고 있다. 기존 등주의 문제점을 보완하기 위해 최근 알루미늄 합금을 사용한 등주가 개발되어 사용되고 있다. 알루미늄은 재료적 특성상 단위중량당 강도가 높고 부식에 대한 저항성이 매우 커서 그 활용성을 크게 증대될 것으로 예측되나 강계에 비해 강성과 강도가 낮기 때문에 구조적 안전성에서 문제점이 제기되고 있어 구조거동에 대한 연구가 필요하다. 이 연구는 현재 가로등 등주로 사용되고 있는 강재 및 알루미늄 등주에 대한 휨, 압축실험 등을 수행하여 알루미늄 등주의 구조거동을 조사하였고, 기존 강재등주와 비교하여 효율성 및 안전성을 평가하였다.

Al-Si-Cu계 AC2B 합금의 최적 용체화 처리 조건 (The Optimal Solution Treatment Condition in a Al-Si-Cu AC2B Alloy)

  • 정재길;박준수;하양수;이영국;전중환;강희삼;임종대
    • 대한금속재료학회지
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    • 제47권4호
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    • pp.223-227
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    • 2009
  • The precipitates, hardness, and tensile properties of Al-6.2Si-2.9Cu AC2B alloy were investigated with respect to solution treatment time at $500^{\circ}C$. $Al(Cu)-Al_2Cu$ eutectic, Si, ${\theta}-(Al_2Cu)$, and $Q-(Al_5Cu_2Mg_8Si_6)$ phases were observed in the as-cast specimen. With increasing the solution treatment time at $500^{\circ}C$, the $Al(Cu)-Al_2Cu$ eutectic and ${\theta}-(Al_2Cu)$ phases were gradually reduced and finally almost disappeared in 5 h. The mechanical properties, such as hardness, tensile strength, and elongation, were improved with solution treatment time until about 5 h due to the dissolution of the $Al_2Cu$ particles. With further holding time, the mechanical properties did not change much. The solution treated specimens for over 5 h at $500^{\circ}C$ exhibit almost the same tensile properties even after aging at $250^{\circ}C$ for 3.5 h. Accordingly, the optimal solution treatment condition of the Al-Si-Cu AC2B alloy is considered to be 5 h at $500^{\circ}C$.

AZ31B 마그네슘합금의 피로균열성장에 미치는 응력비 및 이방성의 영향 (Effect of Stress Ratio and Anisotropy on Fatigue Crack Propagation Behavior of AZ31B Magnesium Alloy)

  • 김귀식;김명근;김현관;김충옥
    • 동력기계공학회지
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    • 제15권1호
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    • pp.39-44
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    • 2011
  • This study was to investigate the effects of stress ratio and anisotropy on Fatigue Crack Propagation(FCP) behavior of rolled magnesium alloy AZ31B. The experimental materials were a Mg-Al-Zn magnesium alloy. The FCP test was conducted on compact tension specimen by a servo-hydraulic fatigue testing machine in air at room temperature. Compact tension specimens were prepared from the extruded parallel and vertical rolling direction. The test condition was frequency of 10Hz and sinusoidal load stress ratios are 0.1 and 0.7. The FCP rates was automatically measured by a compliance method. In the case of the FCP of AZ31B, the FCP of both direction of LT and TL by anisotropy of specimens are almost same value. In lower stress ratio, the FCP of the LT, TL specimens are increased in lower ${\Delta}K$ region but higher ${\Delta}K$ regions are almost same value. Finally, the result of observed the surface crack, it expressed the quasi-cleavage fracture in lower ${\Delta}K$ region and straight mark on the aspect of the facet in high ${\Delta}K$ region.

Bone-like Apatite Formation on Ti-6Al-4V in Solution Containing Mn, Mg, and Si Ions after Plasma Electrolytic Oxidation in the SBF Solution

  • Lim, Sang-Gyu;Choe, Han Cheol
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.157-157
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    • 2017
  • Titanium and its alloys that have a good biocompatibility, corrosion resistance, and mechanical properties such as hardness and wear resistance are widely used in dental and orthopedic implant applications. They can directly connect to bone. However, they do not form a chemical bond with bone tissue. Plasma electrolytic oxidation (PEO) that combines the high voltage spark and electrochemical oxidation is a novel method to form ceramic coatings on light metals such as titanium and its alloys. This is an excellent reproducibility and economical, because the size and shape control of the nano-structure is relatively easy. Silicon (Si), manganese (Mn), and magnesium (Mg) has a useful to bone. Particularly, Si has been found to be essential for normal bone, cartilage growth and development. Manganese influences regulation of bone remodeling because its low content in body is connected with the rise of the concentration of calcium, phosphates and phosphatase out of cells. Insufficience of Mn in human body is probably contributing cause of osteoporosis. Pre-studies have shown that Mg plays very important roles in essential for normal growth and metabolism of skeletal tissue in vertebrates and can be detected as minor constituents in teeth and bone. The objective of this work was to study nucleation and growth of bone-like apatite formation on Ti-6Al-4V in solution containing Mn, Mg, and Si ions after plasma electrolytic oxidation. Anodized alloys was prepared at 270V~300V voltages. And bone-like apatite formation was carried out in SBF solution for 1, 3, 5, and 7 days. The morphologies of PEO-treated Ti-6Al-4V alloy in containing Mn, Mg, and Si ions were examined by FE-SEM, EDS, and XRD.

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Al-Cu첨가(添加)에 의(依)한 CV흑연주철(黑鉛鑄鐵)에 관한 기초연구 (A Study of the CV graphite cast iron with small additions of a Al-Cu alloy)

  • 전형탁;허보영;김수영
    • 한국주조공학회지
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    • 제3권4호
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    • pp.239-247
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    • 1983
  • CV graphite cast iron has been studied and generally known to have properties close to the average values of those between flake and spheroidal graphite cast iron. However, the thermal diffusivity of CV graphite cast iron is much larger than that of the average value of those between flake and spheroidal graphite cast iron. In this study, an easy production method of CV graphite cast iron with small additions of a Al-Cu which is known as the element of the graphitization was investigated. The effects of hold time and of Al-Cu additions after the treatments with spheroidizer (Fe-Si-Mg alloy) were also investigated. Increasing the additions of a Al-Cu alloy, the holding time to form a CV graphite cast iron was decreasing. Tensile strength and thermal diffusivity (flash method) were measured in order to find the changes of the mechanical properties and the physical properties. Spheroidal, CV, and flake graphite cast iron have tensile strengths 46.44, 38.29, and $27.29\;kg/mm^2$ and thermal diffusivities $3.95{\times}10^{-6,}$ $8.41{\times}10^{-6}$, $8.81{\times}10^{-6}m^2/sec$, respectively at room temperature.

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마그네슘용탕의 니켈 함량에 미치는 알루미늄, 망간 및 지르코늄의 영향 (Effect of Aluminum, Manganese, and Zirconium on the Content of Nickel in Molten Magnesium)

  • 정대영;문영훈;문병기;박원욱;손근용
    • 한국주조공학회지
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    • 제35권1호
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    • pp.8-14
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    • 2015
  • Variations of nickel contents and microstructures in molten magnesium alloys on the addition of aluminum, zirconium, and manganese have been investigated. Specimens were prepared by melting under $SF_6$ and $CO_2$ atmosphere and casting into a disc of 29 mm diameter with 7~10 mm thickness from the melt acquired at the top of crucible. Before casting, the molten metal was stirred for 3 minutes after each addition of alloying elements and maintained for 30 minutes for settling down. Results showed that zirconium did not significantly affect the content of nickel while aluminum remarkably reduced it by forming $Al_3Ni_2$ phase. When manganese are added to Mg-1wt%Ni alloy along with aluminum, both elements remarkably reduced the content of nickel. The addition of 1.5 wt% manganese to Mg-1wt%Ni alloy containing aluminum further reduced the content of nickel by more than 30%, during which an additional intermetallic phase $Al_{10}Mn_3Ni$ was precipitated in the molten magnesium.