• Title/Summary/Keyword: Mg and Mg-Al alloy

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Flame Spreading Over Metal Dust Deposits With Particles Size (입경 변화에 따른 퇴적금속 분체층의 화염전파)

  • Han, Ou Sup;Choi, Yi Rac;Han, In Soo;Lee, Jung Suk
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.603-608
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    • 2010
  • A study has been conducted experimentally to investigate behavior of ignition and flame spread over metal dust deposits with particle size using by a developed apparatus and thermogravimetric analysis(TGA). Zr, Ta and Mg-Al(90:10 wt%) alloy metal powders including Mg and Ti with different particle size were used. Also we used PMMA(Polymethylmethacrylate) powder to compare the combustion properties to those of metal powders. When dust layers were more than 5 mm in thickness, the dependency of deposit depth on flame spread rate over dust layer was not shown. With decreasing mean particle diameter, flame spread rate over Ti dust layer decreased, while the spread rate over Mg dust layer increased. For mean diameter of $51{\mu}m$, fire spread rate over pure Mg dust layer decreased to about 50 percent in Mg-Al(90:10 wt%) dust layer. The oxide thickness of metal dust used in this study tended to be inversely proportional with the spread rate, and it was quite small for influence with particle size. From the results of TGA for Ti and Mg, weight increasing curves(550 for Mg, 578 for Ta) were observed in the oxidation process, and they seems to be caused by ignition of upper dust layer.

Hot Cracking Susceptibility in Welds of High Strength Al Alloys by Using DCSP-GTAW (DCSP-GTAW에 의한 고력 Al합금의 고온균열감수성에 대한 연구)

  • Ha Ryeo-Sun;Jung Byong-Ho;Park Hwa-Soon
    • Journal of Welding and Joining
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    • v.22 no.5
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    • pp.65-72
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    • 2004
  • The tendency and degree of hot cracking of high strength 5083, 6N01 and 7N01 Al alloy welds by using DCSP-GTAW through modified Varestraint test and autogenous butt welding were investigated. In hot cracking test, 6N01 alloy showed the highest susceptibility to hot cracking in the weld metal and HAZ. Cracking susceptibilities generally increased with increase of solidification temperature range of the base metal and bead penetration-to-width ratio of the weld metal. The cracks in welds of the alloys vertically formed to solid-liquid interface and propagated along with columnar grain boundaries. The fracture facets of cracks showed the typical morphology of solidification crack observed as dendritic structures. Especially, in 6N01 alloy, liquation cracks which were due to elements of Si, Fe and Mg also observed in HAZ near fusion boundary. In butt welding of different Al alloys, the bead crack was mainly occurred in the welds of 6N01, 7N01 and other Al alloys together with 6N01 or 7N01. In the butt welds of 7N01, it was found that the component of Cu had an effect on the higher susceptibility to the hot cracking.

Atomic-resolution Transmission Electron Microscopy Investigation of η2 Precipitate Growth in Al-Zn-Mg Alloy (원자단위 투과전자현미경을 활용한 알루미늄-아연-마그네슘 합금 내부 η2 석출물 성장 메커니즘 규명)

  • H. Kim;H. N. Han
    • Transactions of Materials Processing
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    • v.33 no.1
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    • pp.12-17
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    • 2024
  • Aluminum-zinc-magnesium alloy is a well-known alloy that is both strong and lightweight. Precipitation strengthening plays a significant role in the strength mechanism of this alloy, with nano-sized η-based precipitates being the representative precipitates. However, the growth of η precipitates can lead to a decrease in strength, necessitating research into ways to control their growth. In this study, we observed the atomic-level behavior of η2 precipitates and discovered that the precipitates grew through a combination with magnesium after a zinc segregation layer was formed around them.

Characteristics of Fuel-rich Solid Propellants with Boron Powder and the Combustion Products (Boron Powder 적용 연료과농 추진제 및 연소 후 생성물의 특성 연구)

  • Kim, Miri;Kim, Jeongeun;Khil, Taeock
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.1
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    • pp.12-19
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    • 2022
  • The propellants used in the gas generator of the ducted rocket are fuel-rich propellants, which contain an excessive amount of metal fuel and a small amount of oxidizing agent compared to general solid rocket propellants. In this paper, boron powder and MgAl(Magnesium-Aluminium alloy) were applied to produce fuel-rich propellants. The optimum formulation was determined by characterizing these metal fuel-rich propellants. Analysis of combustion products in the gas generators confirmed that the fuel-rich propellants containing fine boron powder itself instead of boron-bead could be useful in gas generators.

Effects of Alloying Element and Grain Refinement on the Tensile Properties of Mg-Alloy Casted with Sand Mold (사형 주조 마그네슘 합금의 인장 특성에 미치는 합금 원소와 결정립 미세화의 영향)

  • Han, Jae-Jun;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.31 no.4
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    • pp.212-217
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    • 2011
  • The effects of alloying element and grain refinement on the tensile properties of magnesium alloy poured into sand mold were investigated. The strength of magnesium alloy was greatly increased by the addition of aluminium and that was increased with the increased aluminum content added up to 8.10 wt% and decreased beyond that. Even though the strength of Mg-8.10 wt%Al alloy was rather decreased by the addition of zinc, that was increased with increased zinc content added up to 0.50 wt% and decreased with the increased one beyond that. The maximum tensile strength was obtained with 0.50 wt%Mn added. The strength and elongation were simultaneously increased with grain refinement and the optimum amount of strontium addition for this was 0.30 wt%. The optimum chemical composition was obtained and the yield strength, tensile strength and elongation of the alloy with this composition were 90.2, 176.3MPa and 4.43%, respectively.

A Study on the Comparison of Chloride Ion Quantification Methods for Magnesium-Aluminum (Mg-Al) Alloy Powder (마그네슘-알루미늄(Mg-Al) 합금 분말의 염소이온 정량법의 비교에 관한 연구)

  • Yunhwan, Kim;Youngson Choe
    • Applied Chemistry for Engineering
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    • v.34 no.4
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    • pp.450-454
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    • 2023
  • Chloride ions in the alloy powder used as flux in Flux Cored Arc Welding (FCAW) can cause pores on the bead surface of the welding metal to cause defects, or chloride remaining in the alloy powder can cause corrosion of the metal. Combustion-ion chromatography is mainly used to quantify the chloride ions in alloy powder, but there is a limitation in that the equipment is expensive and requires a high degree of expertise. Therefore, this study aims to find an easy and accurate quantification method in the field by comparing combustion-ion chromatography (C-IC), which is mainly used for chloride ion quantification of alloy powder, X-ray fluorescence analysis (XRF), and potentiometric titration. In this article, magnesium-aluminum alloy powder is applied to the quantification of chloride ions because it is most commonly used as flux. This study confirmed that potentiometric titration can be applied to the quantification of chloride ions in the alloy powder in the industry field.

Effect of Si and Ca Addition on the Strengthening Behavior of Gravity-cast AM60 Magnesium Alloys (중력주조 AM60 마그네슘 합금의 강화 거동에 미치는 Si 및 Ca 첨가영향)

  • Kim, Jae-Woo;Kim, Do-Hyang;Shin, Kwang-Seon
    • Journal of Korea Foundry Society
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    • v.18 no.4
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    • pp.364-372
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    • 1998
  • Effects of Si and Ca additions on the mechanical properties of AM60 based Mg alloys have been investigated. Hardness of the AM60 based Mg alloys reached a maximum value after aging for approximately 33 hours but the amount of hardness increase was negligible. The poor age hardening response of the alloys was due to low Al content, which implies that Al content must be >6 wt.% to observe age hardening effect. The tensile and yield strength increased with increasing Al, Si, and Ca content but elongation decreased with increasing Al and Si content. The best mechanical properties obtained in AM 40-2.5Si-0.2Ca alloy after T4 heat treatment were as follows; tensile strength 193.4 MPa, yield strength 79.2 MPa, and elongation 11.2%. High temperature property obtained from creep test was also improved by introducing $Mg_2Si$ which has high hardness, high melting temperature and low thermal expansion coefficient.

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Surface Observation of Mg-HA Coated Ti-6Al-4V Alloy by Plasma Electrolytic Oxidation

  • Yu, Ji-Min;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.198-198
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    • 2016
  • An ideal orthopedic implant should provide an excellent bone-implant connection, less implant loosening and minimum adverse reactions. Commercial pure titanium (CP-Ti) and Ti alloys have been widely utilized for biomedical applications such as orthopedic and dental implants. However, being bioinert, the integration of such implant in bone was not in good condition to achieve improved osseointegraiton, there have been many efforts to modify the composition and topography of implant surface. These processes are generally classified as physical, chemical, and electrochemical methods. Plasma electrolytic oxidation (PEO) as an electrochemical route has been recently utilized to produce this kind of composite coatings. Mg ion plays a key role in bone metabolism, since it influences osteoblast and osteoclast activity. From previous studies, it has been found that Mg ions improve the bone formation on Ti alloys. PEO is a promising technology to produce porous and firmly adherent inorganic Mg containing $TiO_2$($Mg-TiO_2$ ) coatings on Ti surface, and the amount of Mg introduced into the coatings can be optimized by altering the electrolyte composition. In this study, a series of $Mg-TiO_2$ coatings are produced on Ti-6Al-4V ELI dental implant using PEO, with the substitution degree, respectively, at 0, 5, 10 and 20%. Based on the preliminary analysis of the coating structure, composition and morphology, a bone like apatite formation model is used to evaluate the in vitro biological responses at the bone-implant interface. The enhancement of the bone like apatite forming ability arises from $Mg-TiO_2$ surface, which has formed the reduction of the Mg ions. The promising results successfully demonstrate the immense potential of $Mg-TiO_2$ coatings in dental and biomaterials applications.

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Study on the Superplasticity in Al-Li Alloy Systems (AI-Li계 합금의 초소성에 관한 연구)

  • Jin, Y.C.;Kook, J.S.;Kim, Y.S.;Hong, E.S.;Lee, M.S.;Lee, M.H.;Yoo, C.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.1
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    • pp.41-49
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    • 1992
  • The effects of alloying elements on the superplastic properties of Al-Li based alloys had been investigated. The intermediate thermo-mechanical treated (ITMT) Al-2.0wt%Li, Al-2.0wt%Li-1.0wt%Mg, Al-2.0wt%Li-0.12wt%Zr and Al-2.0wt%Li-1.2wt%Cu-1.0wt%Mg-0.12wt%Zr alloys were tested in tension at various temperature (400, 450, 500 and $550^{\circ}C$) and strain rate($6.7{\times}10^{-3}$, $1.0{\times}10^{-2}$, $1.6{\times}10^{-2}$ and $5.0{\times}10^{-2}/sec$). The results were as follows : The superplasticity in binary, ternary and pentanary alloys appeared at 500 to $550^{\circ}C$, and good strain rate for superplasticity. $1.6{\times}10^{-2}/sec{\sim}1.0{\times}10^{-2}/sec$ for a binary alloy and $1.0{\times}10^{-2}/sec{\sim}6.7{\times}10^{-3}/sec$ for ternary and pentanary alloys. A Zr-added ternary alloy had best value of elongation (730%) in four alloys at $550^{\circ}C$ of tension temperature and $1.0{\times}10^{-2}/sec$ of strain rate. The strain rate was greatly dependent on tension temperature and true strain rate was more than 1.0 at all test temperature and strain rate. In binary and Mg-added teranry alloys. the necks were slightly formed and their fracture surface had lips shape, but Zr-added ternary and pentanary alloy fractured along the grain boundary without necking. Their dislocations moved to grain boundary during superplasticity deformation and arranged perpendicular to grain boundary. Super plastic deformation was made by grain boundary slip of dislocation slip creep and model of core and mantle.

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Bending Behaviors of Stainless Steel Tube Filled with Al5Si4Cu4Mg Closed Cell Aluminum Alloy Foam (발포 Al5Si4Cu4Mg 알루미늄 합금이 충진된 304 스테인리스강 원통의 굽힘저항 특성)

  • Kim, Am-Kee;Lee, Hyo-Jin;Cho, Seong-Seock
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.10
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    • pp.1686-1694
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    • 2003
  • The foam-filled tube beams can be used for the front rail and firewall structures to absorb impact energy during frontal or side collision of vehicles. In the case of side collision where bending is involved in the crushing mechanism, the foam filler would be effective in maintaining progressive crushing of the thin-walled structures so that much impact energy could be absorbed. In this study, bending behaviors of the closed-cell-aluminum-alloy-foam-filled stainless steel tube were investigated. The various foam-filled specimens including piecewise fillers were prepared and tested. The aluminum-alloy-foam filling offered the significant increase of bending resistance. Their suppression of the inward fold formation at the compression flange as well as the multiple propagating folds led to the increase of load carrying capacity of specimens. Moreover, the piecewise foams would provide the easier way to fill the thin-walled shell structures without the drawback of strength.