• Title/Summary/Keyword: Methyl Sulfide

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Tour of Truffles: Aromas, Aphrodisiacs, Adaptogens, and More

  • Allen, Kirsten;Bennett, Joan W.
    • Mycobiology
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    • v.49 no.3
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    • pp.201-212
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    • 2021
  • Truffles are the fruiting bodies of ascomycete fungi that form underground. Truffles are globally valued, culturally celebrated as aphrodisiacs, and highly sought-after delicacies in the culinary world. For centuries, naturalists have speculated about their mode of formation, and in cultures surrounding the Mediterranean Sea, many species have been prized as a delectable food source. Truffle fruiting bodies form underground and emit a variety of volatile organic compounds (VOCs). Truffle volatiles are believed to have evolved to attract animals that disperse their spores. The main VOCs identified from truffles include sulfur compounds, such as dimethyl sulfide (DMS) and dimethyl disulfide (DMDS); in addition, 1-octen-3-ol and 2-methyl-1-propanol have been found in most truffle species. Humans use pigs and dogs trained to detect truffle VOCs in order to find these prized subterranean macrofungi. Truffles have pharmacological potential, but until more reliable cultivation methods become available their high price means they are unlikely to see widespread use as medicinals.

Analysis of Volatile Organosulfur Compounds in Korean Allium Species (국내산 Allium속(마늘, 양파, 대파)의 휘발성 함유황 유기화합물 분석)

  • Song, Hyun-Pa;Shim, Sung-Lye;Jung, In-Sun;Kim, Jun-Hyeong;No, Gi-Mi;Seo, Hye-Yeong;Kim, Dong-Ho;Kim, Kyong-Su
    • Food Science and Preservation
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    • v.16 no.6
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    • pp.929-937
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    • 2009
  • We identified volatile organic compounds in Korean Allium species. Volatile organic components in three Korean Allium species, dried garlic, dried onion, and dried Welsh onion, were extracted using a simultaneous distillation and extraction (SDE) method and identified by GC/MS analysis. The numbers of volatile compounds were 48, 32, and 33 in the three species, respectively. In dried onion, the major compounds were dipropyl trisulfide, methyl propyl trisulfide, and propanethiol. (Z), (E)-propenyl propyl trisulfide, methyl propyl trisulfide, and dipropyl trisulfide were detected at high levels in Welsh onion. In dried garlic, presence of the allyl group identified characteristic volatile organosulfur compounds including diallyl disulfide and diallyl trisulfide. Qualitative and quantitative analysis of volatile compounds in three Korean Allium species showed that sulfur-containing compounds were dominant, and allyl groups derived from (+)-S-(2-propenyl)-L-cysteine sulfoxide (ALLYL CSO, alliin) were more abundant in dried garlic, than in other materials.

A Before and After Study about the Effects of Korean Medical Treatment on Halitosis Patients: Using OralChroma$^{TM}$ (구취 환자의 한방 치료 효과에 대한 전.후 비교 연구: OralChroma$^{TM}$를 이용하여)

  • Choi, Jane;Kim, Jin-Sung;Jang, Seung-Won;Son, Ji-Yeong;Baek, Seung-Hwan;Han, Seong-Jun;Lee, Eom-Jee;Ryu, Bong-Ha
    • The Journal of Internal Korean Medicine
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    • v.35 no.4
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    • pp.532-545
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    • 2014
  • Objectives: The purpose of this study was to evaluate the clinical effect of Korean medical treatments such as herbal medicine, acupuncture, and electroacupuncture by using the portable gas chromatograph OralChroma$^{TM}$ (Abimedical, Japan) in halitosis patients. Methods: We surveyed 30 halitosis patients who had visited the Oral Diseases Clinic in the Korean Medical Hospital of Kyunghee University from October, 2013 to November, 2014. Before starting Korean medical treatment, the subjects were evaluated on sociodemographic characteristics, severity of discomfort using visual analogue scale (VAS), unstimulated salivary flow rate (USFR), and halitosis associated life-quality test (HALT) score. To evaluate the therapeutic effect, we measured the volatile sulfur compounds (VSCs) in breath by using OralChroma$^{TM}$ before and after 3 weeks treatment. Results: The concentration of total VSCs measured by OralChroma$^{TM}$ significantly decreased (p=0.001). Furthermore, the level of hydrogen sulfide and methyl mercaptan also significantly decreased (p<0.05). However, although the level of dimethyl sulfide decreased as well, there was no significance(p>0.05). Conclusions: Korean medical treatment was effective in treating halitosis by decreasing VSCs. Further study, with well-designed randomized controlled trials with larger number of cases will be needed in the future.

Extraction Property of Plasticizer in LPG High Pressure Rubber Hose (LPG용 고압고무호스에서 가소제 추출특성)

  • Kim, Young-Gu
    • Journal of the Korean Chemical Society
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    • v.48 no.2
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    • pp.156-160
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    • 2004
  • The extraction rates of plasticizer of LPG high pressure rubber are studied. Submerging solvents are composed of propane, n-butane, n-pentane, n-hexane, n-heptane, propylene, 1,3-butadiene, 1-pentene, 1-hexene, ethanethiol, t-butanethiol, dimethyl sulfide, methyl ethyl sulfide. The relationship between the extraction rate of plasticizer and the descriptors of submerging solvent by using multiple linear regression is as follows; PE(wt%) = 7.5193 - 0.58500Carbon${\sharp}$ + 2.3294DB + 2364SH, (N = 13, F = 24.135, R$^2$ = 0.8894, R$_{adj}^2$ = 0.8526, Variance = 7.588) Plasticizer is well extracted by LPG composed of the high vapour pressure and polarity compounds. The mass of extracted plasticizer becomes increasing in proportion to the contents of thiol sulfur compound and unsaturated hydrocarbon such as propylene and 1,3-butadiene in LPG. While the heavier hydrocarbons are, the less the quantities of plasticizer extracted from rubber are.

Determination of Sulfur Compounds in Gaseous Fuel by Gas Chromatography-Sulfur Chemiluminescence Detection (GC-SCD를 이용한 가스연료 중 황화합물의 정량)

  • Do, Lee Joo;Koh, Jae Suk;Kim, Ho Jin
    • Journal of the Korean Chemical Society
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    • v.43 no.5
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    • pp.517-521
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    • 1999
  • Gas chromatography using sulfur chemiluminescence detection (GC-SCD) which exhibits very good selectivity, linearity, and sensitivity was applied to the analysis of suIfur compounds in gaseous fuel. The expectmental method used in this study was to resolve the problems of repeatability and reproducibility by means of the adsorption of sulfur compounds, which is different from the existing analysis method of these compounds by GC-SCD. The calibration curves of the standard gases including dimethyl sulfide, t-butylmercaptan and ethyl methyl sulfide exhibited an excellent linearity. As the result of precision tests for the above three compounds, the high reproducibility for tests showed while repeating three times during four days, respectively. In addition, the coefficient of variation was less than 3%. In consequence, the expectmental method of this study is very effective not only with low uncertainty but also with better accuracy, which can quickly determine the concentration of gas odorants in LPG (Liquefied Petroleum Gas) from oil reservoirs and filling stations.

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The Malodor Decreasing Effect of Saccharomyces cerevisiae on Decomposing Waste Egg (Saccharomyces cerevisiae의 폐달걀 분해과정에서 발생하는 악취 감소효과)

  • Lee, Chang Hoon;Lee, Yong Ho;Yoo, Jae Hong;Park, Jun Young;Shim, Myoung Yong
    • Korean Journal of Environmental Biology
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    • v.34 no.3
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    • pp.177-182
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    • 2016
  • Malodor emitted while producing fertilizer from hatchery egg waste treated with microorganism is an important limiting factor. To reduce this problem, we attempted to use two yeast strains, Saccharomyces cerevisiae, KACC 30008 and KACC 30068. Both yeast strains reduce ammonia gas emission 35.4% than only treated with bacterium, Bacillus amyloliquefaciens. When both strains were used together, that was reduced as 57.1%. KACC 30008 and 30068 strains reduced hydrogen sulfide 42 and 90.4%, respectively. Both strains together reduced hydrogen sulfide gas as 98.5%. KACC 30008 did not decrease methyl mercaptan emission. However KACC 30068 decreased 40% and both strains together decreased the gas emission as 66.7%. Overall, this study showed that yeast treatment could enhance the effect of B. amyloliquefaciens treatment in the reduction of malodorous gas emission.

Construction of Strontium Titanate/Binary Metal Sulfide Heterojunction Photocatalysts for Enhanced Visible-Light-Driven Photocatalytic Activity

  • Yu, Yongwei;Yang, Qing;Ma, Jiangquan;Sun, Wenliang;Yin, Chong;Li, Xiazhang;Guo, Jun;Jiang, Qingyan;Lu, Zhiyuan
    • Nano
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    • v.13 no.11
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    • pp.1850130.1-1850130.12
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    • 2018
  • A novel strontium titanate/binary metal sulfide ($SrTiO_3/SnCoS_4$) heterostructure was synthesized by a simple two-step hydrothermal method. The visible-light-driven photocatalytic performance of $SrTiO_3/SnCoS_4$ composites was evaluated in the degradation of methyl orange (MO) under visible light irradiation. The photocatalytic performance of $SrTiO_3/SnCoS_4-5%$ is much higher than that of pure $SrTiO_3$, $SnCoS_4$, $SrTiO_3/SnS_2$ and $SrTiO_3/CoS_2$. The $SrTiO_3/SnCoS_4$ composite material with 5 wt.% of $SnCoS_4$ showed the highest photocatalytic efficiency for MO degradation, and the degradation rate could reach 95% after 140 min irradiation time. The enhanced photocatalytic activity was ascribed to not only the improvement of visible light absorption efficiency, but also the construction of a heterostructure which make it possible to effectively separate photoexcited electrons and holes in the two-phase interface.

Effects of water temperature for oral rinse and the use of toothpastes and tongue cleaners on halitosis (잇솔질 시 양칫물 온도, 치약 사용, 혀클리너 사용에 따른 구취의 영향)

  • Hwang, Soo-Jeong;Jung, Yoon-Zy;Lee, Soo-Kyoung;Lee, Ji-Eun;Lee, Hee-So;Jeon, Hee-Ju;Kim, Do-Kyeong
    • Journal of Korean Academy of Dental Administration
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    • v.7 no.1
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    • pp.44-49
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    • 2019
  • Halitosis is primarily caused by oral conditions. In particular, volatile sulfur compounds (VSCs) are mainly responsible for intra-oral halitosis. They are closely associated with the water temperature. In this study, we investigated the association between halitosis and water temperature for oral rinse (10℃, 30℃, and 45℃) using the BB checker and oral chroma. The application of BB checker on an empty stomach revealed that halitosis decreased with the use of tongue cleaners (p=0.001) and toothpastes (p=0.002). Furthermore, halitosis decreased after drinking milk (VSCs-induced food intake) (p=0.000). There were no significant differences in the results of oral chroma. Finally, we measured halitosis on an empty stomach and after drinking milk. The BB checker showed increased halitosis after drinking milk (p<0.001). The oral chroma showed decreased hydrogen sulfide (p<0.001) and increased methyl mercaptan (p=0.009) and dimethyl sulfide (p=0.002) after drinking milk. In conclusion, halitosis cannot be modulated using water temperature for oral rinse. The findings of this study cannot be generalized because of the small sample size and the limits of age and sex. Further studies are required to extensively analyze both sexes and various age groups, with more number of subjects.

Removal Efficiency of the Deodorization Equipment and Characteristics of Malodor during the Process in Co-treatment of Sewage and Food Waste of Su-young Wastewater Treatment Plant in Busan (부산수영하수처리장 하수와 음식물쓰레기 병합처리 시 공정별 악취특성 및 후처리시설 효율평가)

  • Lee, Hyung-Don;Kang, Dae-Jong;Lee, Min-Ho;Kang, Dong-Hyo;Oh, Kwang-Joong
    • Clean Technology
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    • v.18 no.4
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    • pp.379-389
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    • 2012
  • Environmental issues are being paid more attention due to income growth, urban overcrowding, and population growth in Korea. Among the various environmental problems, odor damage is the one of the serious factors. To take example for food waste combination treatment in Su-young wastewater treatment plant in Busan, many complaints occurred because this plant locate around residential areas. The purpose of this work is not only to analyze odorous elements and their contributions but also to evaluate odor quotient (OQ), sum of odor quotient (SOQ), and treatment efficiency of bio-filter. The results of dilution sensory test of complex odor, grinder, leachate, hopper indicated higher order complex odors happen in July and August. The main odorous elements consisted of hydrogen sulfide, ammonia, methly mercaptan and acetaldehyde, which were analyzed by instrumental detection method, and methyl mercaptan was exceeded over 3,571 times of threshold. In addition, result of contribution of odor was methyl mercaptan (49.95 to 59.08%), hydrogen sulfide (20.43 to 29.27%), trimethylamine (8.82 to 13.42%) and acetaldehyde (9.17 to 11.35%). Other facilities were compared with the contribution of the odor using OQ and SOQ during the process. Sulfur compounds, acetaldehyde, and trimethylamine are high contribution of odor using OQ as well as odor intensity of grinding process is highest. As a result, sulfur compounds (e.g., methyl mercaptan and hydrogen sulfide) are highest for OQ and SOQ of grinding process is highest as 7,067. The removal efficiency of deodorization equipment was more than 90.00% in ammonia and amines, but the average efficiency of sulfur compounds was 53.51%. Thus, this facility is more higher contribution of acetaldehyde and trimethylamine than other treatment facilities. And food waste treatment in environmental area needs to consider appropriate capacity and refers to other bio-filter operating conditions.

Evaluation of Thermal Catalytic Decomposition of Chlorinated Hydrocarbons and Catalyst-Poison Effect by Sulfur Compound (염소계 탄화수소의 열촉매 분해와 황화합물에 의한 촉매독 영향 평가)

  • Jo, Wan-Kuen;Shin, Seung-Ho;Yang, Chang-Hee;Kim, Mo-Geun
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.577-583
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    • 2007
  • To overcome certain disadvantages of past typical control techniques for toxic contaminants emitted from various industrial processes, the current study was conducted to establish a thermal catalytic system using mesh-type transition-metal platinum(Pt)/stainless steel(SS) catalyst and to evaluate catalytic thermal destruction of five chlorinated hydrocarbons[chlorobenzene(CHB), chloroform(CHF), perchloroethylene (PCE), 1,1,1-trichloroethane(TCEthane), trichloroethylene(TCE)]. In addition, this study evaluated the catalyst poison effect on the catalytic thermal destruction. Three operating parameters tested for the thermal catalyst system included the inlet concentrations, the incineration temperature, and the residence time in the catalyst system. The thermal decomposition efficiency decreased from the highest value of 100% to the lowest value of almost 0%(CHB) as the input concentration increased, depending upon the type of chlorinated compounds. The destruction efficiencies of the four target compounds, except for TCEthane, increased upto almost 100% as the reaction temperature increased, whereas the destruction efficiency for TCEthane did not significantly vary. For the target compounds except for TCEthane, the catalytic destruction efficiencies increased up to 30% to 97% as the residence time increased from 10 sec to 60 sec, but the increase of destruction efficiency for TCEthane stopped at the residence time of 30 sec, suggesting that long residence times are not always proper for thermal destruction of VOCs, when considering the destruction efficiency and operation costs of thermal catalytic system together. Conclusively, the current findings suggest that when applying the transition-metal catalyst for the better destruction of chlorinated hydrocarbons, VOC type should be considered, along with their inlet concentrations, and reaction temperature and residence time in catalytic system. Meanwhile, the addition of high methyl sulfide(1.8 ppm) caused a drop of 0 to 50% in the removal efficiencies of the target compounds, whereas the addition of low methyl sulfide (0.1 ppm), which is lower than the concentrations of sulfur compounds measured in typical industrial emissions, did not cause.