• 제목/요약/키워드: Methanol Flame

검색결과 44건 처리시간 0.029초

Ethanol and Methanol Concentration in Commonly Used Brands of Ma-al-shaeer in Iran: Estimation of Dietary Intakes and Risk Assessment

  • Shirani, Kobra;Bostan, Hassan Badie;Baroti, Ashkan;Hassanzadeh, Mohammad;Khashyarmanesh, Zahra;Haghighi, Hamideh Moalemzadeh;Karimi, Gholamreza
    • 대한약침학회지
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    • 제21권3호
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    • pp.168-176
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    • 2018
  • Objectives: Ma-al-shaeer is a popular beverage in Islamic countries. The aim of this study was to determine the concentrations of methanol and ethanol in most consumed brands of Ma-al-shaeer in Iran. Methods: Eighty-one Ma-al-shaeer samples which commonly used in Iran were provided. Methanol and ethanol contents were determined by gas chromatography with flame ionization detector. Results: The mean methanol concentrations in Iranian and foreign brands was $129.84{\pm}205.38mg/L$ and $110.157{\pm}135.98mg/L$, respectively. Although mean ethanol contents of Iranian brands was $1.2{\pm}2.41mg/L$, ethanol level in foreign ones was lower than LOQ. Conclusion: Since the most Ma-al-shaeer brands had methanol pollution at different levels establishment of a definitive relationship between the methanol content and toxicological effects seem to be vital. EDI of methanol for Iranian people through consumption of Maal-shaeer was determined 0.023mg/kg bw/day.

알코올을 주성분으로 하는 손소독제의 안전성 연구 (A Study on the Safety of Alcohol-based Hand Sanitizers)

  • 정선옥;이춘영;류회진;최희진;김지영;최채만;황인숙;신용승
    • 한국산업보건학회지
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    • 제33권1호
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    • pp.34-39
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    • 2023
  • Objectives: In this study, the safety of alcohol-based hand sanitizers (ABHSs) for quasi-drugs and cosmetics was investigated by analyzing the ethanol content, which is an active ingredient with a sterilizing effect, and methanol, which is toxic. Methods: Forty-one ABHSs were purchased at large supermarkets and online stores. Ethanol quantification was performed by gas chromatography-flame ionization detector, and methanol quantification was performed by headspace-gas chromatography-mass spectrometry. Results: The ethanol content of ABHS in quasi-drugs was 49.6-67.8%, which was suitable for standard manufacturing procedures for external disinfectants, and the ethanol content of ABHS in cosmetics was 9.1-61.3%. The methanol content of ABHS in quasi-drugs ranged from not detected(N.D.)-131.8 ppm, which was suitable for the methanol detection standard of ethanol raw materials in the Korean Pharmacopoeia. The methanol content of ABHS in cosmetics was 23.4-859.7 ppm, which was suitable for the detection limit of methanol in cosmetics. Conclusions: The ethanol and methanol content of ABHS was judged to be safe. When selecting an ABHS to be used for sterilization, it seems necessary to check the content of ethanol, an active ingredient, and use it according to its intended purpose.

가솔린 엔진용 대체연료의 타당성에 관한 연구(VI) (A Study on the Propriety of Substitute Fuel of Gasoline Engine(VI))

  • 유정인;양옥용
    • 오토저널
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    • 제7권4호
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    • pp.49-56
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    • 1985
  • This study consists of instrumenting and running tests on variable compression engines and measuring the following combustion characterics: (a)flame speed, (b) emission and (c)performance parameter such as power and economy. The results were as follows: 1) The phase separation diagram of substitute fuels were obtained from phase separation experiment. 2) The flame propagation speed of substitute fuels were higher than gasoline and increased with increasing methanol weight percent of substitute fuels. 3) BEMP of substitute fuels was slightly less than that of gasoline but in the range of small weight percent, BEMP was compatible to gasoline. 4) Concentration of NOx decreased significantly with delaying spark advancing time. Also, it decreased for rich equivalence ratio but increased with high compression ratio. In general, NOx concentration was much lower than that of gasoline. 5) Concentration of HC and CO increased for rich equivalence ratio. Also it was lower than that of gasoline.

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GC/FPD를 利用한 ${\beta}$-락탐系 抗生物質의 分析(II) (Determination of ${\beta}$-Lactam Antibiotics by Gas-Chromatography with Flame Photometric Detector (II))

  • 박만기;조영현;양정선;박정일
    • 약학회지
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    • 제28권4호
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    • pp.243-248
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    • 1984
  • For gas chromatographic determination with the sulfur-specific flame photometric detector, nine ${\beta}$-lactam antibiotics without ${\alpha}$-amino group were esterified with borontrifluoride-methanol complex and then N-benzoylated with benzoyl chloride. The gas chromatographic separation of these products was successfully carried out on various silicon polymers (OV-1, OV-101, OV-17, OV-225, and QF-1) coated on the acid washed, silanized diatomite. The structure of the esterified and N-benzoylated product was confirmed by mass spectromer.

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고압 분위기에서 CH4/O2 혼합기의 2단 다공체 내 부분산화 개질에 관한 실험적 연구 (Experimental Study on the Partial Oxidation Reforming of CH4/O2 Mixture in Two-Section Porous Media at High Pressure Conditions)

  • 곽영태;이대근;김승곤;고창복;박종호
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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    • pp.73-74
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    • 2015
  • Synthesis gas such as hydrogen and carbon monoxide was produced from $CH_4/oxygen$ mixture using insulated pressurized porous media combustor. Experimentally, two cylindrical SiC foams with the different pore density were piled up in a quartz tube and fully premixed mixture was supplied in the axial direction. After stabilizing fuel-rich flame at the interface of the two foams at several pressure conditions, mole fractions of synthesis gases were measured by gas chromatography. Heat recirculation through the inner foam structure could extend the flow velocity of stable region over the laminar burning velocity. As the pressure increased, the rich flammability limit, $H_2/CO$ ratio, and module M increased.

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CH4/O2 혼합기의 2단 다공체 내 부분산화 개질에 관한 실험적 연구 (Experimental Study on the Partial Oxidation Reforming of CH4/O2 Mixture in Two-Section Porous Media)

  • 곽영태;이대근;고창복
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.249-251
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    • 2014
  • Synthesis gas such as hydrogen and carbon monoxide was produced from $CH_4//oxygen$ mixture using two-section porous media combustor. Heat recirculation through the inner foam structure could extend the flow velocity of stable region over the laminar burning velocity. $H_2/CO$ ratio and module M from concentration of flue gas measured by Gas Chromatography was similar to those calculated by equilibrium. But it was made sure that the heat loss effect becomes more influential than heat recirculation effect as the mixture gets richer. To generate synthesis gas appropriate for methanol production, insulated pressurized porous media combustor will be designed and built in the future.

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메타놀의 희박연소를 위한 혼합기의 성층화와 연소특성에 관한 연구(제 I장 : IDI형 정적연소기에서의 혼합기 연소특성) (A Study on the Combustion Characteristics and Stratification for Lean Burn of Methanol (The Combust ion Character istics in a IDI Type Constant Volume Combustion Chamber))

  • 박춘근;윤수한
    • Journal of Advanced Marine Engineering and Technology
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    • 제21권3호
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    • pp.302-310
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    • 1997
  • In this paper, we find a method to improve ignitability using methanol which is prospective as an alternative fuel. The constant volume combuster is divided into main chamber and sub-cham¬ber. These two chambers are linked by an adapter which is shaped like a cup. We also compare CDI to HIS that is revised in our laboratory for making a scrutiny into the effects of ignition char¬acteristics. Besides, we analyze a flame propagation process in the main and sub-chamber through taking pictures 10, 000 frames per second by high speed camera at the state being fabricated quartz glass aside main and sub-chamber.

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Pool 화재에서의 표면 냉각에 의한 소화 (Extingushiment by the Colling Effect of the Fuel Surface with Pool Fires)

  • 한용식;김명배;신현동
    • 한국화재소방학회논문지
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    • 제11권4호
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    • pp.15-23
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    • 1997
  • A series of measurements and visualization to investigate the extingushiment of water sprays with pool fires is presented. Fire source is a small-scale pool burner with methanol, ethanol and gasoline. Measurements of temperature, O2, CO2, and CO concentrations along the plume centerline are carried out to observe pool structures without water sprays. Visualization by the Ar-ion laser sheet flow pattern of droplets of the sprays above the pool fires. It is observed than in the case of methanol and ethanol, water sprays continuously penetrate into the center of fuel surfaces. The gasoline pool fire allows intermittent penetration of water sprays because of pulsating characteristics of the gasoline flame. To evaluate the cooling effect of the fuel surface by the sprays, the temperature was measured at the fuel surface. As soon as the mists reach the fuel surface of methanol and ethanol, the temperatures of the fuel surface decrease rapidly below the boiling point, and then the fires are extinguished. Due to the application of mist upon the gasoline fire, though the fuel temperature decrease abruptly at the time of the injection, such a repid decrease do not continue till the extinction point.

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EXPERIMENTS ON THE INTERACTION OF WATER SPRAYS WITH POOL FIRES

  • Han, Yong-Shik;Kim, Myung-Bae;Shin, Hyun-Dong
    • 한국화재소방학회:학술대회논문집
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    • 한국화재소방학회 1997년도 International Symposium on Fire Science and Technology
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    • pp.518-525
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    • 1997
  • A series of measurements and visualization to investigate the interaction of water sprays with pool fires is presented. Fire source is a small-scale pool burner with methanol, ethanol and gasoline. Measurements of temperatures, $O_2$, $CO_2$, and CO concentrations along the plume centerline are carried out to observe pool fire structures without water sprays. Visualization by the Ar-ion laser sheet shows flow pattern of droplets of the sprays above the pool fires. It is observed that in the case of methanol and ethanol, water sprays continuously penetrate into the center of fuel surfaces. The gasoline pool fire allows intermittent penetration of water sprays because of pulsating characteristics of the gasoline flame. To evaluate the cooling effect of the fuel surface by the sprays, the temperature was measured at the fuel surface. As soon as the mists reach the fuel surface of methanol and ethanol, the temperatures of the fuel surface decrease rapidly below the boiling point, and then the fires are extinguished. Due to the application of mist upon the gasoline fire, though the fuel temperature decrease abruptly at the time of the injection, such a rapid decrease do not continue till the extinction point.

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메탄올 Bluff-Body 난류 화염내의 화염구조 및 $NO_{x}$ 생성 특성에 대한 수치적 연구 (Flamelet Modeling of Structures and $NO_{x}$ Formation Charateristics in Bluff-Body stabilized Methanol Flames)

  • 이준규;김성구;김용모;김세원
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.37-42
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    • 2001
  • This paper computes the bluff-body stabilized jet and flame. This study numerically investigates the nonpremixed $C_{2}H_{4}-air$ jet for the nonreacting case and the nonpremixed $CH_{3}OH-air$ turbulent flames for the reacting case using the laminar flamelet model on modified KIVA2 code. And this study predicts $NO_{x}$ formation characteristics using Eulerian Particle Flamelet Model. In the present study, the turbulent combustion model is applied to analyze both nonreacting and reacting case. And both standard $k-{\varepsilon}$ model and modified $k-{\varepsilon}$ model are used in nonreacting case. Calculations are compared with experimental data in terms of velocity, mixture fraction, mixture fraction Root Mean Square and Temperature. The present model correctly predicts the essential features of flame structures and $NO_{x}$ formation characteristics in the bluff-body stabilized flames.

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