• Applied Chemistry for Engineering
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• v.26 no.4
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• pp.505-510
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• 2015

This study was performed to test the combustive properties of pinus rigida specimens treated with methylpiperazinomethyl-bis-phosphonic acid $M^{n+}$ ($PIPEABPM^{n+}$)s and methylpiperazinomethyl-bis-phosphonic acid (PIPEABP). Each pinus rigida plates were painted three times with 15 wt% $PIPEABPM^{n+}s$ or PIPEABP solutions at the room temperature. After drying specimens treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). It was indicated that the speed to peak mass loss rate ($MLR_{peak}$), (0.104~0.121) g/s for specimens treated with $PIPEABPM^{n+}s$ was lower than that of PIPEABP plate. In addition, the total smoke release rate (TSRR), $(224.4{\sim}484.0)m^2/m^2$ for $PIPEABPM^{n+}s$ treated specimens except specimen treated with PIPEABPAl3+ and $CO_{mean}$ production (0.0537~0.0628) kg/kg was smaller than that of PIPEABP plate. In particular, for the specimens treated with $PIPEABPM^{n+}$ by reducing the smoke production rate, the second-smoke production rate (2nd-SPR) $(0.0117{\sim}0.0146)m^2/s$ was lower than that of PIPEABP plate. It can thus be concluded that combustion-retardation properties of the treated $PIPEABPM^{n+}s$ were partially improved compared to those of the virgin plate.

• Fire Science and Engineering
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• v.28 no.3
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• pp.55-61
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• 2014

This study was performed to test the combustive properties of pinus rigida specimens treated with methylpiperazinomethyl-bis-phosphonic acid $M^{n+}$ ($PIPEABPM^{n+}$)s and methylpiperazinomethyl-bis-phosphonic acid (PIPEABP). Pinus rigida Plates were painted in three times with 15 wt% $PIPEABPM^{n+}s$ and PIPEABP solutions at the room temperature respectively. After drying specimen treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). It was indicated that the specimens treated with $PIPEABPM^{n+}s$ showed the lower speed to peak mass loss rate ($MLR_{peak}$), (0.104~0.121) g/s than that of PIPEABP plate. In adition, the specimens treated with $PIPEABPM^{n+}s$ showed both the lower total smoke release rate (TSRR), (224.4~484.0) $m^2/m^2$ and $CO_{mean}$ production (0.0537~0.0628) kg/kg than those of PIPEAB plate. Especially, for the specimens treated with $PIPEABPM^{n+}$ by reducing the smoke production rate except 2nd-smoke production rate (2nd-SPR), (0.0254~0.02270) g/s treated with $PIPEABPNi^{2+}$, 2nd-SPR (0.0117~0.0146) g/s was lower than that of PIPEABP plate. Thus, It is supposed that the combustion-retardation properties were improved by the partial due to the treated $PIPEABPM^{n+}s$ in the virgin plate.